• Title/Summary/Keyword: Decomposition Product

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Pyrolysis of Waste Oriental Medicine Byproduct Obtained from the Decoction Process of Achyranthes Root (우슬(Achyranthes Root) 탕제 후 얻어진 폐한약재 부산물의 열분해)

  • Park, Ji Hui;Jeong, JaeHun;Lee, Ji Young;Kim, Young-Min;Park, Young-Kwon
    • Applied Chemistry for Engineering
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    • v.29 no.4
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    • pp.474-478
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    • 2018
  • Thermal decomposition of waste Achyranthes Root (WAR) emitted from its decoction process was investigated using a TG analyzer and a fixed-bed reactor. The WAR had the larger C and fixed carbon content than fresh AR (FAR) due to the extraction of hemicelluloses from FAR during decoction process. Thermogravimetric (TG) analysis results also revealed the elimination of hemicellulose by its decoction. Relatively high contents of the cellulose and lignin made high contents of their typical pyrolyzates, such as acids, ketones, furans, and phenols, in the pyrolysis of WAR using the fixed-bed reactor. The increase of pyrolysis temperature from 400 to $500^{\circ}C$ increased yields of oil and gas due to the more effective cracking efficiency of WAR at a higher temperature. The chemical composition of product oil was also changed by applying the higher pyrolysis temperature, which increased the selectivity to furans and phenols.

An Analysis of Money Supply in Indonesia: Vector Autoregressive (VAR) Approach

  • YULIADI, Imamudin
    • The Journal of Asian Finance, Economics and Business
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    • v.7 no.7
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    • pp.241-249
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    • 2020
  • The role of money in the modern economy highly determines the intensity and the development of the macroeconomy. The money supply is assumed to be as much as money demand, which reflects the economic character of a country and indicates the growth and development of macroeconomy. In Indonesia, the money supply (M1) is related to the economic dynamics in either the monetary market or the goods market. This research aims at analyzing factors that influence the money supply and to what extent the economic factors affect the money supply in Indonesia. The analysis method used in this research was Vector Autoregressive (VAR) with some variables, such as money supply (M1), interest rate, and Gross Domestic Product (GDP) from the 1st quarter of 2001 until the 1st quarter of 2013. The data collection method was in the form of data compilation from credible sources, such as Bank of Indonesia (BI), Central Bureau of Statistics (CBS), and International Financial Statistics (IFS). To obtain adequate analysis results, several tests were taken, such as unit-root test, Granger causality test, and optimal lag. VAR analysis formulates the correlation among independent variables, so it also sees the study of impulse response and matrix decomposition.

Design and Performance Evaluation of an Assemble-To-Order System (주문- 조립시스템의 설계 및 성능평가)

  • 박찬우;이효성
    • Journal of the Korean Operations Research and Management Science Society
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    • v.27 no.4
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    • pp.41-65
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    • 2002
  • We study a multi-component production/inventory system in which individual components are made to meet various demand types. We assume that the demands arrive according to a Poisson process, but there is a fixed probability that a demand requests a particular kit of different components. Each component is produced by a flow line with several stations in which the processing times of each station follow a two-stage Coxian distribution. The production of each component is operated by an independent base-stock policy with blocking. We assume that the time needed to assemble final products follows a general distribution and the capacity of an assembling facility is sufficiently large. The objective of this study is to obtain key performance measures such as the distribution of the number of each orders for each final product and the mean time of fulfilling a customer order. The basic principle of the proposed approximation method is to decompose the original system into a set of subsystems, each subsystem being associated with a flow line. Each subsystem is analyzed in isolation using a Marie's method. An iterative procedure is then used to determine the unknown parameters of each subsystem. Numerical results show that the accuracy of the approximation method is acceptable.

Study of Antioxidative Substances from Some Indonesian Plants

  • Cahyana, Herry
    • Proceedings of the Korean Society of Applied Pharmacology
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    • 1998.11a
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    • pp.162-162
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    • 1998
  • Various natural compounds act as antioxidants in protection against lipid peroxidation. Lipid peroxidation yields a variety of decomposition products which have been implicated in not only decreasing the nutritional value of food, but also in developing an off-flavor and toxic substances. As a source of safer and more effective natural antioxidants of natural origin have been widely investigated. Some Indonesian plants have evaluated for their antioxidative activity, and suggested the possible existence of various antioxygenic compounds in them. We attempted to study such antioxygenic compounds with simple method evaluation. As we are interested in the natural product compounds, we examined of several sample such as edible sea-weeds, and some edible fruits. Sea-weed, Eisenia bicyclis, one of the edible brown algae, exhibited the activity. As a traditional food additive consumed by Indonesian, Garcinia parvifolia is used as taste supplement in region West Sumatra, have been studied. Our current studies on the semi-polar fractions shows the activity by the thiocyanate method test. Another sample, Garcinia mangostana, a famous fruit with sweet taste, the part kernel have also evaluated. The acidic fraction of the extract showed antioxidative activity. Some other active components were found in the neutral and BuOH fractions.

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Silk Fibroin/Chitosan Conjugate Crosslinked by Tyrosinase

  • Kang, Gyung-Don;Lee, Ki-Hoon;Ki, Chang-Seok;Nahm, Joong-Hee;Park, Young-Hwan
    • Macromolecular Research
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    • v.12 no.5
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    • pp.534-539
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    • 2004
  • Two biopolymers, silk fibroin (SF) and chitosan, were conjugated by tyrosinase (EC 1.14.18.1), a polyphenolic oxidase, to improve their physicochemical properties, such as their thermal properties and morphological stabilities in organic solvents. The crosslinking between SF and chitosan took place mainly through Michael addition reactions. A main reaction between the amino groups in chitosan and o-quinone, the oxidation product of the tyrosyl residue in SF, was confirmed by UV spectroscopy. Measurements of viscosity and light scattering indicated that the crosslinked SF/chitosan conjugate was compact: it had a smaller particle size because of tight bonding forces between the SF and chitosan molecular chains. Thermal decomposition of SF/chitosan conjugates crosslinked by tyrosinase occurred at higher temperatures. The adhesiveness of the SF/chitosan conjugates decreased steadily as the crosslinking reaction progressed. We propose that this new crosslinking method be used for the preparation of silk fibroin/chitosan conjugates using tyrosinase. We expect that SF/chitosan conjugates crosslinked by tyrosinase can be used preferentially in biomedical applications because of its unique properties and non-toxicity.

Integrated production planning in supply chain management environment considering manufacturing partners (SCM 환경에서의 협력 생산을 고려한 통합 생산 계획에 관한 연구)

  • Jeong Ho Sang;Jeong Bong Ju
    • Proceedings of the Korean Operations and Management Science Society Conference
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    • 2002.05a
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    • pp.363-370
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    • 2002
  • This paper presents a production planning algorithm for minimizing the costs of production and subcontracting in SCM (supply chain management) environment. In our SCM environment, the several local plants that aye dispersed geographically produce parts and products. In this environment, we have to decide the production volumes of both parts and products considering the BOM (bill-of-material) structure to meet the fixed order quantity or forecasted demand quantity. Each plant produces the specified parts of product with finite production capacity. There exist subcontracting decisions relevant to the production capacity of each plant except the core process plant, and when we use the subcontractor's capacities we should be charged for the fixed subcontracting fees. The objective of this study is to solve the production planning problem, which minimizes the total costs of production, inventory, setup, and subcontracting under constraints of production and subcontracting capacity. For this problem, an integrated production planning model based on the multi-level capacitated lot sizing problem was formulated, and efficient decomposition algorithm was proposed. The experimental investigation shows that the proposed heuristic generates quite good solutions at very low computational costs.

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Studies on Telomerization (I) Telomerization of Vinyl Acetate with Chlorinated Hydrocarbons (Telomerization 에 關한 硏究 (I) Vinyl Acetate 와 Chlorinated Hydrocarbons 과의 Telomerization 에 關하여)

  • Shim, Jyong-Sup;Hong, Suck-Joo
    • Journal of the Korean Chemical Society
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    • v.6 no.1
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    • pp.88-93
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    • 1962
  • The telomerization of vinyl acetate with carbon tetrachloride, chloroform and monochlorobenzene were investigated with respect to the synthesis of those telomers, properties and molecular weights of the formed telomers, and reaction mechanisms. Vinyl acetate reacted with carbon tetrachloride and chloroform to form telomers at 70-90$^{\circ}C$ and 60-70$^{\circ}C$, respectively and it formed polymer with monochlorobenzene. As a chain transfer agent, carbon tetrachloride was more effective than chloroform. In the telomerization of vinyl acetate and carbon tetrachloride: 1) The average molecular weight of the telomer decreased as the mole ratio of carbon tetrachloride to vinyl acetate increased. The optimum conditions for the highest yield of the telomer were as follows: Mole ratio of carbon tetrachloride to vinyl acetate : 2.5 Reaction time : 20 hours. 2) As the reaction proceeded, the refractive index and average molecular weight of the telomer increased rapidly in the first 10 hours but the increase was slow through the next 10 hours, so that, the average recurring number(n) of taxogen in the final product reached an almost definite value, i.e., 3. The telomer formed in the telomerization of vinyl acetate with carbon tetrachloride and chloroform turned to brown color in the air due to decomposition or polymerization. The suggested telomerization mechanism was supported by the hexachloroethane detected in the course of reaction.

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An Application of Canonical Analysis on the Distribution of Lichens in Mt. Duckyuoo (덕유산 지의식물 분포에 대한 정준분석법의 적용연구)

  • Park, Seung Tai
    • The Korean Journal of Ecology
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    • v.9 no.3
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    • pp.135-147
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    • 1986
  • The simplification and the searching trends of complex data which assumed relationship between predictor variables and object variables are one of primary objective of ecological research. This study was aimed to apply cononical analysis consisting of canonical correlation analysis and canonical variate analysis related to lichen vegetation and several environmental variables which are elevation, height on grond, exposure side and cover values. Data collected from the Duckyoo National Park in August 1985. Lichen species was ranked by eqivocation information theory with cover values. Canonical correlation analysis was applied to one data set both set both environmental variables and lichem family. In order to make two sets of data matrix the scale of position vector ordination was calculated from the vector scalar product for lichen species. Canonical variate analysis was applied to rearranged data which was made by interval class code for environmental variables. The sharpness values was calculated in frequency of cotingency tables and the dispersion profiles of each species in classes of environmental variables was designed to extract component values based on the decomposition of expected frequencies in contingency table. The results of canonical correlation analysis revealed canonical first correlation value 0.815(89%), and second correlation value 0.083(11%). Significance test showed that the hypothesis of joint mutuallity of canonical correlation is accepted (P>0.05). The relation between canonical score of vegetation variables and that of environmental variable indicated linear tendency.

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Investigation on Reaction Pathways for ZnO Formation from Diethylzinc and Water during Chemical Vapor Deposition

  • Kim, Young-Seok;Won, Yong-Sun
    • Bulletin of the Korean Chemical Society
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    • v.30 no.7
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    • pp.1573-1578
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    • 2009
  • A computational study of the reactions between Zn-containing species, the products of the thermal decomposition of diethylzinc (DEZn) and water was investigated. The Zn-containing species – $C_2H_5)_2,\;HZnC_2H_5,\;and\;(ZnC_2H_5)_2$ – were assumed to react with water during ZnO metal organic chemical vapor deposition (MOCVD). Density functional theory (DFT) calculations at the level of B3LYP/6-311G(d) were employed for the geometry optimization and thermodynamic property evaluation. As a result dihydroxozinc, $Zn(OH)_2$, was the most probable reaction product common for all three Zn-containing species. A further clustering of $Zn(OH)_2$ was investigated to understand the initial stage of ZnO film deposition. In experiments, the reactions of DEZn and water were examined by in-situ Raman scattering in a specially designed MOCVD reactor. Although direct evidence of $Zn(OH)_2$ was not observed, some relevant reaction intermediates were successfully detected to support the validity of the gas phase reaction pathways proposed in the computational study.

A Dynamic Study on Housing and Stock Market in Europe : Focused on Greece

  • JEONG, Dong-Bin
    • East Asian Journal of Business Economics (EAJBE)
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    • v.8 no.1
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    • pp.57-69
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    • 2020
  • Purpose - This study examines what are the asset market fluctuations in Europe and how each economic variable affects major variables, and explore the dynamics of housing and stock market through Greece. The variables under consideration are balance on current account (BCA), index of stock (STOCK), gross domestic product (GDP), housing price indices (HOUSING), M3, real rate of interest (IR_REAL) and household credits (LOAN). We investigate the functional and causal relationships between housing and stock market. Research design, data, and methodology - Vector error correction model (VECM) is used to figure out the dynamic relationships among variables. This study also contains the augmented Dickey-Fuller unit root, cointegration, Granger causality test, and impulse response function and variance decomposition analysis by EViews 11.0. Results - The statistical tests show that all variables under consideration have one unit root and there is a longterm equilibrium relationship among variables for Greece. GDP, IR_REAL, M3, STOCK and LOAN can be considered as causal factors to affect real estate market, while GDP, LOAN, M3, BCA and HOUSING can bring direct effects to stock market in Greece. Conclusions - It can be judged that the policy that affects the lending policy of financial institutions may be more effective than the indirect variable such as monetary interest rate.