• Title/Summary/Keyword: Decay time

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Estimation of Decay Heat Generated from Long-Term Management of Spent Fuel (장기관리 핵연료로부터 방출되는 붕괴열량 추정)

  • Park, J.W.;J.H.Whang;Chun, K.S.;Park, H.S.
    • Nuclear Engineering and Technology
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    • v.21 no.1
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    • pp.48-55
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    • 1989
  • In this study, simple functional forms which could predict decay heat are referred to and modified in order to analyse more easily long-term behavior of decay heat generated from domestic PWR and CANDU spent fuel. To reduce the difference between the predicted data by functional forms and ORIGEN 2 results and to predict the decay heat under the important parameter(s), sensitivity analysis is performed. By introducing the identified hey parameter, turnup, into the functional forms, the decay heat of spent fuels within a limited rangs of cooling time(3~500 years) becomes predictable for various turnup rates. The predicted decay heat of spent fuels with representative turnup rates such as 33, 37 and 40 GWD/MTU by the functional forms is in so good agreement with ORIGEN 2 results within $\pm$10% difference over the cooling time from 1 to 10$^{5}$ years that the functional forms presented here may be used for engineering purposes such as the thermal design and assessment of the facilities associated with spent fuel management.

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Prediction of the Concentration Decay of Volatile Organic Compounds under Different Air Change Rates and Loading Factor Conditions (환기회수 및 부하율 변화에 따른 휘발성유기화합물 농도 감쇠 예측에 관한 연구)

  • Pang Seung-Ki;Sohn Jang-Yeul;Ahn Byung-Wook
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.17 no.6
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    • pp.505-513
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    • 2005
  • We measured the time-dependent concentration of VOCs emitted from Ondol floor, furniture, and the wall made of various building materials. After obtaining results from the previous measurement, we developed the estimation equations of the concentration decay, and obtained the estimated graphs for the concentration decay under different air change rates and loading factor conditions by using the estimated equations. We conducted our tests by applying our measurements to real residences for 110 days in the case of furniture and for 40 days in the case of the floor. We also conducted experiments in the cases of various wall materials for 7 days which totaled 10 times. We used the GC/FID for experiments for real residences accord-ing to the specified procedures of the NIOSH 1501, and carried out experiments for wall materials according to the specified procedures of the ASTM 5116-97. When conducting experiments for wall materials, we set the temperature and relative humidity at $23^{\circ}C$ and $50\%$, respectively. We also set the air change rate and loading factor at 0.7/h and $1.617 m^2/m^3$, respectively. Our results showed that it is possible to predict proplrly the time-dependent concentration decay of VOCs by using logarithmic functions in both cases of experiments for real residences and for wall materials. Furthermore, we found that the concentration decay rate of VOCs increased rapidly as the air exchange rate increased while the concentration decay rate decreased as the loading factor increased.

Decay of Populus cathay Treated with Paraffin Wax Emulsion and Copper Azole Compound

  • Liu, Jie;Liu, Min;Hou, Bingyi;Ma, Erni
    • Journal of the Korean Wood Science and Technology
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    • v.47 no.1
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    • pp.21-32
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    • 2019
  • In order to investigate the decay process of wood treated with preservative, waterproofing agent and their compound systems, a full-cell process was applied to impregnate the sapwood of poplar (Populus cathay) at paraffin wax emulsion concentrations of 0.5% and 2.0%, Copper Azole (CA) concentrations of 0.3% and 0.5%, and their four compound systems, respectively. Leaching tests and laboratory decay resistance against the white-rot fungus Corious versicolor (L.) Murrill for treated wood were carried out according to the America Standard E11-06 and China Standard GB/T 13942.1-2009. At certain time intervals during the decay test, samples were characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray diffraction technique (XRD) to investigate the time-dependent changes of chemical components and crystalline structure, thus clarifying the decay mechanisms. The results suggested that white-rot fungi degrade hemicellulose and lignin in the wood cell wall first, followed by a simultaneous degradation of polysaccharides and lignin. Besides, CA could not only slower the decomposition of both hemicellulose and lignin, but also reduce the degradation amount of hemicellulose. However, paraffin wax emulsion at high concentration had a negative effect on the impregnation of CA for the compound system treated wood.

Effect of three common hot beverages on the force decay of orthodontic elastomeric chain within a 28-day period: An in vitro study

  • Maziar Nobahari;Fatemeh Safari;Allahyar Geramy;Tabassom Hooshmand;Mohammad Javad Kharazifard;Sepideh Arab
    • The korean journal of orthodontics
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    • v.54 no.3
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    • pp.153-159
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    • 2024
  • Objective: This study aimed to assess the effects of commonly consumed hot drinks on the force decay of orthodontic elastomeric chains. Methods: This in vitro experimental study evaluated 375 pieces of elastomeric chains with six rings placed on a jig. Four rings were stretched by 23.5 mm corresponding to the approximate distance between the canine and the second premolar. Fifteen pieces served as reference samples at time zero, and 360 pieces were randomized into four groups: control, hot water, hot tea, and hot coffee. Each group was further divided into six subgroups (n = 15) according to the different exposure periods. The specimens in the experimental groups were exposed to the respective solutions at 65.5℃ four times per day for 90 seconds at 5-second intervals. The control group was exposed to artificial saliva at 37℃. The force decay of the samples was measured at 1, 2, 7, 14, 21, and 28 days using a universal testing machine. Data were analyzed using repeated-measures analysis of variance. Results: Maximum force decay occurred on day 1 in all groups. The minimum force was recorded in the control group, followed by the tea, coffee, and hot water groups on day 1. At the other time points, the minimum force was observed in the tea group, followed by the control, coffee, and hot water groups. Conclusions: Patients can consume hot drinks without concern about any adverse effect on force decay of the orthodontic elastomeric chains.

Photoisomerization of Symmetric Carbocyanines

  • 민형식;강유남;박정희
    • Bulletin of the Korean Chemical Society
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    • v.19 no.7
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    • pp.747-753
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    • 1998
  • The phoisomerization process of symmetric carbocyanine dyes such as 3,3'-diethyloxadicarbocyanine iodide (DODCI), 3,3'-diethylthiadicarbocyanine iodide (DfDCI), 1,1'-diethyl-2,2'-dicarbocyanine iodide (DDI), 1,1'-diethyl-2,2'-carbocyanine iodide (DCI), and cryptocyanine (1,1'-diethyl-4,4'-carbocyanine) iodide (CCI) have been studied by measuring the steady state and time resolved fluorescence spectra and the ground-state recovery profiles. The steady-state fluorescence spectrum of photoisomer as a function of concentration and excitation wavelength provides the evidence that the fluorescence of photoisomer is formed by the radiative energy transfer from the normal form and the quantum yield for the formation of photoisomer is increased by decreasing the excitation wavelength. The fluorescence decay profiles have been measured by using the time correlated single photon counting (TCSPC) technique, showing a strong dependence on the concentration and the detection wavelength, which is due to the formation of excited photoisomers produced either by the radiative energy transfer from the non-nal form or by absorbing the 590 nm laser pulse. We first report the fluorescence decay time of photoisomers for these cyanine dyes. The experimental results are explained by introducing the semiempirical calculations. The ground state recovery profiles of DTDCI, DDI, and CCI normal forms have been measured, showing that the recovery time from the singlet excited state is similar with the fluorescence decay time.

Comparison of Blue Luminescence Between Spark-processed Photoluminescian Silicon and Ambient Air Aged Anodically Etched Porous Silicon

  • Chang, Sung-Sik;Yoon, Sang-Ok
    • The Korean Journal of Ceramics
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    • v.2 no.3
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    • pp.137-141
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    • 1996
  • Ambient air aged anodically etched porous silicon (PS) and spark-processed silicon (sp-Si) show interesting similarities and dissimilarities in some of their luminescence-related properties. Among these similarties are: (1) the photoluminescence (PL) peak maximum in the blue/violet (410 nm);(2) the blue/violet PL peak positions are essentially unchanged with temperature ; (3) PL decay times in the nanosecond region which are independent of the detection wavelength, which is much faster in decay times compared to that of observed decay time in $SiO_2$.Among the dissimilarities are: (1) the PL intensity of blue/violet luminescence, namely, the PL intensity of sp-Si is at least 2 orders of magnitude larger than that of an ambient air aged PS; (2) the blue/violet PL intensity of sp-Si is more stable than that of ambient air aged PS under UV illuminations; (3) FTIR spectra of sp-Si favor those modes, which involve silicon -oxygen bonds in $SiO_2$ stoichiometry, whereas ambient air aged PS can be considered as a nonstoichiometric oxide judging from the observed vibrational spectra.

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The Influence of Moisture Contents on Decay and Carbonization in Flue-Cured Tobacco during Aging storage. (잎담배의 수분함량이 부패 및 탄화엽 발생에 미치는 영향)

  • 민영근;이경구;안동명;이완남
    • Journal of the Korean Society of Tobacco Science
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    • v.13 no.1
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    • pp.61-68
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    • 1991
  • The moisture contents of threshed leaf tobacco during aging storage were very important factor for the improvement or deterioration of leaf quality. Decay and carbonization of leaf tobacco were mainly controlled by moisture contents during storage. The influence of moisture contents on the decay and carbonization of threshed leaf tobacco (Flue-Cured, Var. NC 82. AB3O-1 grade) were examined during 1 year. The moisture contents of leaf tobacco were treated to 3 kg as 12% (controle), 16%, 20% and 24% after redrying, respectively, These tobacco were put into center of carton box containing about 200kg with 12%'s tobacco, and then packed and stored from June, 1988 under natural weather condition in warehouse at Ock-Cheon threshing plant. Samples were taken from dissected carton box at 0, 1, 2, 4, 7 and 12 months after moisture treatment and Racking time, and some chemical properties were investigated at every sampling time. In results of inducement to decay and carbonization of leaf tobaccos during 1 year's storage by moisture treatment. decayed leaf was appeared but carbonized leaf did not. Calorification and decayed leaf occurred at high moisture contents above 20%, and these phenomena were appeared between 30 and 150 days after moisture treatment and packing. High moisture content leaves (above 20%) caused nearby other leaves to be sunk with high moisture content. Nicotine and calcium contents were increased to 20%~30% and 10%~22%, respectively, but total sugar contents was decreased to 40%~60% by moisture treatment(20% ~24% ).

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Surface Analysis of Plasma-treated PDMS by XPS and Surface Voltage Decay

  • Youn, Bok-Hee;Park, Chung-Ryul;Kim, Nam-Ryul;Seo, Yu-Jin;Huh, Chang-Su;Lee, Ki-Taek
    • Transactions on Electrical and Electronic Materials
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    • v.3 no.4
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    • pp.10-15
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    • 2002
  • Surface states of polydimethylsiloxane (PDMS) treated by plasma were investigated by the analysis by x-ray photoelectron spectroscopy (XPS) and surface voltage decay. Plasma treatment causes the silica-like(SiO$\_$x/, x=3∼4) oxidative layer, which is confirmed with XPS, and lowers surface resistivity from 1.78$\times$1014 Ω/square to 1.09$\times$10$\^$13/ Ω/square with increasing the plasma treatment time. By measuring the decay time constant of surface voltage, the calculated surface resistivity was compared with the value directly measured by a voltage-current method, so good agreement between two methods was obtained. It was observed that the plasma treatment led to decrease of the thermal activation energy of the surface conduction from 31.0 kJ/mol of untreated specimen to 21.8 kJ/mol. It is found that our results allow the examination of effects of plasma on electrical properties of PDMS.

Effects of Water Treating on Surface Properties of Epoxy Insulation Materials (Epoxy 절연재료이 표면특성에 미치는 수분처리의 영향)

  • Lim, Kyung-Bum;Lee, Duck-Chool
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.49 no.10
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    • pp.553-558
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    • 2000
  • This paper deals with change of contact angle, surface potential decay, surface resistivity and XPS of water-treated epoxy insulator. From the experimental results on the contact angle was reduced from $74^{\circ}$to $24^{\circ}$ due to the formation of polar hydroxyl groups on surface which was associated with intermolecular reaction between epoxy chains of three-dimensional network structure and water molecules. From the experimental results in the surface potential decay of water treated-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened by the interaction of polar hydroxyl groups induced on the treated surface as the increment of treatment time. The positive charging on the treated surface compared with negative charging is relatively lowered by the induction of polar hydroxyl groups. The surface resistivity was changed from $10^{15}[{\Omega}/cm^2$] to $10^{12}[{\Omega}/cm^2$] caused by water treatment. From XPS, it was found that the changes affected by the surface degradation of epoxy were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.

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