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AFM Study on Surface Film Formation on a Graphite Negative Electrode in a $LiPF_6$-based Non-Aqueous Solution (AFM을 이용한 $LiPF_6$를 주성분으로 하는 비수용액중에서의 흑연 음극 표면에 형성되는 피막에 관한 연구)

  • Jeong, Soon-Ki
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.6
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    • pp.1313-1318
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    • 2006
  • The mechanism fur the surface film formation was studied by in situ Atomic Force Microscopy (AFM) observation of a highly oriented pyrolytic graphite (HOPG) basal plane surface during cyclic voltammetry at a slow scan-rate of 0.5 mV $s^{-1}$ in 1 moi $dm^{-3}$ (M) $LiPF_6$ dissolved in a mixture of ethylene carbonate (EC) and diethyl carbonate (DEC). Decomposition of the electrolyte solution began at a potential around 2.15 V vs. $Li^+$/Li on step edges. In the potential range 0.95-0.8 V vs. $Li^+$/Li, flat areas (hill-like structures) and large swelling appeared on the surface. It is considered that these two features were formed by the intercalation of solvated lithium ions and their decomposition beneath the surface, respectively. At potentials more negative than 0.80 V vs. $Li^+$/Li, particle-like precipitates appeared on the basal plane surface. After the first cycle, the thickness of the precipitate layer was 30 nm. The precipitates were considered to be decomposition of the lithium salt ($LiPF_6$) and solvent molecules (EC and DEC), and to have an important role in suppressing further solvent decomposition on the basal plane.

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Nutrition Survey of Children in A Kindergarten of a Private Elementary School in Pusan 1. A Study on Nutrient intake and Nutritional Status (부산시내 일부 사립국민학교 부속 유치원 어린이의 영양 실태에 관한 연구 1. 영양 섭취실태 및 건강실태 조사)

  • Kim, Kap-Soon;Lee, Sung-Ho;Chae, Ki-Su;Lim, Hyo-Jin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.23 no.4
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    • pp.587-593
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    • 1994
  • A nutrition survey of 152 children , in the kindergarten attached to a proivate elimentary school of Pusan, was undertaken between Dec. 1 and Dec.14, 1993, to investigate dietary intake and nutrition status. The results are summarized as follows. 1) Compared with the Korean child development standard, their development conditions showed 113.1% , 102.2% , 103.3%, 101.75 in weight, height, head and chest, respectively. 2) By the standard of WLI(Weight Length Index) , proper to the children between age 4 and 6 , there proved to be 25% overweight and 4% obesity, 25% overweight and 19% obesity , 28 overweight and 26% obesity in 4-year-old, 5 year-old, and 6 -year-old children, respectively. 3) The children between age 4 and 6 averaged 37.6% in hematocrit and 12.4-12.8 5 in hemoglobin. these values were higher than those of the Korea child development standard. but the numbers of erythocyte, leucocyte and platelets were normal . Only a single child was considered suffering from aenmia . The 8% of them were over 200mg/이 in cholesterol, dangerously approaching the atherosclerosis. The 31% averaged 120mg/이 in triglyceride . And the 6% proved 100mg/이 in blood glucose when hung교. So it came out that not a few children had some factors dangers to diabetes, atherosclerosis and heart diseases : complications arising from obesity. 4) The intake of nutrients , except the 4-year-old children , ranged 108.4% to 2665 from the recommended value. The rates of carbohydrate, fat and protein to be much correlation among total intake of nutrients, development , results of blood test and WLI. The degree of obesity was proportionate to the intake of nutrients.

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Environmental Factors and Catch Fluctuation of Set-Net Grounds in the Coastal Waters of Yeosu (여수연안 정치망 어장의 환경요인과 어항 변동에 관한 연구)

  • Kim, Dong-Soo;Rho, Hong-Kil
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.29 no.1
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    • pp.1-10
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    • 1993
  • In order to investigate the environmental properties of set net grounds located in the coastal waters of Yeosu, oceanographic observations on the fishing grounds were carried out by the training ship of Yeosu Fisheries University from Jun. 1988 to Dec. 1990. The resultes obtained are summarized as follows; 1) The water mass in the fishing grounds were divided into the inner water (29.50-31.00$\textperthousand$), the mixed water (31.10-32.70$\textperthousand$) and the offshore water (32.70-34.30$\textperthousand$) according to the distribution of salinity from T-S diagram plotted all salinity data observed from Jun. 1988 to Dec. 1990. In spring the mixing water prevailed and in summer the inner and mixing water. But in autumn and winter the mixing and offshore waters prevailed. 2) The inner water which was formed by land water from the river of Somjin and the precipitation in the Yeosu district flowed southerly along the coast of Dolsando and spread south-easterly in the vicinity of Kumodo. The inner water and offshore water which supplied from the vicinity of Sorido and Yokchido formed the thermal front and halofront. 3) As the mixing water flowing from the western sea of Cheju to the southern coast of korea was low in temperature, the water mass of low temperature which appeared at the offshore bottom of Sorido in summer was considered not to be the Tsushima warm current. 4) As vertical mixing was made frequently in spring, autumn and winter, the differences in temperature and salinity between surface and bottom was respectively small. In summer, however, the mixing was not made because of the inner water expanded offshore through the space between surface and 10m layer and so a thermocline of $2.0^{\circ}C$/10m and halocline of 4.0$\textperthousand$/10m respectively in vertical gradient was formed. 5) In the vicinity of Dolsando and Kum a water low in salinity prevailed, but in the vicinity of Namhaedo and YoKchido the reverse took place. The inner and mixing waters formed at these arease was limited to the observation area not to spread widely.

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Simulation of the Reduction Effect of Soil Loss Using SWAT Model (SWAT 모형을 이용한 토양유실량 저감효과 모의)

  • Jeong, Jin-Kweon;Kim, Hwan-Gi
    • Journal of Environmental Impact Assessment
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    • v.17 no.4
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    • pp.243-253
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    • 2008
  • The purpose of this study was to simulate the reduction effect of soil loss in the Yongdam reservoir watershed using SWAT model. To evaluate accuracy for flow and sediment yield of SWAT model, calibration was performed for the period from Jan. 2002 to Dec. 2003, and the verification for Jan. 2005 to Dec. 2005. The calibration and the verification were carried out using data observed at the Cheoncheon gaging station. The $R^2$ and EI values in terms of a flow were 0.8 and 0.78 respectively for calibration, whereas they for verification were 0.88 and 0.86 respectively. In terms of a sediment yield, they were 0.7 and 0.48 respectively for calibration, whereas for verification were 0.64 and 0.54 respectively. As a results from model simulation, annual mean soil loss rates in terms of forest, paddy and upland were 0.02 ton/ha/yr, 0.15 ton/ha/yr and 7.58 ton/ha/yr, respectively. The results show that the land use type of a upland has more significant impact on a total soil loss as well as a sediment yield than other types of land use. The sediment delivery ratio was determined to be about 0.35. In this study 2 land cover change scenarios for upland area were considered. These scenarios were used an input to SWAT model in order to evaluate their impact on soil loss and sediment delivery. The results show that a reduction of the upland area would reduce the soil loss and sediment yield.

Seasonal Difference in Linear Trends of Satellite-derived Chlorophyll-a in the East China Sea (위성 해색자료에서 추정한 동중국해 클로로필 선형경향의 계절별 차이)

  • Son, Young Baek;Jang, Chan Joo;Kim, Sang-Hyun
    • Ocean and Polar Research
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    • v.35 no.2
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    • pp.147-155
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    • 2013
  • The purpose of this study is to investigate seasonal difference in linear trends in satellite-derived chlorophyll-a concentration (Chl-a) and their related environmental changes in the South Sea of Korea (SSK) and East China Sea (ECS) for recent 15 years (Jan. 1998~Dec. 2012) by analyzing climatological data of Chl-a, Rrs(555), sea surface wind (SSW) and nutrient. A linear trend analysis of Chl-a data reveals that, during recent 15 years, the spring bloom was enhanced in most of the ECS, while summer and fall blooms were weakened. The increased spring (Mar. - May) Chl-a was associated with strengthened winter (Dec. - Feb.) wind that probably provided more nutrient into the upper ocean from the deep. The causes of decreased summer (Jun. - Aug.) Chl-a in the northern ECS were uncertain, but seemed to be related with the nutrient limitation. Recently (after 2006), low-salinity Changjiang diluted water in the south of Jeju and the SSK had lower phosphate that caused increase in N/P ratio with Chl-a decrease. The decreased fall (Sep. - Nov.) Chl-a was associated with weakened wind that tends to entrain less nutrient into the upper ocean from the deep. This study suggests that phytoplankton in the ECS differently changes in response to environmental changes depending on season and region.

Influence of Ratio of Top and Bottom Oxide Thickness on Subthreshold Swing for Asymmetric Double Gate MOSFET (비대칭 이중게이트 MOSFET에서 상단과 하단 산화막 두께비가 문턱전압이하 스윙에 미치는 영향)

  • Jung, Hakkee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.20 no.3
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    • pp.571-576
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    • 2016
  • Asymmetric double gate(DG) MOSFET has the different top and bottom gate oxides thicknesses. It is analyzed the deviation of subthreshold swing(SS) and conduction path for the ratio of top and bottom gate oxide thickness of asymmetric DGMOSFET. SS varied along with conduction path, and conduction path varied with top and bottom gate oxide thickness. The asymmetric DGMOSFET became valuable device to reduce the short channel effects like degradation of SS. SSs were obtained from analytical potential distribution by Poisson's equation, and it was analyzed how the ratio of top and bottom oxide thickness influenced on conduction path and SS. SSs and conduction path were greatly influenced by the ratio of top and bottom gate oxide thickness. Bottom gate voltage cause significant influence on SS, and SS are changed with a range of 200 mV/dec for $0<t_{ox2}/t_{ox1}<5$ under bottom voltage of 0.7 V.

Estimation of Dormancy Breaking Time by Development Rate Model in 'Niitaka' Pear(Pyrus pirifolia Nakai) (발육속도 모델을 이용한 배 '신고' 자발휴면타파시기 추정)

  • Han, J.H.;Lee, S.H.;Choi, J.J.;Jung, S.B.;Jang, H.I.
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.10 no.2
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    • pp.58-64
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    • 2008
  • This study was carried out to determine the availability of development rate(DVR) model for predicting bud break time of 'Niitaka' pear. In addition, the study also assessed the effect of an increase in temperature on predicting bud dormancy breaking time in winter season. The DVR model, which was developed for 'Kosui' pear, illustrated that the bud break time(e.g., Dec. 12-Dec. 19) of 'Niitaka' pear observed in the field corresponded to the predicted bud break time by DVR model. This result indicates that the bud break time of 'Niitaka' pear can be predicted by DVR model tuned for 'Kosui' pear. As the temperature increased during the winter season, the bud break time was delayed. Chilling requirement deficiency for the bud break time is expected in Jeju Province when the temperature increased above $4^{\circ}C$ in winter season.

Electrochemical Characteristics of EDLCs with Selectivity Factors for the Organic Electrolyte (유기용매전해질에 따른 전기이중층캐패시터의 전기화학적 특성)

  • Lee, Sun-young;Ju, Jeh-Beak;Sohn, Tae-Won;Cho, Won-Il;Cho, Byung-Won
    • Journal of the Korean Electrochemical Society
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    • v.8 no.1
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    • pp.1-5
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    • 2005
  • Electric double layer capacitors(EDLCS) based on the charge stored at the interface between a hi팀 surface area carbon electrode and an organic electrolyte solution are widely used as a maintenance-free power source for IC memories and microcomputers. The achievement of the excellent performance of the capacitor requires an electrolyte solution which provides high conductivities over a wide temperature range and good electrochemical stabilities to allow the capacitor to be operated at high voltage. The electrochemical capacitor using a carbon material as electrodes and using an organic electrolyte with $1M-LiPF_6$ in PC-GBL-DEC(volume ratio 1:1:2) has specific capacitance of 64F/g.

Study on the Electrical Characterization of Inverted Staggered Pentacene Thin Film Transistor using Hydrogen Plasma Treatment (수소 플라즈마 처리를 이용한 역스테거드형 펜타센 트랜지스터의 전기적 특성 향상에 대한 연구)

  • 장재원;이주원;김재경;김영철;주병권
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.11
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    • pp.961-968
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    • 2003
  • In order to reach the high electrical quality of organic thin film transistors (OTFTs) such as high mobility and on-off current ratio, it is strongly desirable to study the enhancement of electrical properties in OTFTs. Here, we report the novel method of hydrogen plasma treatment to improve electrical properties in inverted staggered OTFTs based on pentacene as active layer. To certify the effect of this method, we compared the electrical properties of normal device as a reference with those of device using the novel method. In result, the normal device as a reference making no use of this method exhibited a field effect mobility of 0.055 $\textrm{cm}^2$/Vs, on/off current ratio of 10$^3$, threshold voltage of -4.5 V, and subthreshold slope of 7.6 V/dec. While the device using the novel method exhibited a field effect mobility of 0.174 $\textrm{cm}^2$/Vs, on/off current ratio of 10$\^$6/, threshold voltage of -0.5 V, and subthreshold slope of 1.49 V/dec. According to these results, we have found the electrical performances in inverted staggered pentacene TFT owing to this method are remarkably enhanced. So, this method plays a key role in highly improving the electric performance of OTFTs. Moreover, this method is the first time yet reported for any OTFTs.

Single Crystal Silicon Thin Film Transistor using 501 Wafer for the Switching Device of Top Emission Type AMOLEDs (SOI 웨이퍼를 이용한 Top emission 방식 AMOLEDs의 스위칭 소자용 단결정 실리콘 트랜지스터)

  • Chang, Jae-Won;Kim, Hoon;Shin, Kyeong-Sik;Kim, Jai-Kyeong;Ju, Byeong-Kwon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.4
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    • pp.292-297
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    • 2003
  • We fabricated a single crystal silicon thin film transistor for active matrix organic light emitting displays(AMOLEDs) using silicon on insulator wafer (SOI wafer). Poly crystal silicon thin film transistor(poly-Si TFT) Is actively researched and developed nowsdays for a pixel switching devices of AMOLEDs. However, poly-Si TFT has some disadvantages such as high off-state leakage currents and low field-effect mobility due to a trap of grain boundary in active channel. While single crystal silicon TFT has many advantages such as high field effect mobility, low off-state leakage currents, low power consumption because of the low threshold voltage and simultaneous integration of driving ICs on a substrate. In our experiment, we compared the property of poly-Si TFT with that of SOI TFT. Poly-Si TFT exhibited a field effect mobility of 34 $\textrm{cm}^2$/Vs, an off-state leakage current of about l${\times}$10$\^$-9/ A at the gate voltage of 10 V, a subthreshold slope of 0.5 V/dec and on/off ratio of 10$\^$-4/, a threshold voltage of 7.8 V. Otherwise, single crystal silicon TFT on SOI wafer exhibited a field effect mobility of 750 $\textrm{cm}^2$/Vs, an off-state leakage current of about 1${\times}$10$\^$-10/ A at the gate voltage of 10 V, a subthreshold slope of 0.59 V/dec and on/off ratio of 10$\^$7/, a threshold voltage of 6.75 V. So, we observed that the properties of single crystal silicon TFT using SOI wafer are better than those of Poly Si TFT. For the pixel driver in AMOLEDs, the best suitable pixel driver is single crystal silicon TFT using SOI wafer.