• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.12
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• pp.601-605
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• 2004

In this paper, we investigated ionic impurities and physical properties by change of carbon black content, which is asemiconductive material for underground power transmission. Specimens were made into sheet form with three existing resins and nine specimens for measurement. The ionic impurities of the specimens were measured using anICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer), and the density of specimens was measured by a density meter. Specific heat (Cp) was then measured using aDSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from 0[$^{\circ}C$] to 200[$^{\circ}C$], and heating temperature was 4[$^{\circ}C$/min]. Ionic impurities were measured to be high according to increases in the content of carbon black from this experimental result and density was also increased according to these properties. In particular, the impurity content values of A1 and A2, and existing resins, were measured at more than 4000[ppm]. Specific heat from the DSC results was lowered according to augmentation in the content of carbon black. The ionic impurities of carbon black containing Fe, Co, Mn, Al and Zn are forms of rapidly passed kinetic energy that increase the number of times breaking occurs during unit time with the near particles according to an increase in the vibration of particles by the applied heat energy.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.54 no.4
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• pp.149-153
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• 2005

We have investigated thermal properties showed by changing the content of carbon black which is the component parts of semiconductive shield in underground power transmission cable. Specimens were made of sheet with the nine of those for measurement. Heat capacity (${\Delta}$H), glass transition temperature (Tg) and melting temperature (Tm) were measured by DSC (Differential Scanning Calorimetry). The ranges of measurement temperature were from -100($^{\circ}C$) to 100($^{\circ}C$), and heating rate was 4($^{\circ}C$/min). And then thermal diffusivity was measured by LFA 447. The dimension of measurement temperature was 25[$^{\circ}C$]. Glass transition temperature of specimens was showed near -25[$^{\circ}C$] and the heat capacity and the melting temperature from the DSC results were simultaneously decreased according to increasing the content of carbon black, while thermal diffusivity was increased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.17 no.12
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• pp.1326-1331
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• 2004

In this paper, we have investigated thermal properties and Impurities content of specimens showing by changing the content of carbon black that is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens was measured by ICPAES(Inductively Coupled Plasma Atomic Emission Spectrometer). Heat capacity(ΔH) and melting temperature(Tm) were measured by DSC(Differential Scanning Calorimetry). The ranges of measurement temperature were from $0^{\circ}C$ to 20$0^{\circ}C$, and heating temperature was 4$^{\circ}C$/min. And then thermal diffusivity was measured by LFA 447. The measurement temperature was $25^{\circ}C$. Impurities content was highly measured according to increasing the content of carbon black from ICPAES results. And heat capacity and melting temperature from the DSC results were simultaneously decreased according to increasing the content of carbon black, while thermal diffusivity was increased according to increasing the content of carbon black. Because ionic impurities of carbon black containg Fe, Co, Mn, Al, and Zn were rapidly increasing kinetic energy by vibration of ionic impurities through the applied heat energy.

• The Transactions of the Korean Institute of Electrical Engineers C
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• v.53 no.9
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• pp.455-458
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• 2004

In this paper, we investigated impurities content and physical properties showing by changing the content of carbon black that is semiconductive materials for underground power transmission. Specimens were made of sheet form with the three of existing resins and the nine of specimens for measurement. Impurities content of specimens was measured by ICP-AES (Inductively Coupled Plasma Atomic Emission Spectrometer), and density of specimens were measured by density meter And then specific heat (Cp) was measured by DSC (Differential Scanning Calorimetry). A ranges of measurement temperature were from $0^{\circ}[C]$ to $200^{\circ}[C]$, and heating temperature was $4^{\circ}[C/min]$. Impurities content was highly measured according to increasing the content of carbon black from this experimental result, also density was increased according to these properties. Especially impurities content values of the Al and A2 of existing resins were measured more than 4000［ppm］. Specific heat from the DSC results was decreased according to increasing the content of carbon black. Because ionic impurities of carbon black having Fe, Co, Mn, Al and Zn are rapidly passed kinetic energy increasing the number of times breaking during the unit time with the near particles according to increasing vibration of particles by the applied heat energy.

• Journal of the Korean Institute of Gas
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• v.2 no.4
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• pp.18-24
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• 1998

Polyurethane (PU) synthesized from 4,4'-diphenylmethane diisocyanate having high functionality (f=2.9) and polyester polyol have been investigated by differential scanning calorimeter (DSC), dynamic mechanical thermal analyzer (DMTA), and Fourier transform infrared spectroscope (FT-IR). From the DSC measurement of polyurethane, a single transition temperature ($T_g$) was observed. This result indicates that polyurethanes synthesized in this work have homogeneous network structure due to high functionality of diisocyanate. It was also found that the $T_g$ of polyurethane was increased as hard segment content was increased. The results from DMTA measurement are consistent with DSC results. In order to investigate the effect of thermal annealing on the $T_g$ of polyurethane, the samples were annealed at various annealing conditions. $T_gs$ of polyurethanes were found to increased with annealing temperature. From swelling experiment and FT-IR studies, it was found that the $T_g$ was increased as crosslinking density of polyurethane was increased.

• Proceedings of the KSME Conference
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• 2001.06d
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• pp.226-231
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• 2001

The purpose of this paper is to propose the experimental method of thermal properties of Phase Change Materials (PCMs) by using T-history method. As far, in order to measure the heat of fusion and specific heat of PCMs, conventional thermal analysis methods such as DSC and DTA have been used. Because these methods test very small samples, thermal properties of samples are usually different from those of materials consisting of several components. For these reasons, T-history method, the simple measurement method of the heat of fusion and specific heat of PCMs have been performed. In this paper, we investigated the thermal properties of low temperature PCMs(below $0^{\circ}C$) under the charging process by using T-history method. The results are compared to those of DSC method. The T-history method will be useful for selection of the best PCM from lots of candidates and development of new PCMs.

• Journal of Advanced Marine Engineering and Technology
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• v.21 no.5
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• pp.482-490
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• 1997

The effects of strain amplitude. test temperature and stress on the fatigue properties for Ti-Ni wires were investigated using a rotary bending fatigue tester specially designed for wires. The fatigue test results were discussed in connection with the static tensile properties. The DSC measurement was conducted after fatigue test in order to clarify the change of transformation behavior due to the progress of fatigue. Under the temperature below or near the Af, the strain amplitude($\varepsilon_a$)-failure life (Nf) curve showed to be composed of three straight lines with two turning points. Of the 2 turning points, the upper one was coincident with the elastic limit strain and the lower one with the proportional limit strain. With rising of the test temperature above Af, the pattern of $\varepsilon_a$-Nf curve changed gradually to composition of 2 straight lines. The $\varepsilon_a$-Nf curve shifted depending on test temperature. In the short and medium life zones, the higher the temperature was, the shorter the fatigue life. However, in the long life zone, above the Af temperature, the fatigue life was not affected by the temperature. The transformation enthalpy measured after fatigue test was dependent on Nf, $\varepsilon_a$, and test temperature.

• Journal of Institute of Convergence Technology
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• v.4 no.2
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• pp.51-54
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• 2014

Energy storage not only reduces the mismatch between supply and demand but also improves the performance and reliability of energy systems. The different forms of energy that can be stored, including mechanical, electrical and thermal energy. Phase change materials (PCM) are latent heat storage materials. A large number of phase change materials (organic, inorganic and eutectic) are available in any required temperature range. We concentrated on eutectic materials and made a eutectic by mixing urea and choline chloride. Heat capacity ($C_p$) is one of the most important properties to be considered when a process is developed using the eutectic and currently DSC (Differential Scanning Calorimetry) has been proved as an effective technique to measure the heat capacity. This study focused on measuring heat capacity ($C_p$) of the mixing urea and choline chloride by DSC.

• Journal of the Korean Society of Safety
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• v.20 no.3 s.71
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• pp.27-33
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• 2005

The shape memory effect in Ti-50.4at.%Ni alloy after solution treatment at 1273K for 2h and aged at 350, 450, $550^{\circ}C$ for 0.5, 1, 1.5, 2, 4, 10hrs had been investigated by differential scanning calorimetry measurement. It was found that ageing in the temperature range of $350^{\circ}C{\sim}550^{\cric}C$ induced complex transformation behavior, involving the R-phase and multiple-stage martensitic transformation. Usually aged Ni-rich NiTi alloys undergo martensitic transformation on cooling from high temperatures in two step : Austenite to R-phase and then R-phase to Martensite (normal behavior). In sample aged at $350^{\circ}C$ two distinct DSC peaks arised giving evidence of intermediate stages of martensite transformation. This results in the nucleation and growth of coherent $Ni_4Ti_3$-precipitate. These explain all features of the evolution of DSC charts during ageing including the number of distinct DS peaks and their positions.

• Korean Chemical Engineering Research
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• v.48 no.1
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• pp.93-97
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• 2010

In this study, we have measured the thermo-physical properties of pure organic phase change materials (PCMs) and their mixtures which have the melting points from 0 to $15^{\circ}C$ by using a modified T-history method. These organic PCMs can be used as coolant materials for packaging and shipping of vaccines. Through measuring the thermophysical properties of pure paraffins, we were able to know that we could improve the reliability of measurement if we considered the melting point of each material and subsequently decided an optimum coolant temperature for each system. The modified T-history method showed a potential usefulness for reliably measuring thermo-physical properties of organic mixtures with avoiding possible inaccuracy of measurement due to using a small amount of sample at DSC measurement.