• 한국공작기계학회논문집
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• 제14권5호
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• pp.80-86
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• 2005

High velocity oxy-fuel thermally sprayed coating of the WC-Co cermet material is a well-established process for modifying the surface properties of the structural components exposed to the corrosive and wear attacks. The hard WC phase in the coating resists to the wear while the soft metallic Co increases the adhesive and cohesive bonding properties. The coating properties deposited by the HVOF process are greatly dependent on the feedstock materials and processing parameters. The effects of the feedstock material and process coating parameters including the in-flight particle parameters and resultant coating microstructures were observed in this paper.

• 한국환경보건학회지
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• 제30권2호
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• pp.115-122
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• 2004

A glassy carbon electrode(GCE) modified with nafion-DTPA (diethylene triamine-pentaacetic acid)-glycerol is used for the highly selective and sensitive determination of a trace amount of Cu(II). Various experimental parameters, which influenced the response of nafion-DTPA-glycerol modified electrode to Cu(II), are optimized. The Copper(II) is accumulated on the electrode surface by the formation of the complex in an open circuit, and the resulting surface is characterized by medium exchange, electrochemical reduction, and differential pulse voltammetry(DPV). The electrochemical response is evaluated with respect to concentration of modifier, pH and preconcentration time, quiet time, copper(II) concentration, and other variables. A linear range is obtained in the concentration range 1.0${\times}$10$^{-8}$ M-1.0${\times}$10$^{-6}$ MCu(II) with 7 min preconcentration time. The detection limit(3s) is as low as 2.36${\times}$10$^{-8}$ M (1.50 ppb).

• Bulletin of the Korean Chemical Society
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• 제31권12호
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• pp.3632-3638
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• 2010

2-Iminopyrimidines (1a-e) and 2-thioxopyrimidine (2) were synthesized using the Biginelli three component cyclocondensation reaction of an appropriate $\beta$-diketone, arylaldehyde, and guanidine (for 1a-e) or thiourea (for 2). The electrochemical properties of the novel systems were investigated by CV and DPV. Moreover, B3LYP/6-31G(d,p) method was applied to the present structures in order to gather some structural and physicochemical data.

• 정보보호학회논문지
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• 제13권1호
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• pp.59-67
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• 2003

공개키 인증서와 마찬가지로 속성 인증서 역시 신뢰되기 위해서는 인증서에 대한 유효성 여부를 검증 받아야 한다. 속성 인증서의 유효성 검증은 속성 인증서 체인과 그 체인에 존재하는 각 개체들의 공개키 인증서 체인에 대해 유효성 여부를 검사함으로써 이루어진다. 이렇듯 속성 인증서의 유효성 확인은 공개키 인증서보다 더 복잡하고 많은 처리 과정을 거치게 된다. 이러한 검증 과정은 서비스제공 서버에게는 많은 부담이 될 수 있다. 본 논문에서는 속성인증서 검증을 효과적으로 대신 할 수 있도록 전문화된 검증 서버의 사용을 제안하고 검증 서버와 클라이언트간에 사용될 검증 프로토콜을 정의한다.

• 전기화학회지
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• 제14권3호
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• pp.131-137
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• 2011

[ $LiMn_2O_4$ ] $Mn^{2+}$이온 용출현상 연구를 위한 간단하고 신속한 전기화학적 $Mn^{2+}$이온 분석법을 정립하였다. 이 분석법은 완충용액에서 $Mn^{2+}$이온이 $Mn^{4+}(MnO_2)$로 산화되는 원리를 이용한다. 최적조건 (pH 8.9 0.04 M $NH_3-NH_4Cl$ 완충용액 및 glassy carbon 작업전극)에서, Linear sweep voltammetry(LSV) 측정에 대해 $5{\mu}M-100{\mu}M$ (0.275-5.5 ppm) $Mn^{2+}$이온 범위에서, differential pulse voltammetry (DPV) 측정에 대해 $0.2{\mu}M-10{\mu}M$ (0.011-0.55 ppm) 범위에서 선형적 응답 특성을 확인하였다. 또한, 측정용액에 리튬 이차전지용 전해액 ($LiPF_6$, EC, EMC)이 첨가할 경우, 첨가량에 비례하여 $Mn^{2+}$ 이온의 산화 전류 감소하였는데, 이러한 감소의 주요 원인은 EMC보다는 $LiPF_6$와 EC성분임을 확인하였다.

• 분석과학
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• 제10권6호
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• pp.427-432
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• 1997

도데실황산나트륨(SDS)이 수식된 유리탄소전극에 의해 철(III) 이온의 정량분석이 선택성 있게 제안되었다. 이것은 SDS와 $Fe^{3+}$의 정전기적 인력으로 착물이 형성되는 데 근거한 것이다. 철(III) 이온의 정량분석은 시차펄스전압전류법(DPV)에 의해 하였고, 그 정량분석을 위한 $(DS^-)_n-Fe^{3+}$의 환원 피크는 +0.466(${\pm}0.002$)volt (vs. Ag/AgCl)였다. 철(III) 이온의 정랑분석을 위한 검량선은 $0.50{\times}10^{-5}{\sim}10{\times}10^{-5}mol/L$의 농도 범위에서 얻었으며, 검출한계는 $0.14{\times}10^{-5}mol/L$였다. $Cu^{2+}$, $Ni^{2+}$, $Co^{2+}$, $Pb^{2+}$, $Zn^{2+}$ 및 $Mn^{2+}$는 철(III) 이온의 정량에 거의 영향을 미치지 않으나, $CN^- $ 및 $SCN^-$은 철(III) 이온의 정량을 크게 방해하였다.

• Bulletin of the Korean Chemical Society
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• 제33권5호
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• pp.1485-1490
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• 2012

An electrochemical immunoassay based on osmium-hippuric acid (HA) conjugate films onto the electrode is presented for the detection of urinary HA. This is the first report on the use of the oxidative electropolymerization of 5-amino-1,10-phenanthroline (5-$NH_2$-phen) for immobilizing an antigen, osmium-conjugated HA. As a redox mediator, [Os(5-amino-1,10-phenanthroline)$_2$(4-aminomethylpyridine-HA)Cl]$^{+/2+}$ (Os-phen-HA) was successfully synthesized and electropolymerized onto the screen-printed carbon electrodes (SPCEs). The interaction between osmium-HA conjugate films and antibody-HA ($anti$-HA) was performed by cyclic voltammetry (CV) and differential pulse voltammetry (DPV). The electrical signals were linearly proportional to urinary HA in the range of 0.1-5.0 mg/mL, which is sufficient for use as an immunosensor using a cutoff concentration of 2.0 mg/mL in urine samples. The proposed electrochemical immunoassay method can be extended to various applications for detecting a wide range of different small antigens in the health care area.

• Bulletin of the Korean Chemical Society
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• 제32권4호
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• pp.1215-1220
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• 2011

An electrochemically-modified electrode [P(EDOP-SWNTs)/GCE] was prepared by electropolymerization of 3,4-ethylenedioxy pyrrole (EDOP) single-walled carbon nanotubes (SWNTs) on the surface of a glassy carbon electrode (GCE) and characterized by SEM, CV, and DPV. This modified electrode was employed as an electrochemical biosensor for the selective determination of serotonin concentrations at pH 7.4 and exhibited a typical enhanced effect on the current response of serotonin with a lower oxidation overpotential. The linear response was in the range of $1.0{\times}10^{-7}$ to $1.0{\times}10^{-5}$ M, with a correlation coefficient of 0.998 on the anodic current. The lower detection limit was calculated as 5.0 nM. Due to the relatively low currents and difference of potentials in the electrochemical responses of uric acid (UA), ascorbic acid (AA), and dopamine (DA), the modified electrode was a useful and effective sensing device for the selective and sensitive serotonin determination in the presence of UA, AA, and DA.

• Journal of Electrochemical Science and Technology
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• 제3권2호
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• pp.90-94
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• 2012

A simple and sensitive electrochemical sensor for simultaneous and quantitative detection of ranitidine (RT) and metronidazole (MT) was developed, based on a poly(thionine)-modified anodized glassy carbon electrode (PTH/GCE). The modified electrode showed the excellent electrocatalytic activity towards the reduction of both RT and MT in 0.1M phosphate buffer solution (PBS, pH 7.0). The peak-to-peak separations (${\Delta}E_p$) for the simultaneous detection of RT and MT between the two reduction waves in CV and DPV were increased significantly from ca. 100 mV at anodized GCE, to ca. 550 mV at the PTH/GCE. The reduction peak currents of RT and MT were linear over the range from 35 to $500{\mu}M$ in the presence of 200 and $150{\mu}M$ of RT and MT, respectively. The sensor showed the sensitivity of 0.58 and $0.78{\mu}A/cm^2/{\mu}M$ with the detection limits (S/N = 3) of 1.5 and $0.96{\mu}M$, respectively for RT and MT.

• 한국환경보건학회지
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• 제29권2호
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• pp.62-68
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• 2003

Differential pulse voltammetry (DPV) using nafion-coated glassy carbon electrodes modified with Tetren(tetraethylene pentamine)-glycerol showed sensitivity for determining lead (II) at low concentration. The Lead (II) was accumulated on the electrode surface by the formation of the complex in an open circuit, and the resulting surface was characterized by medium exchange, electrochemical reduction, and differential pulse voltammetry. Various experimental parameters, such as the composition of modifier, preconcentration time, pH of electrolyte (0.1 M acetate buffer), and parameters of differential pulse voltammetry, were optimized. The initial potential was applied for 50 s, the electrode was scanned from -0.9 to -0.3 V, and the anodic peak current was measured at -0.604 V $\pm$ 0.015 V (vs. Ag/AgCl). The calibration plot was obtained in the range 1.0$\times$10$^{-8}$ M~l.0$\times$10$^{-6}$ M with pH 4.5 buffer solution. The detection limit (3$\sigma$) it as low as 5.0$\times$ 10$^{-9}$ M. This method is applied to the determination of lead(II) in a certified reference material and the result agrees satisfactorily with the certified value.