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Effect of the Length of Side Group Substitution on Optical and Electroluminescene Properties

  • Shin, Hwangyu;Kang, Hyeonmi;Kim, Beomjin;Park, Youngil;Yu, Young-Jun;Park, Jongwook
    • Bulletin of the Korean Chemical Society
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    • v.35 no.10
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    • pp.3041-3046
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    • 2014
  • Blue emitting materials, 9,10-bis-biphenyl-4-yl-anthracene (AC-P), 9,10-bis-[1,1';4',1"]terphenyl-4-yl-anthracene (AC-DP), and 9,10-bis[3",5"-deiphenyltriphenyl-4'-yl]anthracene (AC-TP) were synthesized through boration and Suzuki aryl-aryl coupling reaction. EL performance of blue light-emitters was optimized and improved by varying the chemical structures of the side groups. In the thin film state, the three materials exhibit $PL_{max}$ values in the range of 442-456 nm. EL device with the synthesized compounds in the following configuration was fabricated: ITO/4,4',4"-tris(N-(2-naphthyl)-N-phenylamino)triphenylamine (2-TNATA) 60nm/N,N'-bis (naphthalene-1-yl)-N,N'-bis(phenyl)benzidine (NPB) 15nm/synthesized blue emitting materials (30nm)/1,3,5-tri(1-phenyl-1H-benzo[d]imidazol-2-yl)phenyl (TPBi) 20nm/LiF 1nm/Al 200nm. The current efficiency and C.I.E. value of AC-TP were 3.87 cd/A and (0.15, 0.12). A bulky and non-planar side group helps to prevent ${\pi}-{\pi}^*$ stacking interaction, which should lead to the formation of more reliable amorphous film. This is expected to have a positive effect on the high efficiency of the operating OLED device.

A Study on Speech Recognition in a Running Automobile (주행중인 자동차 환경에서의 음성인식 연구)

  • 양진우;김순협
    • The Journal of the Acoustical Society of Korea
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    • v.19 no.5
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    • pp.3-8
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    • 2000
  • In this paper, we studied design and implementation of a robust speech recognition system in noisy car environment. The reference pattern used in the system is DMS(Dynamic Multi-Section). Two separate acoustic models, which are selected automatically depending on the noisy car environment for the speech in a car moving at below 80km/h and over 80km/h are proposed. PLP(Perceptual Linear Predictive) of order 13 is used for the feature vector and OSDP (One-Stage Dynamic Programming) is used for decoding. The system also has the function of editing the phone-book for voice dialing. The system yields a recognition rate of 89.75% for male speakers in SI (speaker independent) mode in a car running on a cemented express way at over 80km/h with a vocabulary of 33 words. The system also yields a recognition rate of 92.29% for male speakers in SI mode in a car running on a paved express way at over 80km/h.

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4-Arm Star Shaped and Linear Block Copolymers for Copper Phthalocyanine Dispersion (4-Arm 스타형과 선형 블록 공중합체의 구리 프탈로시아닌 분산 연구)

  • Kim, Byoungjae;Jeong, Jonghwa;Jung, Ji-Hye;Kim, Bong-Soo;Jung, Ki-Suck;Paik, Hyun-Jong
    • Polymer(Korea)
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    • v.38 no.5
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    • pp.671-675
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    • 2014
  • Well-defined star shaped and linear block copolymers were synthesized to study the dispersion stability of copper phthalocyanine (CuPc). We synthesized dispersants using (2-dimethylamino) ethyl methacrylate (DMAEMA) and poly(ethylene glycol) methyl ether methacrylate) (PEGMA) by activators generated by electron transfer (AGET) atom transfer radical polymerization (ATRP). pDMAEMA-b-pPEGMA copolymers were characterized by GPC and NMR. Furthermore, we studied the effect of the dispersion stability of copper phthalocyanine by controlling the degree of polymerization of PEGMA as a stabilizing group. The 4-arm star shaped polymeric dispersant showed better dispersion stability of CuPc at $25^{\circ}C$ for 7 days.

Indoor Air Quality of Acidic Air Pollutants at a Private House in Seoul During the Spring Months

  • Lee, Hak-Sung;Kang, Byung-Wook;Kang, Choong-Min;Yeo, Hyun-Gu
    • Journal of Korean Society for Atmospheric Environment
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    • v.17 no.E3
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    • pp.109-115
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    • 2001
  • Acidic air pollutants were collected to characterize indoor air quality at a private house in Seoul during the spring period. All indoor and outdoor samples were measured simultaneously using an annular denuder system. The data set was collected on twelve different days with a 24-hr sampling period in April and May 1997. The chemical species measured were HN $O_3$, HN $O_2$, S $O_2$ and N $H_3$in the gas phase and P $M_{2.5}$ (dp 2.5 ${\mu}{\textrm}{m}$), S $O_4$$^{2-}$, N $O_3$$^{[-10]}$ and N $H_4$$^{+}$ in the particulate phase. Indoor concentrations of HN $O_2$, N $H_3$, and P $M_{2.5}$ were greater than outdoor levels. However, indoor concentrations of HN $O_3$, S $O_2$, N $O_3$$^{[-10]}$ and N $H_4$$^{+}$ were less than those found from outdoors. In the case of S $O_4$$^{2-}$, the indoor and outdoor concentrations were similar. Indoor concentrations of P $M_{2.5}$ , S $O_4$$^{2-}$ and N $O_3$$^{[-10]}$ were dependent upon the outdoor concentrations. A tracer-gas decay technique with sulfur hexafluoride (S $F_{6}$ ) as the tracer gas was used to estimate the air exchange rate of a private home in the spring. The average air exchange rate was computed to be 2.87 h $r^{-1}$ .X> .

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A Comparative Study on the Colors of Chinese Traditional Costume in Tang, Song, Yuan, Ming, and Qing Dynasty (중국의 당.송.원.명.청 왕조 복식의 색채에 관한 비교연구)

  • Jendan, Jendan;Lee, Youn-Soon
    • Journal of the Korea Fashion and Costume Design Association
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    • v.14 no.4
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    • pp.63-72
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    • 2012
  • In this study, Characteristics of colors on Chinese traditional costume in Tang, Song, Yuan, Ming, and Qing Dynasty were compared. And general colors of Chinese traditional costume and the viewpoint of them were considered. The purpose of this study were to apt colors of Chinese traditional costumes to the sensory appetite of modern people for new things, and make the recreation inspired by new senses be applied into the fashion industry effectively. The results were as followed : Firstly, colors distribution of 5 dynasties were different. In the Tang, R(red) was highest, YR(yellow red) and Y(yellow) followed. In the Song, YR was highest, Y and R followed and PB(purple blue) was increased, In the Yuan, R, YR, PB, B were concentrated at low rates, and other colors were increased, In the Ming, Y, R and B were concentrated at low rates orderly, and other colors were increased, In the Qing, PB was highest and Y, R, YR, B, P(purple) were increased. Secondly, tons distribution of 5 dynasties were different. In the Tang, L(light) was highest, P(pale) and Lgr(light grayish) followed. In the Song, P(pale) was highest, Lgr, Gr(grayish) and Dl(dull) followed In the Yuan, Dp(deep) was highest, P and Lgr followed, and other tones were increased, In the Ming, S(strong) was highest, DI and V(vivid) followed. Thirdly, The general colors of 5 dynasty were R, YR, Y, B, PB colors with vivid, deep and light tones. Forth, the viewpoint of color on Chinese traditional costume was based on the Yin-Yang and the Five Elements theory. Based on results of this study, the successive researches will be carried out about the unique colors of each nation and application traditional colors to modern fashion industry in order to the unique cultural sense.

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THE PUBERTAL GROWTH SPURT AND SKELETAL MATURITY STAGES OF THE HAND-AND-WRIST IN NORMAL OCCLUSION (정상교합자의 사춘기성장과 수완부골 성숙단계에 관한 연구)

  • Park, Jin-Sung;Suhr, Cheong Hoon
    • The korean journal of orthodontics
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    • v.15 no.2
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    • pp.197-209
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    • 1985
  • To investigate the relationship between the pubertal spurt in body height and bone maturity of the hand-and-wrist in normal occlusion, the author X-rayed the hand-and-wrists of 1,141 students (male 614, female 527) and assessed their bone maturity. In this study, eleven skeletal stages were selected. The bones used to determine skeletal maturity were the ulnar sesamoid of the metacarpophalangeal joint of the first finger, the epiphyses of the proximal, middle, distal phalanges of the third finger, and middle phalanx of the fifth finger, and distal epiphysis of the radius. From the longitudinal data for height, an assessment was made of the change in growth velocity. The pubertal growth stage was divided into onset and peak height velocity phases. The results were as follows; 1. The onset of the pubertal growth was between the $PP_3=\;and\;MP_3=$ stage for boys, and between the $MP_3=\;and\;MP_5=$ stage for girls; the mean age of onset was 10.6 years for boys and 9.0 years for girls. 2. The peak height velocity was between the S and $MP_{3_{cap}}$ stage for boys, and between the $MP_{3_{cap}}$ and $MP_{5_{cap}}$ stage for girls; the mom age of peak height velocity was 12.5 years for boys and 10.9 years for girls. 3. As the stages of bone maturity progressed from $DP_{3u},\;to\;PP_{3u},\;MP_{3u}$, Ru, the peak height velocity had been reached, and the growth rate retarded, therefore the approach to full physical maturity was attained. 4. The evidence for the period of onset, peak height velocity and bone maturation suggested that girls were in advance of boys. During the latter part of pubertal growth, the rate of boys' bone maturation was faster than that of girls'.

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Electrical Characteristics on MOS Structure with Irradiation of Radiation (방사선이 조사된 MOS구조에서의 전기적 특성)

  • 임규성;고석웅;정학기
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2001.10a
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    • pp.644-647
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    • 2001
  • The investigations were discussed on the radiation effects of the electrical properties to the p-type MOS capacitors, which were irradiated by cobalt-60 gamma ray sources. The characteristics of capacitance-bias voltage(C-V) and of dielectric dissipation tarter-bias voltage(D-V) on the capacitors were measured at 1 [MHz] frequency. The microscopic behaviors of spate charges in oxide and silicon-silicon dioxide(Si- $SiO_2$) interface were investigated from the experimental data. The C-V characteristics are statical and convenient for the evaluation of the steady state behavior of carriers and interface states characteristics. While, the distribution and magnitude of space charges in oxide can be found out accurately on the $V_{dp}$ in D-V curves. The density of interface states can be deduced with ease from the magnitude of D-peak at depletion state. Thus, it is also concluded that the D-V curves are more useful and easier than conventional C-V curves for analysis of the microscopic and dynamic behavior of carriers in oxide and Si- $SiO_2$interface.

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Multihop Connection Establishment Algorithms in Wavelength-Routed Optical Networks (파장분할다중화방식 전광통신망에서 다중홉 연결 알고리즘)

  • 김상완;서승우
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.25 no.7A
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    • pp.951-958
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    • 2000
  • In wavelength-routed all-optical networks, signals are transmitted on a direct optical path, or a lightpath, in a single-hop manner without opto-electronic/electro-optic(OE/EO) conversion at intermediate nodes. However, due to the physical constraints of optical elements such as ASE noise and crosstalk signals can be degraded un a long path. To establish a connection under such impairments, the optical signal may need to be regenerated at intermediate nodes, dividing a lightpath into two or more fragments. However, since signal regeneration at intermediate nodes requires additional network resources, the selection of these nodes should be made carefully to minimize blocking of other lightpaths. In this paper, we deal with the problem of establishing a lightpath in a multihop manner under physical constraints. We provide both minimal-cost and heuristic algorithms for locating signal regeneration nodes(SRNs). For a minimal-cost algorithm, we formulate the problem using dynamic programming(DP) such that blocking of other lightpaths due to the lack of transmitters/receivers(TXs/RXs) and wavelengths is minimized throughout the network.

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O1igosaccharide Formation and Production of Transfructosylase and Transglucosylase by Aureobasidium pullulans (Aureobasidium pullulans가 생산하는 과당 및 포도당 전이효소에 의한 올리고당류의 생산)

  • 윤종원;윤태경한성범송승구
    • KSBB Journal
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    • v.9 no.2
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    • pp.133-139
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    • 1994
  • Oligosaccharide formation and the production of transfructosylase and transglucosylase by Aureobasidium pullulans were studied in sucrose or maltose media, respectively. The initial uptake rates of substrate in sucrose-rich media were faster than that in maltose-rich media, also most parts of oligosaccharides formed and other monosaccharides released were utilized progressively as substrate during the cultivation periods. However, when the initial amount of sucrose was raised to $100g/\ell$, high concentration of monosaccharides were liberated, consequently high-level fructose was accumulated unused during fermentation. The biggest molecule of oligosaccharide synthesized was hexasaccharide in all cultivation media examined, of which the organism could not utilize isomalto-oligosaccharide of DP6 synthesized in a maltose-rich medium. The maximum amount of oligosaccharides produced was $58g/\ell$ when $100g/\ell$ of sucrose and $5g/\ell$ of maltose were used as initial substrate. From the early stage of growth both fructooligosaccharides and isomalto-oligosaccharides were synthesized and progressively utilized as substrates during the fermentation. Based on the experimental results, it was suggested that maltose could induce both transfructosylase and transg1ucosylase, whereas sucrose was unable to slimulate transglucosylase formation.

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A Structural Approach to On-line Signature Verification (구조적 접근방식의 온라인 자동 서명 겁증 기법)

  • Kim, Seong-Hoon
    • Journal of the Korea Society of Computer and Information
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    • v.10 no.4 s.36
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    • pp.385-396
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    • 2005
  • In this paper, a new structural approach to on-line signature verification is presented. A primitive pattern is defined as a part segmented by a local minimal position of speed. And a structural description of signature is composed of subpatterns which are defined as such forms as rotation shape, cusp shape and bell shape, acquired by composition of the primitives regarding the directional changes. As the matching method to find identical parts between two signatures, a modified DP(dynamic programming) matching algorithm is presented. And also, variation and complexity of local parts are computed from the training samples, and reference model and decision boundary are derived from these. Error rate, execution time and memory usage are compared among the functional approach, the parametric approach and the proposed structural approach. It is found that the average error rate can be reduced from 14.2% to 4.05% when the local parts of a signature are weighted and the complexity is used as a factor of decision threshold. Though the error rate is similar to that of functional approaches. time consumption and memory usage of the proposed structural approach are shown to be very effective.

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