• 제목/요약/키워드: DMPC monolayer

검색결과 17건 처리시간 0.019초

DMPC 단분자막의 변위전류 특성 연구 (A Study on Displacement Current DMPC Monolayer)

  • 최용성;조장훈;송진원;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 Vol.19
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    • pp.168-169
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    • 2006
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. The phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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DMPC 인지질 단분자막의 변위전류 특성 연구 (II) (A Study on Displacement Current Characteristics of DMPC Monolayer (II))

  • 송진원;이경섭;최용성
    • 전기학회논문지
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    • 제56권2호
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    • pp.343-348
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    • 2007
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. Lipid thin films were deposited by accumulation and the current was measured after the electric bias across the manufactured MIM device. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area. When electric bias is applied across the manufactured MIM device by the deposition condition of phospolipid mono-layer, it wasn't breakdown when the higher electric field to impress by increase of deposition layers.

DMPC 인지질 단분자막의 변위전류 특성 (Displacement Current Characteristics of DMPC Lipid Monolayer)

  • 최용성;송진원;이경섭
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 2006년도 추계학술대회 논문집 전기물성,응용부문
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    • pp.12-13
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    • 2006
  • The physical properties of DMPC monolayer were made for dielectric relaxation phenomena by the detection of the surface pressures and displacements current. The current was measured after the electric bias across the manufactured MIM device. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area. When electric bias is applied across the manufactured MIM device by the deposition condition of phospolipid mono-layer, it wasn't breakdown when the higher electric field to impress by increase of deposition layers.

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아조벤젠기를 가진 지방산과 인지질 혼합 LB막의 전기화학적 특성 (Electrochemical Properties of Mixture Langmuir-Blogett Films of Fatty Acid containing Azobenzene and Phospholipid)

  • 박근호;최성현
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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    • pp.920-923
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    • 2004
  • We have investgated on the monolayer LB film of BASH-DMPC mixture on an ITO for the photoisomerization by light irradiation. We measured electrochemical properties by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution at a variable concentration and monolayer LB films. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of 8A5H-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

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나노기술을 위한 DMPC 유기박막의 유전완화특성 (Dielectric Relaxation Properties of DMPC Organic Thin Films for Nanotechnology)

  • 최영일;조수영
    • 전자공학회논문지 IE
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    • 제49권1호
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    • pp.7-11
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    • 2012
  • 본 논문에서는 인지질 단분자인 DMPC 유기초박막에 압력 자극을 이용하여 표면압과 변위전류의 검출에 따른 유전 완화현상에 대한 물리적 특성 평가를 하였다. 유기초박막에서 약간의 유전 완화 시간이 소요되었는데 이는 분자 영역에 의존한다는 사실을 알 수 있었다. 또한, 유기박막의 누적 조건에 의해 제작된 MIM 소자에 전압을 인가시, LB막의 누적층수가 증가 할수록 저항이 증가한다는 것을 알 수 있었는데 이는 유기초박막의 층수가 증가하여 전극간의 거리가 멀어질수록 더 높은 전계에서도 파괴되지 않는 절연특성이 나타남을 알 수 있었으며 나노단위의 유기초박막의 비교적 양호한 절연성을 확인, 제시 하였다.

스테아르산과 인지질 혼합물의 농도변화에 대한 유기초박막의 안정성에 관한 연구 (A Study on the Stability of Ultra-Thin Film Mixed with Stearic Acid and Phospholipid)

  • 박근호
    • 한국응용과학기술학회지
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    • 제32권4호
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    • pp.789-794
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    • 2015
  • 스테아르산과 인지질혼합물의 농도변화에 띠르는 유기초박막에 대한 안정성을 조사하였다. 스테아르산과 인지질 혼합물 유기초박막은 ITO glass에 LB법을 사용하여 제막하였다. 전기화학적 특성은 $NaClO_4$ 용액에서 3 전극 시스템으로 순환전압전류법을 사용하여 초기 1650 mV에서 최종 퍼텐셜 -1350 mV 까지 측정하였다. 그 결과 스테아르산과 인지질의 혼합물 유기초막은 순환전압전류도표로부터 산화전류로 인한 비가역공정으로 나타났다. 스테아르산과 인지질혼합물 LB막(몰비 1:1, 1:2, 1:3)에서 확산계수(D)는 $0.01N\;NaClO_4$에서 각각 $1.4{\times}10^{-3}$, $1.7{\times}10^{-3}$$1.6{\times}10^{-3}(cm^2/s)$로 산출되었다.

포화지방산과 인지질(DMPC)혼합 Langmuir-Blodgett막의 전기화학적 특성에 관한 연구 (A Study on the Electrochemical Properties of Langmuir-Blodgett Film Mixed with Saturated Fatty Acid and Phospholipid(DMPC))

  • 우성협;박근호
    • 한국응용과학기술학회지
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    • 제31권3호
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    • pp.359-366
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    • 2014
  • 포화지방산과 인지질(DMPC)혼합 LB막에 대한 전기화학적 특성을 조사하였다. 포화지방산과 DMPC 혼합 단분자 LB막은 ITO glass에 Langmuir-Blodgett법을 사용하여 제막하였다. 전기화학적 특성은 $NaClO_4$ 용액에서 3 전극 시스템 (Ag/AgCl 기준전극, 백금선 카운터 전극 및 LB 필름이 코팅된 ITO 작업 전극)으로 순환전압전류법을 사용하여 측정하였다. 그 결과 포화지방산과 인지질(DMPC)의 LB막은 순환전압전류도표로부터 산화전류로 인한 비가역공정으로 나타났다. 포화지방산과 인지질(DMPC)혼합(몰비 1:1) LB막(C14, C16, C18, C20)에서 확산계수(D)는 0.05 N $NaClO_4$에서 각각 $1.2{\times}10^{-3}$, $2.1{\times}10^{-3}$, $1.4{\times}10^{-4}$$1.1{\times}10^{-3}cm^2/s$로 산출되었다.

나노기술을 위한 유기초박막의 유전완화특성 (Dielectric Relaxation Properties of Organic Ultra Thin Films for Nanotechnology)

  • 조수영;송진원;이경섭
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집
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    • pp.9-13
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    • 2004
  • In this paper, evaluation of physical properties about dielectric relaxation phenomena by the detection of the surface pressures and displacements current on the monolayer films of phospolipid monomolecular DLPC, DMPC using pressure stimulus. As a result, the changed surface pressure, displacement current and the transition forms of dipole moment of phospolipid monomolecular in area per molecular by pressure stimulus were conformed well. It was known that the monolayers by linear relationship for decision of dielectric relaxation time between compressure speed and molecule area By according to the linear relationship relation get that frictional constant, DLPC was $1.89{\times}10^{-19}$[Js] and DMPC was $0.722{\times}10^{-19}$[Js]. It is found that the phospolipid monolayer of dielectric relaxation takes a little time and depend on the molecular area.

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아조벤젠기를 가진 지방산과 $L-{\alpha}-dimyristoylphosphatidylcholine$ 혼합 LB막의 전기화학적 특성 (Electrochemical Properties of Langmuir-Blodgett(LB) Films of Fatty Acid Containing Azobenzene and $L-{\alpha}-dimyristoylphosphatidylcholine$ Mixture)

  • 박근호;최성현;송주영
    • 한국응용과학기술학회지
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    • 제22권4호
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    • pp.315-322
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    • 2005
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with 4-octyl-4'-(5-carboxylpentamethyleneoxy)azobenzene (denoted as 8A5H) and $phospholipid(L-{\alpha}-dimyristoylphosphatidylcholine$, denoted as DMPC). LB films of 8A5H monolayer and 8A5H-DMPC were deposited by using the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by using cyclic voltammetry with a three_electrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0mol/L) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rates were 50, 100, 150 and 200mV/s, respectively. As a result, LB films of 8A5H monolayer appeared irreversible process caused by only the oxidation current from the cyclic voltammogram and LB films of 8A5H-DMPC mixture were found to be caused by a reversible oxidation-reduction process.

유기초박막의 산화-환원 반응에 관한 연구 (A Study on the Oxidation-reduction Reaction of Organic Thin Films)

  • 박근호;송주영
    • 한국전기전자재료학회논문지
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    • 제19권8호
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    • pp.724-731
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    • 2006
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with 4-octyl-4'-(5-carboxylpentamethyleneoxy)azobenzene (denoted as 8A5H) and phospholipid(L-a-dimyristoylphosphatidylcholine, denoted as DMPC and L-a-dilauroylphosphayidylcholine, denoted as DLPC). The LB films of 8A5H, 8A5H-DMPC and 8A5H-DLPC mixture monolayers were deposited by using the LB method on the indium tin oxide(ITO) glass. The electrochemical properties measured by using cyclic voltammetry with a three-electrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0 mol/L) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rates were 50, 100, 150 and 200 mV/s, respectively. As a result, LB films of 8A5H and 8A5H-DLPC mixture monolayers appeared irreversible process caused by only the oxidation current from the cyclic voltammogram and LB films of 8A5H-DMPC monolayer mixture was found to be caused by a reversible oxidation-reduction process.