• Bulletin of the Korean Chemical Society
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• v.23 no.6
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• pp.803-807
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• 2002

The conversion of dimethyl ether(DME) has been carried out over $\gamma-alumina$, silica-alumina, and modified $\gamma-aluminal$ catalysts. Especially, the water effect has been investigated on purpose to develop a suitable catalyst for one-step synthesis of DME from $CO_2$ hydrgenation, The $\gamma-Al_2O_3$ modified with 1 wt% silica is more active and less deactivated by water than unmodified one. $CO_2has$ no effect on catalytic dehydration of methanol to DME.

• Journal of Korean Society for Atmospheric Environment
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• v.22 no.1
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• pp.53-61
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• 2006

Recently, lots of researchers have been attracted to develop various alternative fuels and to use renewable fuels in order to solve the exhaust emission problems. DME (Dimethylether) is synthetic fuel, and can be produced from natural gas, coal and biomass. The emission is clean because it contains little sulfur and aromatic components In this study, the fuel was tested to investigate the applicability as an alternative fuel for diesel. This study was carried out by comparing the exhaust emissions and performance of diesel engine with DME, ULSD (ultra low sulfur diesel), LSD (low sulfur diesel) respectively. In order to measure regulated emissions, CO, $NO_{3}$, HC from vehicle different fuel types were used on chassis dynamometer CVS (constant volume sampler)-75 mode and EPA TO-I1A method was chosen for aldehydes analysis.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.12
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• pp.1017-1024
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• 2006

In this work, pool boiling heat transfer coefficients (HTCs) of five hydrocarbon refrigerants of propylene, propane, isobutane, butane and dimethylether (DME) were measured at the liquid temperature of $7^{\circ}C$ on a 26 fpi low fin tube, Turbo-B, and Thermoexcel-E tubes. All data were taken from 80 to $10kW/m^2$ in the decreasing order of heat flux. The data of hydrocarbon refrigerants showed a typical trend that nucleate boiling HTCs obtained on enhanced tubes also increase with the vapor pressure. Fluids with lower reduced pressure such as DME, isobutane, and butane took more advantage of the heat transfer enhancement mechanism of enhanced tubes than those enhancement ratios of $2.3\sim9.4$ among the tubes tested due to its sub-channels and re-entrant cavities.

• Korean Membrane Journal
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• v.6 no.1
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• pp.10-15
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• 2004

We developed a water-selective ceramic composite membrane for use as a dehydration membrane reactor for dimethylether (DME) synthesis from methanol. The membranes were modified on the porous stainless steel support by the sol-gel method accompanied by a suction process. The improved membrane modification process was effective in increasing the vapour permselectivity by removal of defects and pinholes. The optimized alumina/silica composite membrane exhibited a water permeance of 1.14${\times}$10$^{-7}$ mol/$m^2$.sec.Pa and a water/methanol selectivity of 8.4 at permeation temperature of 25$0^{\circ}C$. The catalytic reaction for DME synthesis from methanol using the membrane was performed at 23$0^{\circ}C$, and the reaction conversion was compared with that of the conventional fixed-bed reactor. The reaction conversion of the membrane reactor was much higher than that of the conventional fixed-bed reactor. The reaction conversion of the membrane reactor and the conventional fixed-bed reactor was 82.5 and 68.0%, respectively. This improvement of reaction efficiency can last if the water vapour produced in the reaction zone is removed continuously.

• Clean Technology
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• v.13 no.1 s.36
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• pp.28-33
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• 2007

We measured cloud points of Poly(methylmethacrylate) (PMMA) in various solvents using the high-pressure variable volume view cell apparatus. The solvents used for dissolving PMMA were chlorodifluoromethane (HCFC-22), dimethylether (DME), 1,1,1-trifluoroethane (HFC-143a), 1,1-difluoroethane (HFC-152a) and 1,1,1,2-tetrafluoroethane (HFC-134a), and the effect of $CO_2$ concentration on the phase behavior of $PMMA+HCFC-22+CO_2$ system and $PMMA+DME+CO_2$ system was observed. PMMA was dissolved well in HCFC-22 from about 340 K, 5MPa and in DME from about 300 K, 28MPa. However, PMMA was not dissolved at all up to 423.15 K, 160MPa in the other fluorine compound such as HFC-l43a, HFC-152a and HFC-134a. PMMA+HCFC-22, $PMMA+HCFC-22+CO_2$ and PMMA+DME systems exhibit the lower critical solution temperature (LCST) behavior, however, $PMMA+DME+CO_2$ system exhibits the upper critical solution temperature (UCST) behavior. In the $CO_2$ mixture, the cloud point pressure of PMMA was increased dramatically proportional to the amount of $CO_2$ added, and from this result, it was known that $CO_2$ could be used as an antisolvent for fabricating PMMA nano-particles. And the cloud point of PMMA could be controlled by changing the concentration of $CO_2$.

• Journal of Mechanical Science and Technology
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• v.19 no.10
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• pp.1957-1963
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• 2005

In this study, external condensation heat transfer coefficients (HTCs) of six flammable refrigerants of propylene (RI270), propane (R290), isobutane (R600a), butane (R600), dimethylether (RE170), and HFC32 were measured at the vapor temperature of $39^{\circ}C$ on a 1023 fpm low fin and Turbo-C tubes. All data were taken under the heat flux of $32\~116\;and\;42\~142kW/m^2$ for the low fin and Turbo-C tubes respectively. Flammable refrigerants' data obtained on enhanced tubes showed a typical trend that external condensation HTCs decrease with increasing wall subcooling. HFC32 and DME showed up to $30\%$ higher HTCs than those of HCFC22 due to their excellent thermophysical properties. Propylene, propane, isobutane, and butane showed similar or lower HTCs than those of HCFC22. Beatty and Katz' correlation predicted the HTCs of the flammable refrigerants obtained on a low fin tube within a mean deviation of $7.3\%$. Turbo-C tube showed the best performance due to its 3 dimensional surface geometry for fast removal of condensate.

• Membrane Journal
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• v.22 no.2
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• pp.142-154
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• 2012

In order to remove $CO_2$ from the DME plant process, we investigated the composite membrane with rubbery polymers as the separation layer and its separation performance of $CO_2$ and $H_2$. Hollow fiber membranes for supporting layer were prepared by solution spinning method. In case of using PDMS as a separation layer, the composite membranes showed the permeation rates of $CO_2$ were over 300 GPU and minimum $CO_2/H_2$ selectivitties were 4.3 and in case of using PEBAX as a separation layer, the composite membranes showed the permeation rates of $CO_2$ were over 120 GPU and minimum $CO_2/H_2$ selectivities were 5.

• Transactions of the Korean Society of Automotive Engineers
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• v.9 no.4
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• pp.44-49
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• 2001

Reduced chemical kinetics mechanism has been derived, which can be applicable for autoignition model of hydrocarbon fuels, and contains 23 reactions and 18 species. The present model is validated with the experimental data, where the ignition delays of several hydrocarbon fuels, such as n-heptane, i-octane, n-decane and DME(dimethylether) are measured as equivalence ratios are varied. Especially, the effects of different fuels on ignition delays can be explained by changing the rate constants of three reactions among the present model. As a result, the proposed model can be applicable to two stage ignition model of Diesel combustion.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.18 no.3
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• pp.247-253
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• 2006

In this work, pool boiling heat transfer coefficients (HTCs) of hydrocarbon refrigerants are measured from a horizontal smooth tube of 19.0 mm outside diameter. Tested pure refrigerants are Propylene, Propane, Isobutane, Butane and Dimethylether (DME). The pool temperature was maintained at saturation temperature of $7^{\circ}C$ and heat flux was varied from $10kW/m^2$ to $80kW/m^2$ with an interval of $10kW/m^2$. Wall temperatures were measured directly by thermocouple hole of 0.5 mm out-diameter, 152 mm long and inserting ungrounded sheathed thermocouples from the side of the tube. Tested results show that HTCs of Propane, Propylene are 2.5%, 10.4% higher than those of R22 while those of Butane and Isobutane are 55.2%, 44.3% lower than those of R22 respectively. For pure refrigerants, new correlation can be applied to all of CFCs, HCFCS, HFCs, as well as hydrocarbons was developed. The mean deviation was 4.6%.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.19 no.5
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• pp.403-410
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• 2007

In this study, natural refrigerants and their mixtures that can supplement and replace R12 and R134a in automobile air-conditioners are studied. R134a is currently used as the refrigerant in new motor vehicle air conditioners, replacing the ozone depleting refrigerant R12. Although R134a has no ozone depletion potential, it has a relatively large global warming potential, approximately 1300 times that of $CO_2$ over a 100 year time horizon. For this reason, performance of natural refrigerants and their mixtures containing R152a, RE170 (Dimethylether, DME) and R600a (Isobutane) are measured under 2 different temperature conditions. They were tested in a refrigerating bench tester with an open type compressor. The test bench provided about 4 kW capacity and water and water/glycol mixture were employed as the secondary heat transfer fluids. Test results show that the coefficient of performance (COP) of these refrigerants is up to 21.55% higher than that of R12 in all temperature conditions. Overall, these fluids provide good performance with reasonable energy savings without any environmental problem and thus can be used as long term alternatives for automobile air-conditioners.