• Journal of ILASS-Korea
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• v.14 no.4
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• pp.163-170
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• 2009

The present study has numerically investigates the vaporization, auto-ignition and combustion processes in the high-pressure and high-temperature conditions encountered in the diesel engine. In the present study, in order to understand the overall spray combustion characteristics of DME fuel as well as to identify the distinctive differences of DME combustion processes compared to conventional hydrocarbon liquid fuels, the sequence of the comparative analysis has been systematically made for DME and n-Heptane liquid fuels. Computations for DME fuel are made for two cases including constant fuel mass flow rate condition and fixed heat release rate. Based on numerical results, the discussions are made for the detailed combustion processes of DME and n-Heptane spray.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.158.2-158.2
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• 2011

DME is acronym of dimethyl ether, which is spotlighted as an ideal fuel to produce hydrogen due to its high hydrogen/carbon ratio, high energy density and easiness to carry. In this research, we calculated thermodynamic hydrogen (or syngas) yield from DME autothermal reforming and compared to other fuels. The reforming efficiency was about 80% above $700^{\circ}C$. Lower OCR has higher reforming efficiency but, it requires additional heat supply since the reactions are endothermic. SCR has no significant effect on the reforming efficiency. The optimized condition is $700^{\circ}C$, SCR 1.5, OCR 0.45 without additional heat supply. Comparing to other commercial gaseous fuels (methane and propane), DME has higher selectivity of $H_2O$ and $CO_2$ than the others due to the oxygen atom in the molecule. To apply DME autothermal reforming to real system, a proper catalyst is required. Therefore, it is performed the experiment comparing various novel metal catalysts based on CGO. Experiments were performed at calculated condition. The composition of product was measured and reforming efficiency was calculated. The catalysts have similar efficiency at high temperature(${\sim}800^{\circ}C$) but, CGO-Ru has the highest efficiency at low temperature ($600^{\circ}C$).

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.5
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• pp.147-156
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• 2008

As the management of fuel efficiency becomes globally reinforced in attempts to find an environment-friendly vehicle that will operate against global warming, the interest in and the demand for the type of vehicle with a high-efficiency diesel engine using light oil. However, it also emits a greater amount of PM (particulate matter) and NOx than emissions from vehicles using other types of fuels. Therefore, the DME (Dimethyl Ether), an oxygen containing fuel draws attention as an alternative fuel for light oil that can be used for diesel engines since it generates very little smoke. But to develop and compare performance of an electric controlled common-rail DME engine, engine tests requires optimized injection conditions at required engine RPM and engine torque. These injection conditions cannot be set freely and the data configuration through the experimentally repeated application requires much time as well as a significant amount of errors and effort. The object of this study is to configure the basic injection map using the results of the DME engine experiments performed so far. For this, in this study, the functionalization of the required equations were performed along with the basic review of the factors that had influence on the data map. Through this, the information on the injection pressure, injection amount, injection duration, injection timing, etc. under certain operation condition could be obtained.

• Journal of Hydrogen and New Energy
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• v.34 no.6
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• pp.581-586
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• 2023

As the development of alternative energy is required due to the depletion of fossil fuels, interest in the use of hydrogen energy is increasing. Hydrogen is a promising clean energy source with high energy density and can lead to the application of environmentally friendly technologies. However, due to difficulties in production, storage, and transportation that prevent the application of hydrogen-based eco-friendly technology, research on reforming reactions using dimethyl ether (DME) is being conducted. Unlike other hydrocarbons, DME is attracting attention as a hydrogen carrier because it has excellent storage stability and transportability, and there is no C-C bond in the molecule. The reaction between DME and steam is one of the reforming processes with the highest hydrogen yield in theory at a temperature lower than that of other hydrocarbons. In this study, a hydrogen reforming device using DME was developed and a catalyst prepared by supporting Cu in alumina was put into a reactor to find optimal hydrogen production conditions for supplying hydrogen to fuel cells while changing reaction temperature (300-500℃), pressure (5-10 bar), and steam/carbon ratio (3:1 to 5:1).

• Journal of the Korea Academia-Industrial cooperation Society
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• v.11 no.2
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• pp.590-596
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• 2010

Through this study, we have attempted the thermodynamic analysis on the dimethyl ether (DME) separation process, which can be used for diesel alternative fuel, additive to LPG and natural gas. And we also have completed the simulation of DME separation process using PRO/II with PROVISION. As an appropriate thermodynamic models, we selected NRTL liquid activity coefficient model to describe the non-ideality between methanol and water. To estimate the vapor phase non-idealities, we have chosen the Peng-Robinson equation of state model. And we also use the Henry's law option to predict the solubilities of non-condensible gases like CO, $CO_2$, $H_2$, $CH_2$ and $N_2$ in methanol solvent. Case study showed that optimal solvent to feed molar ratio was 3.40

• Journal of Hydrogen and New Energy
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• v.22 no.2
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• pp.232-239
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• 2011

DME has received much attention because of its possible use as a fuel and a chemical feedstock. Chemical conversion of DME to olefin (DTO) over various SAPO-34 catalysts was carried out using a fixed bed reactor. Main products of the reaction were light olefins such as ethylene, propylene and butenes. The best reaction conditions for high life time of the catalyst and high selectivity of light olefins were a reaction temperature of $400^{\circ}C$ and a WHSV of $3.54h^{-1}$. In addition, it was found that the deactivation of a SAPO-34 catalyst can be significantly suppressed by the addition of $ZrO_2$ as a supporter.

• Journal of ILASS-Korea
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• v.17 no.4
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• pp.205-209
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• 2012

This study focused on comparing macroscopic characteristics of DME and diesel fuel experimentally. DME fuel is one of the most promising alternative fuels because of its superiority in atomization characteristic and clearness in terms of exhaust gas compared with existing fossil fuels. In addition, DME fuel has high cetane number so it could be applied to compression ignition engine. However because DME fuel exists in gas phase at room temperature and atmospheric pressure, and it corrodes rubber parts of fuel line, DME fuel is hard to apply to commercial vehicles. To establish knowledge about DME fuel and furthermore, to develop commercial DME vehicles such as passenger cars, many research have been proceeded steadily. The present study, by comparing spray characteristics of DME fuel to those of diesel fuel, improved atomization characteristics in DME were revealed. Injection quantity measurement and spray visualization experiment were progressed and it was revealed that DME fuel shows small injection quantity than that of diesel fuel and axial development of spray in terms of spray tip penetration decreases when DME fuel was injected.

• Journal of Advanced Marine Engineering and Technology
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• v.36 no.8
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• pp.1010-1015
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• 2012

DME(Dimethyl ether) is the one of the massive energy sources synthesized from natural gas. KOGAS has already developed the commercial-scale production plant of DME and has been doing to obtain overseas resources to meet the domestic needs. This paper presents the DME storage tank design criteria by stress and strain analysis, and the experimental study on the evaporation phenomena of DME by thermal intake and physical rolling movement of DME FPSO or cargo vessel, because the various moving motions along with heat intake cause the evaporation of low temperature liquid. The experimental result shows that the evaporation rate was increased with larger rolling degree and higher liquid level. The rolling motion leads to evaporate about 20% increase with 15 degree rolling based on the evaporation quantity without rolling.

• Transactions of the Korean Society of Automotive Engineers
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• v.14 no.3
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• pp.178-185
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• 2006

This paper investigates the steady-state combustion characteristics of the Homogeneous charge compression ignition(HCCI) engine with variable valve timing(VVT) and dimethyl ether(DME) direct injection, to find out its benefits in exhaust gas emissions. HCCI combustion is an attractive way to lower carbon dioxide($CO_2$), nitrogen oxides(NOx) emission and to allow higher fuel conversion efficiency. However, HCCI engine has inherent problem of narrow operating range at high load due to high in-cylinder peak pressure and consequent noise. To overcome this problem, the control of combustion start and heat release rate is required. It is difficult to control the start of combustion because HCCI combustion phase is closely linked to chemical reaction during a compression stroke. The combination of VVT and DME direct injection was chosen as the most promising strategy to control the HCCI combustion phase in this study. Regular gasoline was injected at intake port as main fuel, while small amount of DME was also injected directly into the cylinder as an ignition promoter for the control of ignition timing. Different intake valve timings were tested for combustion phase control. Regular gasoline was tested for HCCI operation and emission characteristics with various engine conditions. With HCCI operation, ignition delay and rapid burning angle were successfully controlled by the amount of internal EGR that was determined with VVT. For best IMEP and low HC emission, DME should be injected during early compression stroke. IMEP was mainly affected by the DME injection timing, and quantities of fuel DME and gasoline. HC emission was mainly affected by both the amount of gasoline and the DME injection timing. NOx emission was lower than conventional SI engine at gasoline lean region. However, NOx emission was similar to that in the conventional SI engine at gasoline rich region. CO emission was affected by the amount of gasoline and DME.

• Proceedings of the KSME Conference
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• 2007.05b
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• pp.3329-3334
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• 2007

The purpose of the research is to investigate of diesel spray combustion for simultaneously reduce way NOx and PM. The pressure diesel injection were done into intermediates that are generated by very lean DME HCCI combustion using a RCM. The concentration of intermediate could not be directly measured; we estimated it by CHEMKIN calculation. DME HCCI characteristic is surveyed. Validations of the CHEMKIN calculation were confirmed pressure rise of an experiment and pressure rise of a calculation. Using a framing streak camera captured two dimensional spontaneous luminescence images from chemical species at low temperature reaction(LTR) and high temperature reaction (HTR). Also, the combustion events were observed by high-speed direct photography, the ignition and combustion were analyzed by the combustion chamber pressure profiles.