• Clean Technology
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• v.30 no.2
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• pp.123-133
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• 2024

Zeolite template carbon (ZTC) was synthesized as an adsorbent to remove low-concentration CH₄ from the atmosphere. The synthesis of ZTC was performed using CH₄ and C₂H₂ as carbon precursors and their impact on adsorption was investigated. ZTC was also synthesized using Y zeolite ion-exchanged with CaCl₂ and LiCl as templates to investigate the effect of using metals in ion exchange. The comparison of the carbon precursors revealed that C₂H₂ had a higher carbon yield than CH₄. The synthesized ZTC exhibited developed micropores due to carbon deposition deep inside the micropores of the zeolite template. The kinetic diameter of C₂H₂ (0.33 nm) is smaller than that of CH₄ (0.38 nm), which allowed for its deposition. The study compared metal precursors used for ion exchange and confirmed that the CaCl₂-based ZTC developed more micropores compared to the LiCl-based ZTC. The ion-exchanged Ca inhibited pore blocking by the carbon precursor, allowing it to enter the pores. The ability of synthesized ZTC to adsorb N₂ and CH₄ at 298 K was investigated. The results showed that CH₄ had a higher overall adsorption amount than N₂. The sample synthesized using C₂H₂ and CaY exhibited the highest N₂ and CH₄ adsorption capacity. However, the sample synthesized with CH₄ had the highest CH₄/N₂ gas uptake ratio, which is a crucial factor in designing an adsorption process. The observed difference was likely caused by the underdevelopment of ultrafine pores that are associated with N₂ adsorption. This resulted in a reduction of N₂ adsorption, leading to an increase in CH₄/N₂ separation.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.26 no.4
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• pp.381-388
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• 2015

In this paper, a wireless video streaming system is designed and implemented for TV white space applications. It consists of a RF transceiver module, a digital modem, a camera, and a LCD screen. A VGA resolution video is captured by a camera, modulated by modem, and transmitted by RF transceiver module, and finally displayed at a destination 2.6-inch LCD screen. The RF transceiver is based on direct-conversion architecture. Image leakage is improved by low pass filtering LO, which successfully covers the TVWS. Also, DC offset problem is solved by current steering techniques which control common mode level at DAC output node. The output power of the transmitter and the minimum sensitivity of the receiver is +10 dBm and -82 dBm, respectively. The channel bandwidth is tunable among 6, 7 and 8 MHz according to regulations and standards. Digital modem is realized in Kintex-7 FPGA. Data rate is 9 Mbps based on QPSK and 512ch OFDM. A VGA video is successfully streamed through the air by using the developed TV white-space RF communication module.