• Title/Summary/Keyword: D1-D2 region

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Tri-branched tri-anchoring organic dye for Visible light-responsive dye-sensitized photoelectrochemical water-splitting cells (염료감응형 광전기화학 물분해 전지용 Tri-branched tri-anchoring organic dye 개발)

  • Park, Jeong-Hyun;Kim, Jae-Hong;Ahn, Kwang-Soon
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.87-87
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    • 2010
  • Photoelectrochemical (PEC) systems are promising methods of producing H2 gas using solar energy in an aqueous solution. The photoelectrochemical properties of numerous metal oxides have been studied. Among them, the PEC systems based on TiO2 have been extensively studied. However, the drawback of a PEC system with TiO2 is that only ultraviolet (UV) light can be absorbed because of its large band gap (3.2 - 3.4 eV). Two approaches have been introduced in order to use PEC cells in the visible light region. The first method includes doping impurities, such as nitrogen, into TiO2, and this technique has been extensively studied in an attempt to narrow the band gap. In comparison, research on the second method, which includes visible light water splitting in molecular photosystems, has been slow. Mallouk et al. recently developed electrochemical water-splitting cells using the Ru(II) complex as the visible light photosensitizer. the dye-sensitized PEC cell consisted of a dye-sensitized TiO2 layer, a Pt counter electrode, and an aqueous solution between them. Under a visible light (< 3 eV) illumination, only the dye molecule absorbed the light and became excited because TiO2 had the wide band gap. The light absorption of the dye was followed by the transfer of an electron from the excited state (S*) of the dye to the conduction band (CB) of TiO2 and its subsequent transfer to the transparent conducting oxide (TCO). The electrons moved through the wire to the Pt, where the water reduction (or H2 evolution) occurred. The oxidized dye molecules caused the water oxidation because their HOMO level was below the H2O/O2 level. Organic dyes have been developed as metal-free alternatives to the Ru(II) complexes because of their tunable optical and electronic properties and low-cost manufacturing. Recently, organic dye molecules containing multi-branched, multi-anchoring groups have received a great deal of interest. In this work, tri-branched tri-anchoring organic dyes (Dye 2) were designed and applied to visible light water-splitting cells based on dye-sensitized TiO2 electrodes. Dye 2 had a molecular structure containing one donor (D) and three acceptor (A) groups, and each ended with an anchoring functionality. In comparison, mono-anchoring dyes (Dye 1) were also synthesized. The PEC response of the Dye 2-sensitized TiO2 film was much better than the Dye 1-sensitized or unsensitized TiO2 films.

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Investigation of PCR-RFLPs within Major Histocompatibility Complex B-G Genes Using Two Restriction Enzymes in Eight Breeds of Chinese Indigenous Chickens

  • Xu, R.F.;Li, K.;Chen, G.H.;Qiang, B.Y.Z.;Mo, D.L.;Fan, B.;Li, C.C.;Yu, M.;Zhu, M.J.;Xiong, T.A.;Liu, Bang
    • Asian-Australasian Journal of Animal Sciences
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    • v.18 no.7
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    • pp.942-948
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    • 2005
  • New polymorphism of major histocompatibility complex B-G genes was investigated by amplification and digestion of a 401bp fragment including intron 1 and exon 2 using polymerase chain reaction-restriction fragment length polymorphism (PCR-RFLP) technique with two restriction enzymes of Msp I and Tas I in eight breeds of Chinese indigenous chickens and one exotic breed. In the fragment region of the gene, three novel single nucleotide polymorphisms (SNPs) were detected at the two restriction sites. We found the transition of two nucleotides of A294G and T295C occurred at Tas I restriction site, and consequently led to a non-synonymous substitution of asparagine into serine at position 54 within the deduced amino acid sequence of immunoglobulin variable-region-like domain encoded by the exon 2 of B-G gene. It was observed at rare frequency that a single mutation of A294G occurring at the site, also caused an identical substitution of amino acid, asparagine 54-to-serine, to that we described previously. And the transversion of G319C at Msp I site led to a non-synonymous substitution, glutamine 62-to-histidine. The new alleles and allele frequencies identified by the PCR-RFLP method with the two enzymes were characterized, of which the allele A and B frequencies at Msp I and Tas I loci were given disequilibrium distribution either in the eight Chinese local breeds or in the exotic breed. By comparison, allele A at Msp I locus tended to be dominant, while, the allele B at Tas I locus tended to be dominant in all of the breeds analyzed. In Tibetan chickens, the preliminary association analysis revealed that no significant difference was observed between the different genotypes identified at the Msp I and Tas I loci and the laying performance traits, respectively.

Behaviour of micropiles in collapsible loess under tension or compression load

  • Qian, Zeng-Zhen;Lu, Xian-Long;Yang, Wen-Zhi;Cui, Qiang
    • Geomechanics and Engineering
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    • v.7 no.5
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    • pp.477-493
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    • 2014
  • This study examines the behaviour of single micropiles subjected to axial tension or compression load in collapsible loess under in-situ moisture content and saturated condition. Five tension loading tests and five compression loading tests on single micropiles were carried out at a typical loess site of the Loess Plateau in Northwest China. A series of laboratory tests, including grain size distribution, specific gravity, moisture content, Atterberg limits, density, granular components, shear strength, and collapse index, were carried out during the micropile loading tests to determine the values of soil parameters. The loess at the test site poses a severe collapse risk upon wetting. The tension or compression load-displacement curves of the micropiles in loess, under in-situ moisture content or saturated condition, can generally be simplified into three distinct regions: an initial linear, a curvilinear transition, and a final linear region, and the bearing capacity or failure load can be interpreted by the L1-L2 method as done in other studies. Micropiles in loess should be considered as frictional pile foundations though the tip resistances are about 10%-15% of the applied loads. Both the tension and compression capacities increase linearly with the ratio of the pile length to the shaft diameter, L/d. For micropiles in loess under in-situ moisture content, the interpreted failure loads or capacities under tension are 66%-87% of those under compression. However, the prewetting of the loess can lead to the reductions of 50% in the tensile bearing capacity and 70% in the compressive bearing capacity.

A Study on Minimizing Position Error in Hyperbolic Fix Determination. (쌍곡면항법에 있어서 편위오차이 최소화에 관한 연구)

  • 김우숙;김동일;정세모
    • Journal of the Korean Institute of Navigation
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    • v.14 no.2
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    • pp.1-14
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    • 1990
  • The Radio Navigation System(R. N. S.) has been progressed consistantly with the development of electric-electronic engineering techniques since the R. D. E had been developed in 1910. The R. N. S. mostly depends on either Hyperbolic Navigation System(H. N. S.) or Spherical Navigation System(S. N. S.) in the ocean, and on Rectangular Navigation System (R. N. S.) in the air near the airport or an a combinations of the above systems in both area. Another effective R. N. S may be the Ellipse-Hyperbola Navigation System(E-H N. S.), which is proposed and named such in this paper. The equations calculating GDOP are derived and the GDOP values are calculated in the case of H. N. S., S. N. S, and E-H. N. S., respectively, for the specified case that four transmitting stations are arranged on the apex of a square, Then the GDOP diagrams of above navigation systems are presented for qualitative comparison in this paper. To measure the distances from the receiver to the stations in S. N. S., and/or the sum of distances to two stations in E-H N. S., the time synchronization between the transmitter clocks and the receiver clock is a major premise. The author has proposed the algorithm for getting this synchronmization utilizing the by S. N. S. or E-H N. S while GDOPs of those are relatively good. Even though clock synchronization error is a voidable due to the fix error used, the simulated results shows that the position accuracy of S. N. S. and E-H N. S. by the proposed method is far upgraded compared with that determined by H. N. S. directly, as far as the outer region of transmitter arrangement is concerned.

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The Preliminary Study on the Structure of Cop Protein by CD and NMR

  • Kim, Yun-Kyong;Park, Sang-Ho;Lee, Jee-Hyun;Kwak, Jin-Hwan;Lee, Bong-Jin
    • Journal of the Korean Magnetic Resonance Society
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    • v.3 no.2
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    • pp.100-108
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    • 1999
  • Cop protein is the transcription repressor protein in rolling circle replication plasmid. With antisense RNA, Cop protein controls the copy number of plasmid. Cop family proteins have been found in various plasmids. Among Cop family proteins, Cop studied in this paper consists of 55 amino acids (Mw. 6,400), and was known to have trimer structure. Since no structural facts are elucidated, we have carried out preliminary experiments aimed at the elucidation of its three dimensional structure. The secondary structure of Cop is studied by CD and NMR. To solve the aggregation of Cop at high concentration, we tested various detergents and salts. The addition of detergents and salts could not solve the aggregation problem. However, we found that concentration is important in solving the aggregation problem. We knew that 0.18mM in 50mM potassium phosphate without any other ingredients is maximum concentration not to aggregate. Wa also investigated the pH dependence of Cop protein, and knew that Cop protein is more stable in acid state. At various temperatures, 15N-1H HSQC spectra were measured in order to find the optimal experimental condition. To enhance the peak resolution, 3D NOESY-HSQC spectrum is acquired. Since there are NOE peaks in the NH-NH region, we knew that Cop protein has $\alpha$-helical content, which was also confirmed by CD.

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Methane hydrate : The state of the art of Production technologies and environmental issues (메탄 하이드레이트의 생산 기술 현황과 환경에 미치는 영향)

  • Chang Seung yong
    • The Korean Journal of Petroleum Geology
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    • v.7 no.1_2 s.8
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    • pp.13-18
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    • 1999
  • Methane hydrate is an ice-like solid material and it has a structure which water molecules enclose gas molecules. For low temperature and high pressure, hydrocarbon gas forms hydrate and due to this condition, it is existed in the arctic region or deep sea. Presently, the amount of methane hydrate is unpredictable, but it is assumed that the amount will be enormous. For this reason, it is expected that it will play a major role as natural gas resources in the future. However, the production technologies are stayed on the low level and the economical technology was not developed yet. Also, emission of natural gas from methane hydrate will cause global warming and thus it is considered as a critical environmental problem. In this paper, the state of the art of the production technologies and environmental effects of methane hydrate were summarized.

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Seismicity of the Korean Peninsula and Its Vicinity (한반도와 그 인접지역의 지진활동(地震活動))

  • Kim, So Gu
    • Economic and Environmental Geology
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    • v.13 no.1
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    • pp.51-63
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    • 1980
  • The seismicity of the Korean Peninsula and its vicinity is investigated temporally (2 A. D. to 1978) and spatially to evaluate the seismic risk and to understand the neotectonics around the peninsula. The study has been conducted using macrocosmic data obtained from historical literature, and instrumental records recorded by the Worldwide Network of Standardized Seismographs(WWNSS). The seismicity of the peninsula was active from the 13th through the 17th centuries. A seismic quiescence began at the onset of the 18th century, and has continued for the last 200 years. Presently, the seismicity region is found to be active again. The return periods are determined by a statistical method based upon the cumulative magnitude recurrence. They indicate that the seismic risk is greater in the south or west than in the north or east of the peninsula. Focal mechanism solutions demonstrate that the neotectonic stress distribution in the Japan Sea is greatly influenced by the subduction of the Pacific Plate under the Eurasian Plate or the Philippine Sea Plate, even though the predominate local paleotectonics is controlled by the spreading of the earth's crut.

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New Record of Three Percoids (Pisces: Perciformes) from Cheju Island, Korea (제주도에서 출현한 농어목 어류의 3 미기록종)

  • Youn, Chang-Ho
    • Korean Journal of Ichthyology
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    • v.10 no.2
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    • pp.260-267
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    • 1998
  • Three species of the order Perciformes collected from coastal waters of Cheju Island, Korea were documented with photographs, all of which are newly known to Korea. Nemipterus bathybius Snyder, 1911 of the family Nemipteridae is distinguished by seven anal soft rays and the most upper ray at the caudal fin elongated. Cirrhitichthys aureus (Temminck et Schlegel, 1842) of the family Cirrhitidae (New Korean name: Hwangbokdom-kwa), is characterized by the five to six light black spots on the dorso-Iateral sides, 12 dorsal soft rays and a dorsal fin without spots and bands. Parapercis aurantiaca D$\ddot{o}$erlein, 1884 of the family Pinguipedidae, has several taxonomic characters. The dorsal spines and the soft rays of the dorsal fins were connected without a notch. The five to six dark yellow bands with the same size of eye length were shown on the lateral region. A new Korean name Kinsilkkoridom is proposed for the Nemipterus bathybius, and Cirrhitichthys aureus, Hwangbukdom, and Parapercis aurantiaca, Hwangssangdonggari.

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Status of Mechanization of Small Farms in India

  • Ojha, T.P.
    • Proceedings of the Korean Society for Agricultural Machinery Conference
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    • 1996.06c
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    • pp.263-269
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    • 1996
  • In indian agricultural , the energy use pattern has played dominant role in influencing the level of mechanization . Besides that the agro-climatic factors as well as the size of holdings do affect the degree of mechanization . Nearly 30 percent of total cultivated area is owned by l76 percent of the small and tiny land holders each owning even less than a hectare. On the other hand, about 2 percent of land owners cultivate land. These variabilitieshave greatly influenced the ownership of power sources on Indian farms. Small farmers, employ human and animal energies with the use of hand tools and animal drawn equipments. Whereases, the use of tractors, power tillers, electric motors, etc. on small farms is on a marginal scale. There are few pockets and also extensive wheat growing regions where mechanical and electrical power sources are extensively used in production agriculture leading to about 185% of cropping intensity . In that region, the animal energy is employed for on the farm transport of fertilizers, fodders and fuel to support milch animals and other household activities . Inspite of high degree of mechanization, the harvesting of crops is done by human labour with few exceptions of harvesting wheat crops by combines in few pockets. In overall assessment of mechanization, the following conclusions are drawn : ⅰ) Farm operation which show a growing trend of mechanization are (a) tillge, (b) seedling (c) Irrigation (d) Plant protection application (e) Threshing and (f) Transport . ⅱ) Crop cultivation system in respect of wheat, maize and sorghum have been greatly mechanized. ⅲ) The least mechanized cropping systems are (a) vegetable production and (b) cultivation of sugarcane, cotton, rice and pulses. ⅳ) Annual production of tractor has touched the figure of 280.000 by 1995 and the total number has crossed 1.5million on Indian farms.

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Size-homogeneous gold nanoparticle decorated on graphene via MeV electron beam irradiation

  • Kim, Yoo-Seok;Song, Woo-Seok;Jeon, Cheol-Ho;Kim, Sung-Hwan;Park, Chong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.487-487
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    • 2011
  • Recently graphene has emerged as a fascinating 2D system in condensed-matter physics as well as a new material for the development of nanotechnology. The unusual electronic band structure of graphene allows it to exhibit a strong ambipolar electric field effect with high mobility. These properties lead to the possibility of its application in high-performance transparent conducting films (TCFs). Compared to indium tin oxide (ITO) electrodes, which have a typical sheet resistance of ${\sim}60{\Omega}$/sq and ~85 % transmittance in the visible range (400?900 nm), the CVD-grown graphene electrodes have a higher/flatter transmittance in the visible to IR region and are more robust under bending. Nevertheless, the lowest sheet resistance of the currently available CVD graphene electrodes is higher than that of ITO. Here, we report an ingenious strategy, irradiation of MeV electron beam (e-beam) at room temperature under ambient condition, for obtaining size-homogeneous gold nanoparticle decorated on graphene. The nano-particlization promoted by MeV e-beam irradiation was investigated by transmission electron microscopy, electron energy loss spectroscopy elemental mapping, and energy dispersive X-ray spectroscopy. These results clearly revealed that gold nanoparticle with 10 ~ 15 nm in mean size were decorated along the surface of the graphene after 1.5 MeV-e-beam irradiation. A chemical transformation and charge transfer for the metal gold nanoparticle were systematically explored by X-ray photoelectron spectroscopy and Raman spectroscopy. This approach advances the numerous applications of graphene films as transparent conducting electrodes.

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