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Crystallization Behavior and Electrical Properties of BNN Thin Films by IBSD Process

  • Lou, Jun-Hui;Jang, Jae-Hoon;Lee, Hee-Young;Cho, Sang-Hee
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07b
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    • pp.960-964
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    • 2004
  • [ $Ba_2NaNb_5O_{15}$ ](BNN) thin films have been prepared by the ion beam sputter deposition (IBSD) method on Pt coated Si substrate at temperature as low as $600^{\circ}C$ XRD, SEM were used to investigate the crystallization and microstructure of the films. It was found that the films were crack-free and uniform in microstructure. The electric properties of thin films were carried out by observation of D-E hysteresis loop, dielectric constant and leakage current. It was found the deposition rate strongly influenced the phase formation of the films, where the phase of $BaNb_2O_6$ was always formed when the deposition rate was high. However, the single phase (tungsten bronze structure ) BNN thin film was obtained with the deposition rate as low as $22{\AA}/min$. The remanent polarization Pr and dielectric constant are about 1-2 ${\mu}C/cm^2$ and $100\sim200$, respectively. It was also founded the electric properties of thin films were influenced by the deposition rate. The Pr and dielectric constant of films increased with the decrease of deposition rate. The effects of annealing temperature and annealing time to the crystallization behavior of films were studied. The crystallization of thin film started at about $600^{\circ}C$. The adequate crystallization was gotten at the temperature of $650^{\circ}C$ when the annealing time is 0.5 hour or at the temperature of $600^{\circ}C$ when the annealing time is long as 6 hours.

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Mathematical Model for the Removal of SO2 by the γ-Alumina Impregnated with CuO (γ-Alumina에 담지된 산화구리에 의한 SO2의 제거에 관한 수치모사)

  • Jeon, Bup Ju;Hong, In Kwon;Park, Kyung Ai;Jung, Il Hyun
    • Applied Chemistry for Engineering
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    • v.5 no.3
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    • pp.385-394
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    • 1994
  • Numerical solutions were obtained to the model equations for various of the parameters characterizing the pore structure, effective internal diffusion, and the chemical reaction constant. The conversion was decreased with the cause of pore closure at the surface of reacting particles, reduction of porosity, surface area of reaction and effective diffusion coefficient in the solid with the progress of reaction. Total conversion was strongly dependent on the local conversion at surface. According to the decreasing of impregnated concentration of the copper oxide and the increase of the flue gases concentration, total conversion was increased. The conversion was affected by gas flow rate and pore size distribution in the reacting solid.

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Fabrication of Film Bulk Acoustic Wave Filters with Ladder and Stacked Crystal Filter Types (Ladder 형과 SCF 형의 구조를 가지는 FBAR 필터의 제작)

  • ;;Mai Linh
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2003.10a
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    • pp.630-632
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    • 2003
  • In this paper, we present the fabrication and performance of FBAR filters with ladder and stacked crystal filter (SCF) types. The structure of the unit resonator in our work is the solidly mounted resonator (SMR) with W/SiO$_2$ multi-layer reflectors, the return loss of of which show -24dB at resonant frequency of -2.0GHz. The $K^2$eff, Q$_{s}$, and Q$_{p}$, indicating the performance of resonator were 3.24%, 6,363 and 6,749 and were calculated for the resonator with the resonance area of 21200${\mu}{\textrm}{m}$$^2$. Based on this unit resonator, FBAR filters with ladder and SCF types were fabricated and compared. The sizes of filters were 800$\times$2000(${\mu}{\textrm}{m}$$^2$) for the ladder type and 600$\times$500(${\mu}{\textrm}{m}$$^2$) for the SCF type.e..

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Correlation Between Mechanical Behavior and Electrical Resistance Change in Carbon Particle Dispersed Plastic Composite

  • Song, D.Y.;Takeda, N.;Kim, J.K.
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.377-382
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    • 2001
  • Mechanical behavior and electrical resistance change of CPDP (carbon particle dispersed plastic) composite consisting of epoxy resin and conductive carbon particle were investigated under monotonic loading and repeated loading-unloading. The electrical resistance almost linearly increased with increasing strain during loading and the residual electrical resistance was observed even after removing load. The value of the residual electrical resistance was dependent on the maximum strain under the applied stress. This result suggests that the estimation of maximum strain (i.e., damage) is possible by the measuring electrical resistance of composite. The behavior of electrical resistance change during and after loading was discussed on the basis of the results of microscopic deformation and fracture observation. Moreover, the relationship between the volume fraction of carbon particle and the electrical resistivity of CPDP was investigated in relation to the percolation theory. Simulation model of percolation structure was established by Monte Carlo method and the simulation result was compared to the experimental results. The electrical resistance change under applied loading was analyzed quantitatively using the percolation equation and a simple model for the critical volume fraction of carbon particle as a function of the mechanical stress. It was revealed that the prediction was in good agreement with the experimental result except in the region near the failure of material.

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Genetic Characterization of Indigenous Goats of Sub-saharan Africa Using Microsatellite DNA Markers

  • Chenyambuga, S.W.;Hanotte, O.;Hirbo, J.;Watts, P.C.;Kemp, S.J.;Kifaro, G.C.;Gwakisa, P.S.;Petersen, P.H.;Rege, J.E.O.
    • Asian-Australasian Journal of Animal Sciences
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    • v.17 no.4
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    • pp.445-452
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    • 2004
  • Genetic diversity of sub-Saharan African goats was assessed using 19 microsatellite markers. Breeds were sampled from eastern Africa (Maasai, Kigezi, Mubende, North West Highland, Arsi-Bale), southern Africa (Ndebele, Pafuri) and West Africa (West African Dwarf, Maure, Djallonke). European breeds (Grisons Striped, Toggenburg), Asian breeds (Mongolian Cashmere, Bandipur) and a Middle East breed (Arab) were also included. The mean number of alleles per locus and average gene diversity ranged from 5.26$\pm$0.464 (Djallonke) to 7.05$\pm$0.516 (Mubende) and from 0.542$\pm$0.036 (Pafuri) to 0.672$\pm$0.031 (Ndebele), respectively. The between breeds variation evaluated using $$G_{ST}$$ and $\theta$ were found to account for 14.6% ($\theta$) and 15.7% ($$G_{ST}$$) of the total genetic variation. The $D_{A}$ measure of genetic distance between pairs of breeds indicated that the largest genetic distance was between Pafuri and Djallonke while the lowest genetic distance was between Arsi-Bale and North West Highland. A neighbour-joining tree of breed relationships revealed that the breeds were grouped according to their geographic origins. Principal component analysis supported the grouping of the breeds according to their geographic origins. It was concluded that the relationships of sub-Saharan African goat breeds were according to their geographical locations implying that the goats of eastern Africa, West Africa and southern Africa are genetically distinct. Within each sub-region, goat populations could be differentiated according to morphological characteristics.

Enrichment of Lithium Isotope by an Ion Exchange Resin Containing Azacrown Ether (아자크라운 에터를 포함한 이온교환수지에 의한 리튬 동위원소의 농축)

  • Kim, Dong Won;Chung, Yongsoon;Choi, Ki Young;Lee, Yong-Ill;Jeong, Young Kyu;Jang, Young Hun
    • Analytical Science and Technology
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    • v.10 no.6
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    • pp.403-407
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    • 1997
  • Separation factor for $^6Li$ and $^7Li$ have been determined using ion exchange resin having 1,7,13-trioxa-4,10,16-triazacyclooctadecane($N_3O_3$) as an anchor group. The lighter isotope, $^6Li$ is concentrated in the solution phase, while the heavior isotope, $^7Li$ is enriched in the resin phase. By Ccolumnl chromatography[0.9cm(I.D)${\times}$20cm(height)] using 2.0M ammonium chloride solution as an eluent, single separation factor, ${\alpha}$, 1.009. i.e.$(^7Li/^6Li)_{resin}$/$(^7Li/^6Li)_{solution}$ was obtained by the Glueckauf theory from the elution curve and isotope ratios.

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Stress Tolerance of Bifidobacterium infantis ATCC 27920 to Mild-heat Adaptation

  • Kang, Seok-U;Kim, Young-Hoon;Cho, In-Shick;Kang, Ja-Heon;Chun, Il-Byung;Kim, Kwang-Hyun;Oh, Se-Jong
    • Food Science and Biotechnology
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    • v.18 no.1
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    • pp.249-252
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    • 2009
  • Two-dimensional gel electrophoresis (2-DE) was employed to assess the thermo-tolerance characteristics of Bifrdobacterium infantis ATCC 27920 to mild heat adaptation. When exposed to various heat levels, pH, and hydrogen peroxide ($H_2O_2$) stress conditions, B. infantis ATCC 27920 exhibited high level of stress resistance. Under mild-heat treatment ($46^{\circ}C$), no significant change in viability level was observed after 2 hr. Interestingly, improved viability was observed in mild-heat adapted ($46^{\circ}C$ for 1 hr) cultures exposed to $55^{\circ}C$, in comparison to control experiments. Viability was not affected by pH, bile, and $H_2O_2$ stress conditions. 2-DE analysis revealed those mild-heat adaptation up-regulated 4 proteins and down-regulated 3 proteins. Among these protein spots, isopropyhnalate dehydratase (leuD), glycosyltransferase (glgA), and ribosomal protein L5 (rp1E) were identified by matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALD1-TOF/MS).

Characterization of Thermal Properties of Concrte and Temperature Prediction Model (콘크리트재료의 열특성 및 수화열 해석)

  • 양성철
    • Magazine of the Korea Concrete Institute
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    • v.9 no.2
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    • pp.121-132
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    • 1997
  • The thermal behavior of' concrete can be ch;lracterized from a knowledge of concrete ternperatu1.e at early ages, environmental conditions, and cement hydration in the mixture. 'l'o account for thost. interactions, a computer model was developed for prwlicting the temperature pr.ol'ile in hnrdcning c o n c r c t ~ st.r~icture in terms of material and tmvironmcntal factors. The cerncnt hydration cha~.acteristics such as the activating energy, total heat 1ihei.atr.d. anti th\ulcorner degree of' hydration. can represent the internal heat gc,neration. In this study. th(> activating c1ncrgy and the tlcgree of' hydration curve were determined well fmm the rnortn~. compressive strength tests while total amount of heat liberated was determined by tht> isothermal calorimctcr method. The main purpose of' this study is to correlate measured tt>mperaturr distributions in a concrete st1,ucture during thc hardening process with the ~ c s u l t s computed f'ro~n theoretical considrl.ations. Using twodimensional heat transfer model, first. the importance of several parameters will be identified by a parametric analysis. Then, the tcmpcmture distribution of thc cylindrical concrete specimen in the laboratory was mensuwti and compared with that yielded by thc theoretical considel.ations.

STUDIES ON THE PLANT GROWTH REGULATING EFFECT OF PHTHALAMIC ACID AND ITS DERIVATIVES (Phthalamic acid 및 이의 유도체의 식물생장조정작용에 미치는 영향에 관한 연구)

  • Lee Sung Hwan;Do Un Hoi
    • Korean journal of applied entomology
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    • v.8
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    • pp.11-18
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    • 1969
  • 식물 생장 조절제로서 phthalamic acid와 그 유도체를 사용하여 추락답을 개량하기 위한 예비 시험을 실시하여 다음과 같을 결과를 얻었다. 1) 아래 7종의 phthalamic acid 및 그 유도체를 합성 또는 정제하여 공시약제로 하였으며 합성품의 수율은 $87-92\%$였다. (표 1) A. Phthalamic acid B. Phthalanilic acid C. N- (o-Chlorophenly)-phthalamic acid D. N-(p-Chlorophenyl)-phthalamic acid E. N- (3,4-Dichlorophenyl)-phthalamic acid F. Sodium-N- (m-tolyl)-phthalamate (Duraset) G. Sodium-N-(1-naphthyl)-phthalamate (Alanap) 2) Wheat straight growth test에서 공시약제는 10ppm 및 20ppm의 농도에서 Control보다 월등한 생장 촉진효과를 보였으며 특히 흥미있는 것은 phthalamic acid 유도체가 phthalamic acid 자체보다 더 좋은 효과를 보였다. (표4, 그림 1) 3) 수도 종자의 발아 시험 결과 초장은 phthalamic acid 유도체가 적시 phthalamic acid 자체보다 좋았으며 기중 Alanap. 3,4-dichlorophenyl phthalamic acid 및 Duraset가 가장 좋았으나 10-100ppm 범위내의 농도에 거의 영향없었다. (표 5) 근의 생육은 일반적으로 약제의 종류에 따라 상이할 뿐 아니라 초장의 생육보다 더욱 약제에 민감하였다. 근장은 phthalamic acid, phthalanilic acid, (p-chlorophenyl)phthalamic acid, 3,4-dichlorophenyl phthalamic acid가 Control 보다 약간 좋은 효과를 보였고, Alanap은 매우 불량하였다. (표 6) 근수는 (p-chlorohhenyl) phthalamic acid만 Control에 비해 우수하였고 나머지 약제는 대체로 근수를 감소시키거나 Control과 비슷한 효과를 보였다. (표 7) 또한 농도가 증가함에 따라 근수는 감소하였으며, Alanap, (o-chlorophenyl) phthalamic acid는 근단에 심한 약해가 일어났다. 4) 전근시험에서 근수는 공시약제에 의하여 증가되었으나 50-200ppm의 농도에서 별 영향이 없었다.(표 8, 그림 2) 근장은 농도가 증가함에 따라 감소되는 영향이었으나 공시약제에는 상이한 효과를 보였다. 5) 이상 결과에서 p-chlorophenyl phthalamic acid 및 3,4-dichlorophenyl phthalamic acid가 수도용 식물생장조절제로서 실용적 개발의 가능성을 보였다.

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Crystal Chemistry and Paragenesis of Aluminum Sulphates from Mudstones of the Yeonil Group (I): basaluminite, hydrbasaluminite, and metabasaluminite (연일층군 이암에서 산출되는 알루미늄 황산염 광물의 결정화학 및 생성 (I): 배사알루미나팅, 하이드로베사알루미나이트 및 메타배사알루미나이트)

  • 노진환
    • Journal of the Mineralogical Society of Korea
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    • v.11 no.1
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    • pp.1-12
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    • 1998
  • In Pohang area, basaluminite accompanying a little amounts of hydrobasalumnite, super-genetically occurs as whitish cryptocrystalline (2-4 $\mu\textrm{m}$) clay-like aggregates in the vicinity of altered carbonate concretions embedded within mudstones of the Tertiary Yeonil Group. A hydrobasaluminite changed readily into a basaluminite at room temperature in air, and, in turn, into a metabasaluminite when heating to 150$^{\circ}$~30$0^{\circ}C$. For the basaluminite, a monoclinic unit-cellparameters (a=14.845$\AA$, b=10.006$\AA$, c=11.082$\AA$, $\beta$=122.15$^{\circ}$) were calculated by X-ray powder diffraction data. Its basal reflections (001 and 002) are XRD analyses strongly indicate that the aluminum sulphate mineral has a layer structure and, at least, three types of water, i.e., (1) interlayer water (9.0 wt %), (2) crystal water (8.0 wt %), and (3) structural water (19.0 wt %). may present in its lattice. Based on TG-DTG data combined with EDS and IR analyses, a new chemical formula of Al5SO4(OH)134H2O was given to the basaluminite. Field occurrence and stable isotope data ($\delta$18O, $\delta$D, $\delta$34S) for the basaluminite seem to reflect that it was formed by the leached meteoric solution from surrounding mudstones during or after uplifting. An interaction of the acid solution with carbonate concretion and the resultant local neutralization of the fluid rich in Al3+ and SO42- are major controls on the basaluminite formation.

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