• 제목/요약/키워드: D.B.H. analysis

검색결과 1,378건 처리시간 0.035초

DFT Studies on Two Novel Explosives Based on the Guanidine-Fused Bicyclic Structure

  • Jin, Xing-Hui;Hu, Bing-Cheng;Jia, Huan-Qing;Liu, Zu-Liang;Lu, Chun-Xu
    • Bulletin of the Korean Chemical Society
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    • 제35권4호
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    • pp.1043-1049
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    • 2014
  • Density functional theory (DFT) calculations at the B3LYP/6-31G(d,p) theoretical level were performed for two novel explosives (compounds B and C) based on the guanidine-fused bicyclic skeleton $C_4N_6H_8$ (A). The heats of formation (HOFs) were calculated via isodesmic reaction. The detonation properties were evaluated by using the Kamlet-Jacobs equations. The bond dissociation energies (BDEs) for the thermolysis initiation bond were also analyzed to investigate the thermal stability. The results show that the compounds have high positive HOF values (B, 1064.68 $kJ{\cdot}mol^{-1}$; C, 724.02 $kJ{\cdot}mol^{-1}$), high detonation properties (${\rho}$, D and P values of 2.04 $g{\cdot}cm^{-3}$ and 2.21 $g{\cdot}cm^{-3}$, 9.98 $km{\cdot}s^{-1}$ and 10.99 $km{\cdot}s^{-1}$, 46.44 GPa and 59.91 Gpa, respectively) and meet the basic stability requirement. Additionally, feasible synthetic routes of the these high energy density compounds (HEDCs) were also proposed via retrosynthetic analysis.

돼지 로타바이러스(Gottfried 주)의 VP4 항원구조분석 (Analysis of antigenic sites on the VP4 of porcine rotavirus, Gottfried strain)

  • 송윤경;김원용;강신영
    • 대한수의학회지
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    • 제41권3호
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    • pp.343-350
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    • 2001
  • The neutralization epitopes of the outer capsid protein VP4 of a porcine rotavirus, Gottfried strain, were studied using neutralizing monocolonal antibodies(N-MAbs). Eight N-MAbs which are specific for the VP4 of Gottfried strain were used for analyzing the antigenic sites of VP4. Three different approaches were used for this analysis; i)testing the serological reactivity of each N-MAb against different G and P types of human and animal rotavirusese ii) analyzing N-MAb-resistant viral escape mutants and iii) performing nucleotide sequence analysis of the VP4 gene of each N-MAb-resistant viral escape mutant. From experimental results, at least four antigenic sites(I, II, III, and IV) were identified. Antigenic site I recognized by N-MAbs 24B9, 23G10, and 26A2 was separated from antigenic site II recognized by N-MAbs 30H5, 32B3, and 29B3. However, these antigenic sites were overlapped with antigenic site III recognized by N-MAb 21A1. The other antigenic site IV recognized by N-MAb 16D2 was separated from antigenic sites I, II, and III.

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Thermodynamic Analysis of Intergranular Additives in Sintered Nd-Fe-B Magnet

  • Cui, X.G.;Wang, X.H.;Cui, C.Y.;Yin, G.C.;Xia, C.D.;Cheng, X.N.;Xu, X.J.
    • Journal of Magnetics
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    • 제22권2호
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    • pp.244-249
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    • 2017
  • To get deeper insight into the effect of intergranular additives in sintered Nd-Fe-B magnet and consequently improve the properties better, the interaction between additives (oxide, nitride, and carbide) and Nd-rich phase in the temperature range of 298.15-1400 K was analyzed thermodynamically. It can be found that the oxide additives became less stable than nitrides and carbides. Except for calcium oxide, almost all oxides could react with Nd from Nd-rich phase. To be different from oxide additives, the mechanism of nitrides and carbides was defined with various elements, either reaction with Nd from Nd-rich phase or not. The two different mechanisms would show different effects on the microstructure and hence properties of magnet. The thermodynamic analysis had a better agreement with the experimental information.

연결발화에서 마비말화자의 음질 특성 (Voice Quality of Dysarthric Speakers in Connected Speech)

  • 서인효;성철재
    • 말소리와 음성과학
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    • 제5권4호
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    • pp.33-41
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    • 2013
  • This study investigated the perceptual and cepstral/spectral characteristics of phonation and their relationships in dysarthria in connected speech. Twenty-two participants were divided into two groups; the eleven dysarthric speakers were paired with matching age and gender healthy control participants. A perceptual evaluation was performed by three speech pathologists using the GRBAS scale to measure the cepstrual/spectral characteristics of phonation between the two groups' connected speech. Correlations showed dysarthric speakers scored significantly worse (with a higher rating) with severities in G (overall dysphonia grade), B (breathiness), and S (strain), while the smoothed prominence of the cepstral peak (CPPs) was significantly lower. The CPPs were significantly correlated with the perceptual ratings, including G, B, and S. The utility of CPPs is supported by its high relationship with perceptually rated dysphonia severity in dysarthric speakers. The receiver operating characteristic (ROC) analysis showed that the threshold of 5.08 dB for the CPPs achieved a good classification for dysarthria, with 63.6% sensitivity and the perfect specificity (100%). Those results indicate the CPPs reliably distinguished between healthy controls and dysarthric speakers. However, the CPP frequency (CPP F0) and low-high spectral ratio (L/H ratio) were not significantly different between the two groups.

위성 DMB 중계기용 Cavity-Backed슬롯 배열 안테나 (Cavity-Backed Slot Array Antenna for a Repeater System of a Satellite Digital Multimedia Broadcasting)

  • 정희철;이학용;정병운;강기조;박면주;이병제
    • 한국전자파학회논문지
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    • 제16권4호
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    • pp.366-372
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    • 2005
  • 본 논문에서는 $2,630\;\cal{MHz}\~2,655\;\cal{MHz\$의 위성 DMB(Digital Multimedia Broadcasting)의 지상 중계기 시스템에 적합한 낮은 부엽레벨과 높은 전후방 비를 갖는 슬롯배열 안테나를 제안하였다. 중계기용 안테나는 시스템의 특성상 고이득과 시스템간의 신호 간섭을 줄이기 위해 충분한 격리도가 확보되어야 하며, 이를 위해서는 안테나의 부엽레벨을 억제시키고, 전후방 비는 증대시켜야 한다. 제안된 안테나는 도파관 구조의 직접급전이 가능한 CBSA(Cavity-Backed Slot Array) 안테나이다. 일반적인 마이크로 스트립 급전라인을 이용한 구조와는 달리 유전체 손실이나 급전라인의 손실이 없는 공기를 매질로 하므로, 고출력에 적합하며, 고효율을 가진다. 또한 tapered 배열 방식과 최적화된 수직 반사판을 이용하여 부엽레벨 및 전후방 비를 개선하고 이득을 증대시켰다. 제작 및 측정을 통하여 부엽레벨은 수평 및 수직면에서 각각 $-33.24\;\cal{dB}$ 이하, $-35.78\;\cal{dB}$ 이하를 얻었고 전후방비는 $37.84\;\cal{dB}$ 이상, 이득은 전 대역에서 $17\;\cal{dBi}$ 이상을 얻었다.

A new hybrid HSDT for bending, free vibration, and buckling analysis of FGM plates (2D & quasi-3D)

  • Belkhodja, Y.;Ouinas, D.;Fekirini, H.;Olay, J.A. Vina;Achour, B.;Touahmia, M.;Boukendakdji, M.
    • Smart Structures and Systems
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    • 제29권3호
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    • pp.395-420
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    • 2022
  • A new hybrid quasi-3D and 2D high-order shear deformation theory is studied in this mathematical formulation, for an investigation of the bending, free vibrations and buckling influences on a functionally graded material plate. The theoretical formulation has been begun by a displacement field of five unknowns, governing the transverse displacement across the thickness of the plate by bending, shearing and stretching. The transverse shear deformation effect has been taken into consideration, satisfying the stress-free boundary conditions, especially on plate free surfaces as parabolic variation through its thickness. Thus, the mechanical properties of the functionally graded plate vary across the plate thickness, following three distributions forms: the power law, exponential form and the Mori-Tanaka scheme. The mechanical properties are used to develop the equations of motion, obtained from the Hamilton principle, and solved by applying the Navier-type solution for simply supported boundary conditions. The results obtained are compared with other solutions of 2D, 3D and quasi-3D plate theories have been found in the literature.

로어투스의 롤오버 및 금형 면압 저감을 위한 하프블랭킹 공정 설계 (Design of Half Blanking Process for Reducing Rollover and Stress Acting on Tools in Forming of Lower Tooth)

  • 장명진;최홍석;이상훈;김동수;배재호;고대철;김병민
    • 소성∙가공
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    • 제20권3호
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    • pp.214-221
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    • 2011
  • In recent years, automotive seat components have been manufactured by the fine blanking process, allowing an improvement of dimensional accuracy at sheared surface in series production. However, the rollover has increased and die failures have occurred more frequently when manufacturing gears by fine blanking. Consequently, important goals for manufacturing seat recliner parts with gears have been to decrease the rollover as well as to improve the tool life. In this study, the half blanking and shaving processes were introduced to improve aforementioned problems for the lower tooth, the main component of a seat recliner. For this purpose, the half blanking process was optimized using the finite element (FE) analysis and design of experiment (DOE). The optimized conditions resulting from this study were an offset of 0.2 mm, a clearance of 0.1 mm and a penetration depth of 4.5 mm. Fine blanking experiment conducted under the optimal condition resulted in a rollover depth decrease from 1.9 to 1.3 mm, and no die failure occurrence.

Anti-tumor Promoting Activity of Some Malaysian Traditional Vegetable (Ulam) Extracts by Immunoblotting Analysis of Raji Cells

  • Ali, A.M.;Mooi, L.Y.;Yih, K. Yih;Norhanom, A.W.;Saleh, K. Mat;Lajis, N.H.;Yazid, A.M.;Ahmad, F.B.H.;Prasad, U.
    • Natural Product Sciences
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    • 제6권3호
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    • pp.147-150
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    • 2000
  • The extracts of Carica papaya (flower), Barringtonia macrostachya (leaves), Coleus tuberosus (tuber), Mangifera indica (fruit skin) and Eugenia polyantha (leaves) showed strong in vitro anti-tumor promoting activity when assayed using Raji cells (Mooi et al., 1999). The antitumor promoting activity of the crude extracts was further analyzed by immunoblotting analysis of Raji cells carving Epstein-Barr virus genome. The expression of early antigens diffuse (EA-D) and early antigens restricted (EA-R) was determined by performing western blotting of treated Raji cells with human sera of nasopharyngeal carcinoma patients. All the plant extracts were shown to be able to suppress both EA-D and EA-R.

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Mitochondrial DNA Diversity of Korean Ogol Chicken

  • Lee, Y.J.;Bhuiyan, M.S.A.;Chung, H.J.;Jung, W.Y.;Choi, K.D.;Jang, B.G.;Paek, W.K.;Jeon, J.T.;Park, C.S.;Lee, J.H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제20권4호
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    • pp.477-481
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    • 2007
  • Korean Ogol chicken has been registered as a natural monument in Korea and regarded as a valuable genetic resource for the world. As an initial step to investigate the genetic structures of this breed, phylogenetic analysis and calculation of genetic diversities have been performed using mitochondrial DNA (mtDNA) sequence variations. A total of 31 Korean Ogol chicken was grouped into four haplotypes and the large haplotype was represented in 12 individuals. The unrooted neighbor-joining tree indicates that the Korean Ogol chicken shared three (A to C) major chicken lineages representing the high genetic variability of this breed. These results can be used for making the breeding and conservation strategies for the Korean Ogol chicken.

웹 기반 자동차용 엔진 풀리 설계 지원 시스템 (Web-based Design Support System for Automotive Engine Pulley)

  • 김형중;천두만;안성훈;황범철;장재덕
    • 한국정밀공학회:학술대회논문집
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    • 한국정밀공학회 2006년도 춘계학술대회 논문집
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    • pp.639-640
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    • 2006
  • Many companies in mechanical engineering fields have accumulated information of design and manufacturing. The Enterprise Resource Planning (ERP) and Product Data Management (PDM) systems help information gathering and data managing. However, these systems are not flexible to support suitable functionality for specific product because these systems deal with entire enterprise resources. To cope with this issue, a web-based design support system was constructed for the design process of automotive steel pulley. This system provided 1) search service for part design with key word and clustering map, and 2) estimation service of maximum stress. These services reduced design time by reducing iterative jobs with Computer Aided Design (CAD) and Computer Aided Engineering (CAE) for stress analysis, and by enhancing search for existing data of steel pulley.

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