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Study of Molecular Reorientation in Liquid with Raman Spectroscopy(III). Temperature Dependence of Molecular Rotation of $C_6F_6$ in Neat Liquid (액체분자의 재배치 운동에 관한 라만 분광법적 연구 (제3보) 순수한 $C_6F_6$ 액체분자의 회전운동에 대한 온도의 영향)

  • Myung Soo Kim
    • Journal of the Korean Chemical Society
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    • v.28 no.1
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    • pp.34-40
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    • 1984
  • The reorientational motion of $C_6F_6$ in neat liquid is investigated in the temperature range 293∼333K by analyzing ${\nu}_2$ and ${\nu}_16$ bands of its Raman spectrum. Diffusion constants for the tumbling ($D_{\bo}$) and spinning ($D_{\parallel}$) motions are determined. The reorientation of the molecule seems to be distinctly anisotropic. Based on the hydrodynamic model, the tumbling motion of the figure axis of $C_6F_6$ is largely diffusional. On the other hand, the spinning motion of the same axis looks mostly inertial.

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Effect of the Fish Oil Fortified Chitosan Edible Film on Microbiological, Chemical Composition and Sensory Properties of Göbek Kashar Cheese during Ripening Time

  • Yangilar, Filiz
    • Food Science of Animal Resources
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    • v.36 no.3
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    • pp.377-388
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    • 2016
  • Objective of the present study is to investigate the effect of coated edible films with chitosan solutions enriched with essential oil (EO) on the chemical, microbial and sensory properties of Kashar cheese during ripening time. Generally, no differences were found in total aerobic mesophilic bacteria, streptococci and lactoccocci counts among cheeses but these microorganism counts increased during 60 and 90 d storage especially in C1 (uncoated sample) as compared with coated samples. Antimicrobial effectiveness of the films against moulds was measured on 30, 60, and 90 d of storage. In addition of fish EO into chitosan edible films samples were showed to affect significantly decreased the moulds (p<0.05) as 1.15 Log CFU/g in C4 (with fish oil (1% w/v) fortified chitosan film) on the 90th d, while in C1 as 3.89 Log CFU/g on the 90th d of ripening. Compared to other cheese samples, C2 (coated with chitosan film) and C4 coated cheese samples revealed higher levels of water-soluble nitrogen and ripening index at the end of storage. C2 coated cheese samples were preferred more by the panellists while C4 coated cheese samples received the lowest scores.

The Crystal and Molecular Structure of Fluocinolone Acetorlide $(C_{24}H_{30}F_2O_8)$ (FloucinoloneAcetonide의 결정 및 분자구조)

  • Jeong, Jong-Sun;Jo, Seong-Il;Jeong, Yong-Je
    • Korean Journal of Crystallography
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    • v.3 no.1
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    • pp.31-36
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    • 1992
  • 6, 9-Difluoro-11, 21-dihydroxyl-16, 17-[(1methylehtylidene)bis(oxy)]-pregna-1, 4-diene-3, 20-dione (fluorocinolone acetonide) , C24H3OF106, trigonal, R3 (defined as a hexagonal lattice), a =b = 17.896 k, c: 18.365 k, V=5094.3 A', Z=9, 1 (MoK a) =0.7107 A, D=1.31 g/cm3, D.: 1.328 g/cm3 T=298 K, final R=0.050 for 1101 unique observed reflections. The molecule has conformational features in common with other corticosteroids. Three molecules related by 3-fold symmetry are involved in hydrogen bonding, forming a layer of molecules perpendicular to the c-axis.

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The Effect of the Thermal Stress on the Transport Property of Pocheon Granite (열응력이 포천화강암의 투수성에 미치는 영향)

  • Yoon, Yong-Kyun
    • Tunnel and Underground Space
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    • v.7 no.3
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    • pp.238-245
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    • 1997
  • A transient pulse methos has been used to measure the permeability of Pocheon granite pre-heated from $25^{\circ}C$ to $600^{\circ}C$ at effective pressure up to 32MPa. The permeability of whole rock ranged from 0.72 $\mu$d at 10MPa to 0.20 $\mu$d at 32MPa. The permeability of rock heated to $600^{\circ}C$ ranged from 18.07$\mu$d at 10MPa to 6.39$\mu$d at 32MPa. Confining pressure has greater effects on the rocks thermally treated to lower thermal-cycle temperatures than on the higher thermally treated rocks. The increase of permeability is most pronounced between 40$0^{\circ}C$ and $600^{\circ}C$. Below 40$0^{\circ}C$, permeability increase is expected to be associated with the formation of new cracks and widening of preexisting cracks, whereas above 40$0^{\circ}C$, permeability increase is expected to reflect widening of cracks. Using the equivalent channel model, author shows that the exponent n in the relationship relating the permebility(k) to porosity($\phi$) by k∝$$\phi$^n$ falls in the range 2.7$\leq$n$\leq$3.0.

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The structural properties of the (Ba,Bi,Sr)$TiO_3$ceramics with sintering temperature (소결온도에 따른 (Ba,Bi,Sr)$TiO_3$세라믹스의 구조적 특성)

  • 남규빈;최의선;김지헌;이문기;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.693-696
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    • 2001
  • The (Ba$_{0.3}$Bi$_{0.3}$Sr$_{0.4}$)TiO$_3$[BBST] ceramics were prepared by conventional mixed oxide method. The structural properties of the BBST ceramics with sintering temperature were investigated by XRD, SEM, EDS. In the case of BBST ceramics sintered at 1150~135$0^{\circ}C$, the $Ba_{0.5}$Sr$_{0.5}$TiO$_3$and SrBi$_4$Ti$_4$O$_{15}$ phase were coexisted. The 2$\theta$ value of the BST (110) peaks were shifted to the lower degree at the sintering temperature of 130$0^{\circ}C$ and 135$0^{\circ}C$. The grains of the BBST ceramics sintered at 130$0^{\circ}C$ and 135$0^{\circ}C$ were not appeared. Increasing the sintering temperature, the densities of the BBST ceramics were increased. In the BBST ceramics sintered at 130$0^{\circ}C$ and 135$0^{\circ}C$, the mole ratio of Bi was decreased.d.ed.d.d.d.

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Identification and Association of SNPs in TBC1D1 Gene with Growth Traits in Two Rabbit Breeds

  • Yang, Zhi-Juan;Fu, Lu;Zhang, Gong-Wei;Yang, Yu;Chen, Shi-Yi;Wang, Jie;Lai, Song-Jia
    • Asian-Australasian Journal of Animal Sciences
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    • v.26 no.11
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    • pp.1529-1535
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    • 2013
  • The TBC1D1 plays a key role in body energy homeostasis by regulating the insulin-stimulated glucose uptake in skeletal muscle. The present study aimed to identify the association between genetic polymorphisms of TBC1D1 and body weight (BW) in rabbits. Among the total of 12 SNPs detected in all 20 exons, only one SNP was non-synonymous (c.214G>A. p.G72R) located in exon 1. c.214G>A was subsequently genotyped among 491 individuals from two rabbit breeds by the high-resolution melting method. Allele A was the predominant allele with frequencies of 0.7780 and 0.6678 in European white rabbit (EWR, n = 205) and New Zealand White rabbit (NZW, n = 286), respectively. The moderate polymorphism information content (0.250.05). Our results implied that the c.214G>A of TBC1D1 gene might be one of the candidate loci affecting the trait of 35 d BW in the rabbit.

Development and Verification of Thermal Control Subsystem for High Resolution Electro-Optical Camera System, EOS-D Ver.1.0 (고해상도 전자광학카메라 EOS-D Ver.1.0의 열제어계 개발 및 검증)

  • Chang, Jin-Soo;Kim, Jong-Un;Kang, Myung-Seok;Yang, Seung-Uk;Kim, Ee-Eul
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.41 no.11
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    • pp.921-930
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    • 2013
  • Satrec Initiative successfully developed and verified a high-resolution electro-optical camera system, EOS-D Ver.1.0. We designed this system to give improved spatial and radiometric resolution compared with EOS-C series systems. The thermal control subsystem (TCS) of the EOS-D Ver.1.0 uses heaters to meet the opto-mechanical requirements during in-orbit operation and uses different thermal coatings and multi-layer insulation (MLI) blankets to minimize the heater power consumption. Also, we designed and verified a refocusing mechanism to compensate the misalignment caused by moisture desorption from the metering structure. We verified the design margin and workmanship by conducting the qualification level thermal vacuum test. We also performed the verification of thermal math model (TMM) by comparing with thermal balance test results. As a result, we concluded that it faithfully represents the thermal characteristics of the EOS-D Ver.1.0.

The Mechanical Properties of Fluffy Spun-like Yarn by ATY Textured (1) (ATY 사가공에 의한 Fluffy Spun-like Yarn의 물성 (1))

  • Park, Myung Soo
    • Textile Coloration and Finishing
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    • v.25 no.3
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    • pp.223-231
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    • 2013
  • This research has a main focus on providing fundamental data for on-the-spot industrial fields by comparing and contrasting physical properties of fluffy spun-like material. The fluffy spun-like yarn is developed as fluffy yarn similar to natural spun-like yarn by treating polyester(FDY and + type shaped DTY) with ATY machine. In this experiment, using ATY machine for raw material texturing, we produced two fluffy yarns: (i) + type shaped(50d/36f, DTY) as core yarn and 100d/192f FDY as effect yarn[ATY(D)], (ii) FDY(75/36) as core yarn and 100d/192f FDY [ATY(F)] as effect yarn. After producing thous yarns, we twisted them with 500T/M, 700T/M, 1000T/M, respectively. produced yarns through this process were used as the samples for this experiment. Even though the shrinkage of fluffy yarn ATY(F) and ATY(D) becomes high as treated temperature rises and treated time lengthens, it is more affected by treated temperature then by treated time. In this experiment, produced fluffy yarn[ATY(D)] shows a little high values for temperature, but almost same values for higher temperatures. When we compare ATY(F) with ATY(D) fluffy yarn shows more natural fluffy yarn surface structure like natural cotton. The shrinkage of 700T/M twisted ATY(D) fluffy yarn show about 11% under treated temperature $180^{\circ}C$ and treated time 30min, and about 7% under $120^{\circ}C$ and 30min, respectively. But the shrinkage of 1000T/M fluffy yarn shoes about 9% and 6% under same conditions. Regarding treated time, tenacity and initial modulus of ATY(D) fluffy yarn rise high until 30min, but do not show much increase above 30min. Regarding treated temperature, tenacity and initial modulus of it rise high aboyer $140^{\circ}C$.

COMPOSITION OPERATORS ON 𝓠K-TYPE SPACES AND A NEW COMPACTNESS CRITERION FOR COMPOSITION OPERATORS ON 𝓠s SPACES

  • Rezaei, Shayesteh
    • Communications of the Korean Mathematical Society
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    • v.32 no.1
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    • pp.55-64
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    • 2017
  • For -2 < ${\alpha}$ < ${\infty}$ and 0 < p < ${\infty}$, the $\mathcal{Q}_K$-type space is the space of all analytic functions on the open unit disk ${\mathbb{D}}$ satisfying $$_{{\sup} \atop a{\in}{\mathbb{D}}}{\large \int_{\mathbb{D}}}{{\mid}f^{\prime}(z){\mid}}^p(1-{{\mid}z{\mid}^2})^{\alpha}K(g(z,a))dA(z)<{\infty}$$, where $g(z,a)=log\frac{1}{{\mid}{\sigma}_a(z){\mid}}$ is the Green's function on ${\mathbb{D}}$ and K : [0, ${\infty}$) [0, ${\infty}$), is a right-continuous and non-decreasing function. For 0 < s < ${\infty}$, the space $\mathcal{Q}_s$ consists of all analytic functions on ${\mathbb{D}}$ for which $$_{sup \atop a{\in}{\mathbb{D}}}{\large \int_{\mathbb{D}}}{{\mid}f^{\prime}(z){\mid}}^2(g(z,a))^sdA(z)<{\infty}$$. Boundedness and compactness of composition operators $C_{\varphi}$ acting on $\mathcal{Q}_K$-type spaces and $\mathcal{Q}_s$ spaces is characterized in terms of the norms of ${\varphi}^n$. Thus the author announces a solution to the problem raised by Wulan, Zheng and Zhou.

A STUDY ON THE DIFFUSE ATTENUATION COEFFICIENT OF DOWN-WELLING IRRADIANCE AROUND THE YELLOW SEA

  • Min, Jee-Eun;Ahn, Yu-Hwan;Ryu, Joo-Hyung;Lee, Kyu-Sung
    • Proceedings of the KSRS Conference
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    • v.1
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    • pp.459-462
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    • 2006
  • The diffuse attenuation coefficient for down-welling irradiance ($K_d$) is an important parameter for ocean studies including remote sensing applications. For the vast ocean, ocean color remote sensing is the only possible means to get the fine-scale measurements of $K_d$. To develop a technique of estimating $K_d$ from remotely sensed data, the following underwater optical parameters (absorption coefficient (a), attenuation coefficient (c), scattering coefficient (b), diffuse attenuation coefficient ($K_d$), etc.) have been studied. For this research we conducted the field campaign around the Yellow Sea at $8{\sim}9$ June, 2006. We obtained a set of underwater optical parameter data: down-welling irradiance ($E_d$), up-welling irradiance ($E_u$) and up-welling radiance ($L_u$) using TriOS optical sensors and a, c coefficient using Spectral Absorption and Attenuation Meter (AC-S). We then derived $K_d$ values from $E_d$ for each depth.

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