• Title/Summary/Keyword: Cycloisomerization

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Gold-Catalyzed Cycloisomerization of (2-Alkynyl-1-cycloalkenyl)methanols to Highly Substituted Furans

  • Oh, Chang-Ho;Yi, Hyun-Jik;Lee, Kyu-Hwan
    • Bulletin of the Korean Chemical Society
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    • v.31 no.3
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    • pp.683-688
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    • 2010
  • A new and efficient Au-catalyzed alkoxycyclization of conjugated enynols offers a general entry to a wide range of highly substituted furans in good to excellent yields. These furans were subjected to diethyl acetylenedicarcoxylate to afford the interesting cycloadducts in good to excellent yields.