• Title/Summary/Keyword: Cyclicvoltammetry

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Electrochemical Sensor for Detecting Underwater Biofilm Using Cyclicvoltammetry (순환전압전류법을 이용한 수중 생물막 측정 전기화학센서)

  • Hwang, Byeong-Jun;Lee, Sung-Ho
    • Journal of Sensor Science and Technology
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    • v.21 no.5
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    • pp.374-378
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    • 2012
  • Biofouling causes many problem in industrial processes, medical health industries, water utilities and our daily life. So detecting formation of biofilm on the surface of medical appliance, water pipe and industrial utility is highly important to prevent the problem caused by biofouling. In this study, we suggest an electrochemical sensor for detecting biofilm. We fabricated the electrochemical sensor in MEMS process and cultivated two different kinds of Pseudomonas aeruginosa RpoN type and Wild type on the surface of electrochemical sensor. Each group of Pseudomonas aeruginosa was cultivated according to the hours of 2, 4, 6, 8, 12 and 24. Then we investigated changes in degree of biofilm cultivation using cyclic voltammetry. As a result, it was observed that peak of the cyclic voltammetry curve is increased according as the biofilm growth on the surface of electrochemical sensor. Also we can discern between Pseudomonas aeruginosa RpoN type and Wild type.

A Study on the Electronic Properties of Poly-$\gamma$ Benzyl $_D$-Glutamate Organic Thin Films (Poly-${\gamma}$ Benzyl $_D$-Glutamate 유기박막의 전자이동특성에 관한 연구)

  • Song, Jin-Won;Lee, Kyung-Sup;Lee, Bong-Ju;Gu, Hal-Bon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.05b
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    • pp.86-89
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    • 2002
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al and Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Au; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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A Study on the Interface Properties of Metal/Organic Films/Metal (Metal/Organic Films/Metal에서 계면특성에 관한 연구)

  • Song, Jin-Won;Cho, Su-Young;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.723-726
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    • 2002
  • We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-$\gamma$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Electrochemical Study for 1,3-Bisdicyanovinylindane

  • Kim, Hyungjoo;Rao, Boddu Ananda;Son, Young-A
    • Textile Coloration and Finishing
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    • v.25 no.2
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    • pp.89-93
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    • 2013
  • The electrochemical study has been enjoyed in many areas of chemistry. Through this approach using electrochemical measurement, empirical HOMO and LUMO values can be calculated by three methods such as absorption measurement, cyclicvoltammetry and computational calculations. In this study, 1,3-bisdicyanovinylindane was prepared and investigated toward its optical properties. The absorption intensities were changed depending on changes of pH. These absorption changes are induced by resonance form of 1,3-bisdicyanovinylindane. The electron delocalization in ${\pi}$ system is related to the resonance form. In according to this electron density distribution and HOMO/LUMO values of 1,3-bisdicyanovinylindane were simulated and calculated by Material Studio 4.3, absorption measurement and cyclicvoltammograms. The 1,3-bisdicyanovinylindane is one of the most attracted acceptor units in D-${\pi}$-A system. This attempt is useful to determine more detailed characteristics of the energy potentials.

A Study on the Electronic Properties of LB Thin Films (LB박막의 전자이동 특성에 관한 연구)

  • Song, Jin-Won;Choi, Young-Il;Lee, Kyung-Sup
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.08a
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    • pp.101-104
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    • 2002
  • Abstract We give pressure stimulation into organic thin films and then manufacture a device under the accumulation condition that the state surface pressure is 10[mN/m]. In processing of a device manufacture, we can see the process is good from the change of a surface pressure for organic thin films and transfer ratio of area per molecule. The structure of manufactured device is Au/Poly-${\gamma}$ Benzyl $_D$-Glutamate/Al; the number of accumulated layers is 1, 3, 5 and 7. Also, we then examined of the MIM device by means of I-V. The I-V characteristic of the device is measured from 0 to +2[V]. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system. LB film accumulated by monolayer on an ITO. In the cyclicvoltammetry, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $LiBF_4$ solution, stable up to 0.9V vs. Ag/AgCl.

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Surface Characteristics and Photoelectrochemical Properties of the Polyphridine LB films (폴리피리딘계 LB 단분자막의 표면측정과 전기화학적 감광특성)

  • 최인희;나재진;임기조;박수길;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1995.05a
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    • pp.132-135
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    • 1995
  • This paper describes the electrochemical and photochemical behavior of amphiphilic Os bipyridine compelx adsorbed on SnO$_2$electrodes by the Langmuir-Blodgett(LB) film as monolayer state. Theoretical equation of cyclicvoltammetry for redox species were discussed. And the cyclic voltammogram were simulated taking account theinteraction parameters. From these obtained values, we could fit almost all measured voltammograms with these parameters.

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Electrochemical Analysis of CdTe Deposition Using Cyclovoltammetric Method for Hybrid Solar Cell Application (나노복합 태양전지를 위한 CdTe 전착 거동의 순환전류법을 이용한 전기화학적 분석)

  • Kim, Seong-Hun;Han, Wone-Keun;Jin, Hong-Sung;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.42 no.5
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    • pp.197-202
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    • 2009
  • The electrodeposition in acidic aqueous electrolyte bath of cadmium telluride on gold electrodes has been studied by electrochemical analysis. Conventional cyclic voltammetry using potentiostat is considered as a reliable method to study electrochemical behavior of electrodeposition of CdTe. In this paper, the mechanism of CdTe deposition and its cyclic voltammetry were studied with the Te ion concentration, temperature, potential, and scan rate. We also investigated surface morphologies using FESEM and atomic composition of Cd and Te using EDS. Atomic composition of Cd and Te were varied with Te ion concentration in the electrolyte.

Study of HOMO and LUMO Energy Levels for Spirolactam Ring Moiety Using Electrochemical Approach

  • Kim, Hyungjoo;Lee, Sehoon;Son, Young-A
    • Textile Coloration and Finishing
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    • v.25 no.2
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    • pp.83-88
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    • 2013
  • Rhodamine dyes have been studied in various scientific areas due to their excellent photophysical properties. In particular, these rhodamine dyes are one of the most famous fluorophores as signal unit in chemosensor study. This is related to spirolactam ring system in rhodamine dyes. When the spirolactam ring is closed, there is nonfluorescence and colorless. Whereas, ring-opening of the corresponding spirolactam induces strong fluorescence and color. These absorption and emission changes are related to structural changes as well as electron energy potential levels such as HOMO and LUMO values. In this study, two different structures of rhodamine 6G hydrazide depending on the spirolactam ring system were investigated using absorption measurement, electrochemical measurement and computational calculations.

Synthesis and Characterization of properties for Iridium Complexes (Ir 착체의 합성과 특성에 관한 연구)

  • Kim, Dong-Hwan;Kim, Hwa-Seon;Kwak, Ji-Hoon;Lee, Ji-Hoon;An, Ho-Guen;Chung, Min-Chul
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.437-438
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    • 2007
  • A Iridium complexes has been synthesised from the reaction of [$lr(ppy)_2Cl_2$] with 5-bromo-2.2'-bipyridine, 5-Ethynyl-2.2'-bipyridine Characterization of the complexes were by FT-IR, $^1H(^{13}C)$-NMR and photo-, electro-chemistry properties were showed by UV-vis, Cyclicvoltammetry, Photoluminescence.

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전해증착법을 이용한 결정성 ZnTe 나노와이어 성장 및 특성평가

  • Kim, Dong-Uk;Rajakumar, Shanmugam;Park, Gi-Mun;Yu, Bong-Yeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2011.05a
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    • pp.39.1-39.1
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    • 2011
  • 본 연구에서는 전해증착법을 이용하여 결정성 ZnTe 나노와이어를 성장시켰고, 구조적 및 전기적 특성을 평가하였다. 또한 나노와이어 성장에 앞서, 결정성 ZnTe 박막을 전해증착법으로 형성하였고, 그 박막의 특성을 관찰하였다. 화학양론적(stoichiometric) 조성을 가지는 박막을 성장시키기 위하여, 순환전류전압법(cyclicvoltammetry)을 이용하여 Zn, Te, 이온들과 구연산 착화체(citrate-complexes)로 구성된 수용액 전해질에서 각 원소의 환원전위 분석이 이루어졌고, 과전압(overpotential)과 전해질 온도와 농도등과 같은 전해증착 조건에 따라 박막을 증착하였다. 각 조건에서 전해증착된 박막은 주사전자현미경(SEM)과 EDS를 이용하여 표면과 두께 그리고 성분분석을 하였고, XRD 분석법을 이용하여 박막의 결정성 변화를 관찰하였다. 박막증착 실험에서의 알맞은 증착조건을 나노와이어 전해증착실험에 적용하여, 다공성의 양극산화알루미늄(Anodic Aluminium Oxide, AAO) 템플레이트를 이용하여 bottom-up 방식으로 결정성 ZnTe 나노와이어를 성장시켰다. 수산화 나트륨(NaOH)용액을 이용하여 템플레이트를 선택적으로 에칭하여 제거한 후, ZnTe 나노와이어의 구조적 및 전기적 특성을 분석하였다.

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