• 공업화학
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• 제2권4호
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• pp.311-329
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• 1991

산화주석전극 위에 LB 법에 의해 단분자층상으로 흡착된 양친매성 Os 착체의 전기화학적 거동을 살펴보았다. 또한 단분자막형태로 흡착된 redox 종의 전극반응의 이론식을 가역, 비가역, 준가역파에 대하여 검토하였고, 이들막이 진공증착된 $SnO_2$ 전극 위로 전이될 때, 그 전극에서 흐른 전체 전하를 cyclic voltammogram 의 그림적분법에 의해 구하였다. 그리고 이들 단분자막을 이용한 전자이동 중개반응의 응용면도 $Fe^{2+}$, TEMPOL 등을 이용해 해석하였다. 이들 측정된 cyclic voltammogram을 이론식으로부터 유도하여 분자들간의 상호작용 parameter를 고려해서 simultation 하였다. 이들로부터 구해진 parameter 들은 측정된 cyclic voltammogram 과 거의 일치함을 확인할수 있었다. 마지막으로 LB 법을 이용한 최근의 연구동향 및 응용분야를 소개하였다.

• 센서학회지
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• 제30권6호
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• pp.384-387
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• 2021

Cyclic voltammetry (CV) is a powerful electrochemical measurement technique that can determine redoxable substances in a solution. The advantage of CV is that we can observe redox behavior over a wide potential range in a short time. Because of its practicality and versatility, CV is used not only in electrochemistry but also in various fields of chemistry, such as inorganic chemistry, organic chemistry, and biochemistry. As technology advances and the popularity of CV grows, the need for trained electrochemists also increases. However, most students do not receive formal training in these technologies as part of their curriculum. There are few concise and accessible resources for learning CV. Therefore, this manuscript provides a brief introduction to cyclic voltammetry to aid readers in collecting and interpreting useful data from cyclic voltammograms.

• 방사성폐기물학회지
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• 제15권4호
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• pp.313-320
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• 2017

LiCl-KCl 용융염에서 광학적으로 투명한 텅스텐 망으로 제작된 작업전극에 대해 사마륨의 전기화학적 거동을 Cyclic voltammetry와 Potential step chronoabsorptometry의 전기화학적 및 분광전기화학적 방법으로 조사하였다. Cyclic voltammogram으로 결정된 $Sm^{3+}/Sm^{2+}$의 산화환원 반응의 가역성을 기반으로 형식전위와 확산계수를 계산하여 각각 -1.99 V vs. $Cl_2/Cl^-$와 $2.53{\times}10^{-6}cm^2{\cdot}s^{-1}$를 얻었다. 작업 전극에 -1.5 V vs. Ag/AgCl (wt%)로 전압을 인가하여 측정한 Chronoabsorptometry를 통해 사마륨 이온의 특성 파장으로 $Sm^{3+}$에 대해 408.08 nm, $Sm^{2+}$에 대해 545.62 nm를 확인하였다. Voltammogram에서 얻은 환원 피크 전압과 산화 피크 전압을 이용하여 Potential step chronoabsorptometry를 수행하였다. 545.63 nm의 흡광피크 값을 분석하여 $2.15{\times}10^{-6}cm^2{\cdot}s^{-1}$의 확산계수를 얻었으며 이 값은 동일한 온도에서 Cyclic voltammtry 분석으로 얻은 값과 큰 차이를 보이지 않았다. 실험결과로부터 고온 용융염에서 광학적으로 투명한 작업전극을 이용한 분광전기화학적 방법이 용융염에 용해된 이온의 종류를 확인하며 전기화학적 거동을 조사하는데 유용한 도구로 활용될 수 있음을 확인하였다.

• 자원리싸이클링
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• 제10권3호
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• pp.29-36
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• 2001

전기화학적 환원 반응을 이용하는 전기 분해에 의한 방법으로 중금속 폐수를 처리하여 금속성분을 회수하는데 있어 cyclic voltammetry를 적용하였다. 아연용액에서의 아연전극과 탄소전극에 대한 전기적 반응 특성은 voltammogram으로 확인할 수 있었으며 수중 아연이온 환원은 전위가 -0.76V 이하에서 반응이 일어나는 것을 알 수 있었다. 용액 중 아연이온의 산화와 환원으로 인해 형성되는 금속 특성은 X선 회절분석 결과를 통해서 확인할 수 있었으며, AFM 이용하여 구리판에 환원된 아연을 관찰할 수 있었다. 본 연구의 결과는 전기분해에 의한 폐수 중 중금속의 처리 및 회수에 있어 기초자료로 활용죌 수 있을 것으로 사료된다.

• KIEE International Transactions on Electrophysics and Applications
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• 제4C권4호
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• pp.133-136
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• 2004

This research aims to develop a DNA chip array without an indicator. We fabricated a microelectrode array through photolithography technology. Several DNA probes were immobilized on an electrode. Then, target DNA was hybridized and measured electrochemically. Cyclic-voltammograms (CVs) showed a difference between the DNA probe and mismatched DNA in an anodic peak. This indicator-free DNA chip resulted in a sequence-specific detection of the target DNA.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 춘계학술대회 논문집
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• pp.132-135
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• 1995

This paper describes the electrochemical and photochemical behavior of amphiphilic Os bipyridine compelx adsorbed on SnO$_2$electrodes by the Langmuir-Blodgett(LB) film as monolayer state. Theoretical equation of cyclicvoltammetry for redox species were discussed. And the cyclic voltammogram were simulated taking account theinteraction parameters. From these obtained values, we could fit almost all measured voltammograms with these parameters.

• Corrosion Science and Technology
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• 제3권2호
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• pp.54-58
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• 2004

Effects of texture on the electrochemical behaviors of single grains in polycrystalline zinc were investigated using a capillary-based micro-droplet cell. Pontiodynamic sweeps and capacity measurements were carried out in pH 9 borate buffer solution. The cyclic voltammograms and the capacity measurements on single grains with different crystallographic orientations in polycrystalline Zn showed a strong dependence of oxide growth on crystallographic grain orientation. The total charge consumed for oxide formation and the inverse capacity increased with an increase of surface packing density of grain. suggesting the oxide formation was greater on grains with higher surface packing density.

• 한국산업융합학회 논문집
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• 제19권4호
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• pp.198-205
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• 2016

For the study on the ion exchange of nickel hexacyanoferrate(NiHCNFe) electrode with the several cations, the film of hexacyanoferrate was prepared on the bare nickel surface by the electrochemical and chemical methods in the solution composed with 5mM K3Fe(CN)6 and 100mM KNO3. To compare the capability of the ion exchange of NiHCNFe film electrode, the repeated cyclic voltammograms were measured in the 0.5M cation nitrate solutions at $25^{\circ}C$ and pH7. It was found that the capacity of the electrochemically derivatized NiHCNFe reduced in the rate of 0.5~0.7%/cycle and was nearly exhausted at the 150th potential cycle. Better result was obtained from that the capacity loss of the chemically assembled NiHCNFe was less than 0.02%/cycle for 5,000cycles. Furthermore, the residual capacity was more than 30% at the 5,000th cycle.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1995년도 추계학술대회 논문집
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• pp.240-243
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• 1995

The basic electrochemical and photochemical behavior of ultrathin mono- and hetero-type LB film of amphiphilic Ru bipyridine complex adsorbed on ITO electrode by the Langmuir- Blodgett(LB) method as monolayer and alternating multilayer state. With theoretical equation of cyclic voltammetry for redox species, the cyclic voltammogram were simulated successfully taking account the interaction parameters. We could fit almost all measured voltammograms with k$^{\circ}$=72s$\^$-1/, ${\alpha}$$\sub$a/=0.44, ${\alpha}$$\sub$c/=0.54, $\Gamma$$\sub$T/=1.4${\times}$10$\^$-10/, k=0.015s$\^$-1/ values. The AFM images of mono and hetero type LB film surfaces on ITO were also studied.

• 한국환경과학회지
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• 제11권5호
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• pp.437-443
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• 2002

The chemical behavior and properties of the redox state of environmental pollutants were investigated using electrochemical methods. Cyclic voltammograms were performed on the compounds to measure the variations in the redox reactions. Temperature and pH were established as influencing the redox potential and current. The electrode reactions were a mixture of quasi-reversible and irreversible Precesses, which changed according to the reaction current. Although the Co(BPA)$_2$ and Cu(BPA)$_2$ compounds were not found to dissociate in wastewater, they were very unstable(K=1.02).