• 제목/요약/키워드: Cyclic modulation process

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Enhancement of the characteristics of carbon nanofibers by the on/off cyclic modulation of $C_2H_2/H_2$ flow

  • Kim, Sung-Hoon
    • 한국결정성장학회지
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    • 제17권4호
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    • pp.160-164
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    • 2007
  • Carbon nanofibers were deposited on silicon oxide substrate by thermal chemical vapor deposition method. For the enhancement of the characteristics of carbon nanofibers, the source gases ($C_2H_2,\;H_2$) flows were intentionally manipulated as the cyclic on/off modulation of $C_2H_2$ flow. By the cyclic modulation process during the initial deposition stage, the formation density of carbon nanofibers on the substrate could be much more enhanced. The diameter of as-grown carbon nanofibers was also reduced by the cyclic modulation process. The cause for the variation in the characteristics of carbon nanofibers by the cyclic modulation process was discussed in association with the hydrogen gas etching ability.

$CH_4/O_2$의 사이클릭 유량제어에 의한 다이아몬드 박막의 특성향상 (Cyclic on/off Modulation of $CH_4\;and/or\;O_2$ Flows for the Enhancement of the Diamond Film Characteristics)

  • 김태규;김성훈;윤수종
    • 한국표면공학회지
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    • 제39권2호
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    • pp.82-86
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    • 2006
  • Diamond films were deposited on 10.0$\times$10.0$mm^2$ pretreated (100) Si substrate using $CH_4$, $H_2$ and $O_2$ source gases in a horizontal-type microwave plasma enhanced chemical vapor deposition system. We introduced a cyclic on/off modulation of $CH_4$ and/or $O_2$ flows is a function of the reaction time during the initial deposition stage. Surface morphology and diamond quality of the films were investigated as a function of the different cyclic modulation process of the source gases flows: For the enhancement of the nucleation density, there is an optimal process for the incorporation of oxygen. Diamond qualities of the films were improved by introducing oxygen gas during the initial deposition stage.

C2H2/H2/SF6 기체들의 싸이클릭 유량 변조를 통한 탄소 나노 필라멘트 직경크기 조절 (Controlling the Diameter Size of Carbon Nanofilaments by the Cyclic on/off Modulation of C2H2/H2/SF6 Flow in a Thermal Chemical Vapor Deposition System)

  • 김광덕;김성훈
    • 한국진공학회지
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    • 제18권6호
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    • pp.481-487
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    • 2009
  • 탄소나노필라멘트의 직경크기를 조절하기 위하여 증착 반응초기에 $SF_6$를 증착원료기체($C_2H_2$, $H_2$)에 주입하였다. 증착 원료 기체와 $SF_6$를 열화학기상증착시스템에서 시간에 따라 싸이클릭 유량 변조시켰다. 싸이클릭 유량 변조 프로세스와 기판의 온도에 따라 기판위에 증착된 탄소나노필라멘트들의 특성을 조사하였다. 싸이클릭 에칭기간에 $SF_6$를 투입하자 탄소나노필라멘트의 직경크기는 급격히 감소하였다. 이러한 탄소나노필라멘트 직경의 크기 감소 원인은 $SF_6$ 기체의 주입에 따른 에칭능력 향상에 기인하는 것으로 이해되었다.

Enhancement of the nucleation density for diamond film on the pretreated glass substrate by the application of cyclic modulation of the source-gas flow rate

  • Kim, T.-G.;Kim, S.-H.;Kim, Y.-H.
    • Journal of Korean Vacuum Science & Technology
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    • 제4권1호
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    • pp.18-22
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    • 2000
  • For the enhancement of the nucleation density of the diamond film, we introduced the cyclic process. The cyclic process was carried out by the on/off control of CH$_4$ flow rate for a relatively short time (10 min), compared with the total reaction time (6 h). Prior to depositing the diamond film, we made the pretreated glass substrate via the unidirectional scratch using ∼l $\mu\textrm{m}$ size diamond powders. Diamond films were deposited on the pretreated glass substrate in a microwave plasma enhanced chemical vapor deposition (MPECVD) system. We observed the enhancement of the nucleation density of the diamond films caused by the cyclic process. Detailed surface morphologies of the substrate were investigated after the cyclic process. Based on these results, we discussed the cause for the enhancement of the nucleation density on the pretreated glass substrate by the cyclic process.

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순환정상 프로세스의 고차 통계 특성을 이용한 디지털 변조인식 (Digitally Modulated Signal Classification based on Higher Order Statistics of Cyclostationary Process)

  • 안우현;나선필;서보석
    • 방송공학회논문지
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    • 제19권2호
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    • pp.195-204
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    • 2014
  • 이 논문에서는 순환정상 프로세스의 고차 통계 특성을 바탕으로 2-FSK, 4-FSK, 8-FSK, MSK, BPSK, QPSK, 8-PSK, 16-QAM, 32-QAM, 64-QAM 등 10개의 기저대역 디지털 변조신호를 자동으로 인식하는 방법을 제안하였다. 변조신호의 고유한 성질을 나타내는 특징변수로는 1차 순환 모멘트와 고차 순환 큐뮬런트를 이용하였다. 제안한 변조인식기는 크게 두 단계로 구성되며, 첫 번째 단계에서는 1차 순환 모멘트가 나타내는 첨두치를 이용하여 M-FSK와 비FSK로 변조신호를 분류한다. 두 번째 단계에서는 비FSK를 분류하기 위해 고차 순환 큐뮬런트 값을 이용하는 Gaussian 혼합 모델 기반의 분류기를 적용하였다. 제안한 방법의 성능을 검증하기 위해서 모의실험을 실시하였다. 모의실험 결과 제안한 분류기는 주파수와 위상 옵셋이 존재하는 환경에서도 우수한 분류확률을 나타내었다.

The geometry change of carbon nanofilaments by SF6 incorporation in a thermal chemical vapor deposition system

  • Kim, Sung-Hoon
    • 한국결정성장학회지
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    • 제21권3호
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    • pp.119-123
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    • 2011
  • Carbon nanotilaments (CNFs) could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and$H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ as a cyclic modulation manner, the geometries of carbon coils-related materials, such as nano-sized coil and wave-like nano-sized coil could be observed on the substrate. The characteristics (formation density and morphology) of as-grown CNFs with or without $SF_6$ incorporation were investigated. Diameter size reduction for the individual CNFs-related shape and the enhancement of the formation density of CNFs-related material could be achieved by the incorporation of $SF_6$ as a cyclic modulation manner. The cause for these results was discussed in association with the slightly increased etching ability by $SF_6$ addition and the sulfur role in SF 6 for the geometry change.

Geometry variation for as-grown carbon coils under the minimized sulfur additive condition

  • Lee, Seok-Hee;Kim, Sung-Hoon
    • 한국결정성장학회지
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    • 제22권5호
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    • pp.213-217
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    • 2012
  • Carbon coils could be synthesized on nickel catalyst layer-deposited silicon oxide substrate using $C_2H_2$ and $H_2$ as source gases under thermal chemical vapor deposition system. By the incorporation of $SF_6$ additive in cyclic modulation manner, the dominant formation of the nanosized carbon coils could be achieved with maintaining the minimized sulfur additive amount. The geometry variation of the as-grown carbon coils, such as linear type, microsized coil type, wavelike nanosized coil type, and nanosized coil type, were investigated according to the different cyclic modulation manner of $SF_6$ flow. $SF_6$ gas incorporation develops the coil-type geometry. Furthermore, the higher flow rate of $SF_6$ gas increased the amount of the nanosized carbon coils. The slightly increased etching ability by $SF_6$ addition seems to be the cause for these results.

Solar Cyclic Modulation of Diurnal Variation in Cosmic Ray Intensity

  • Park, Eun Ho;Jung, Jongil;Oh, Suyeon;Evenson, Paul
    • Journal of Astronomy and Space Sciences
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    • 제35권4호
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    • pp.219-225
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    • 2018
  • Cosmic rays are ions that move at relativistic speeds. They generate secondary cosmic rays by successive collisions with atmospheric particles, and then, the secondary particles reach the ground. The secondary particles are mainly neutrons and muons, and the neutrons are observed by the ground neutron monitor. This study compared the diurnal variation in cosmic ray intensity obtained via harmonic analysis and that obtained through the pile-up method, which was examined in a previous study. In addition, we analyzed the maximum phase of the diurnal variation using four neutron monitors with a cutoff rigidity below approximately 6 GV, located at similar longitudes to the Oulu and Rome neutron monitors. Expanding the data of solar cycles 20-24, we examined the time of the maximum cosmic ray intensity, that is, the maximum phase regarding the solar cyclic modulation. During solar cycles 20-24, the maximum phase derived by harmonic analysis showed no significant difference with that derived by the pile-up method. Thus, the pile-up method, a relatively straightforward process to analyze diurnal variation, could replace the complex harmonic analysis. In addition, the maximum phase at six neutron monitors shows the 22-year cyclic variation very clearly. The maximum phase tends to appear earlier and increase the width of the variation in solar cycles as the cutoff rigidity increases.

Cyclic olefin copolymer (COC) 폴리머 프리즘을 사용한 광섬유 기반 표면 플라즈몬 공명 (SPR) 바이오 센서 (A fiber optic surface plasmon resonance (SPR) sensorusing cyclic olefin copolymer (COC) polymer prism)

  • 윤성식;이수현;안종혁;이종현
    • 센서학회지
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    • 제17권5호
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    • pp.369-374
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    • 2008
  • A novel fiber optic surface plasmon resonance (SPR) sensor using cyclic olefin copolymer (COC) prism with the spectral modulation is presented. The SPR sensor chip is fabricated using the SU-8 photolithography, Ni-electroplating and COC injection molding process. The sidewall of the COC prism is partially deposited with Au/Cr (45/2.nm thickness) by e-beam evaporator, and the thermal bonding process is conducted for micro fluidic channels and optical fibers alignment. The SPR spectrum for a phosphate buffered saline (0.1.M PBS, pH.7.2) solution shows a distinctive dip at 1300.nm wavelength, which shifts toward longer wavelength with respect to the bovine serum albumin (BSA)concentrations. The sensitivity of the wavelength shift is $1.16\;nm{\cdot}{\mu}g^{-1}{\cdot}{\mu}l^{-1}$. From the wavelength of SPR dips, the refractive indices (RI) of the BSA solutions can be theoretically calculated using Kretchmann configuration, and the change rate of the RI was found to be $2.3{\times}10^{-5}RI{\cdot}{\mu}g^{-1}{\cdot}l^{-1}$. The realized fiber optic SPR sensor with a COC prism has clearly shown the feasibility of a new disposable, low cost and miniaturized SPR biosensor for biochemical molecular analyses.