• Title/Summary/Keyword: Cyclic difference see

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New Cyclic Difference Sets with Singer Parameters Constructed from d-Homogeneous Functions (d-동차함수로부터 생성된 Singer 파라미터를 갖는 새로운 순회차집합)

  • 노종선
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.12 no.1
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    • pp.21-32
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    • 2002
  • In this paper, for any prime q, new cyclic difference sets with Singer parameter equation omitted are constructed by using the q-ary sequences (d-homogeneous functions) of period $q_n$-1. When q is a power of 3, new cyclic difference sets with Singer parameter equation omitted are constructed from the ternary sequences of period $q_n$-1 with ideal autocorrealtion found by Helleseth, Kumar and Martinsen.

Adsorption of Macrocyclic Cobalt Complex on a Glassy Carbon Electrode for the Electrocatalytic Reduction of $O_2$

  • 강찬
    • Bulletin of the Korean Chemical Society
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    • v.19 no.7
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    • pp.754-760
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    • 1998
  • It was found that the adsorption of a cobalt(III) complex with a macrocyclic ligand, C-meso-5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane (hmc), was induced on a glassy carbon electrode by heavily oxidizing the electrode surface. Adsorption properties are discussed. The glassy carbon electrode with the adsorbed complex was employed to see the catalytic activities for the electro-reduction of O2. In the presence of oxygen, reduction of (hmc)Co3+ showed two cathodic waves in cyclic voltammetry. Compared to the edge plane graphite electrode at which two cathodic waves were also observed in a previous study, catalytic reduction of O2 occurred in the potential region of the first wave while it happened in the second wave region with the other electrode. A rotating disk electrode after the same treatment was employed to study the mechanism of the O2 reduction and two-electron reduction of O2 was observed. The difference from the previous results was explained by the different reactivity of the (hmc)CoOOH2+ intermediate, which is produced after the two electron reduction of (hmc)Co3+ in the presence of O2.

Electrochemical Evaluation on Corrosion Property of Welding Zone of 22APU Stainless Steel (22APU 스테인리스강의 용접부위의 부식특성에 관한 전기화학적 평가)

  • Moon, Kyung-Man;Kim, Yun-Hae;Lee, Sung-Yul;Kim, Jong-Do;Lee, Myung-Hoon;Kim, Jin-Gyeong
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.8
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    • pp.1162-1169
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    • 2009
  • Two kinds of welding methods were carried out for 22APU stainless steel, one is a Laser welding and the other is the TIG welding. In this case, difference of corrosion characteristics of welded zone with two welding methods mentioned above was investigated with electrochemical methods such as measurement of corrosion potential, polarization curves and cyclic voltammogram etc.. Vickers hardness of all welded zone (WM:Weld Metal, HAZ:Heat Affected Zone, BM:Base Metal)in the case of Laser welding showed a relatively higher value than those of TIG welding. Futhermore their corrosion current density in all welding zone were also observed with a lower value compared to TIG welding. In particular corrosion current density of BM regardless of welding method indicated the lowest value than those of other welding zone. Intergranular corrosion was not observed at the corroded surface of all welding zone in the case of Laser welding, however it was observed at WM and HAZ with TIG welding, which is suggested that chromiun depletion due to forming of chromium carbide appears to WM and HAZ which is in the range of sensitization temperature. Therefore their zone can easily be corroded with more active anode. Consequently we can see that corrosion resistance of all welding zone of 22APU stainless steel can apparently be improved by using of Laser welding.