• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.5A
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• pp.495-501
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• 2009

In this paper, a numerical anchor bond-slip model is proposed to improve the numerical simulation of concrete-steel structures connected with steel anchor bolts and subjected to extreme cyclic loading. The suggested bond-slip model is composed of a group of nonlinear uniaxial connector elements and its parameters can be determined by calibrating the model with pull-out test data. Numerical analysis results from simulating a concrete foundation-steel column structure using the proposed bond-slip anchor model, which is implemented based on Abaqus elements, and the perfect-bond anchor model are compared with the experimental results. It is concluded that a reasonable anchor bond-slip model is required to realistically simulate concrete-steel structures subjected to extreme cyclic loading, and the proposed anchor bond-slip model shows acceptable performance in the present numerical analysis.

• Geomechanics and Engineering
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• v.31 no.2
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• pp.167-181
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• 2022

Soil liquefaction has been one of the most important concerns in geotechnical earthquake engineering in recent years, due to its damages to structures and its destructive effects. The cyclic liquefaction of silty sands, in particular, remains of great interest for both research and application. Although many factors are known that affect the liquefaction resistance of sands, the effect of fine grain content is perhaps one of the most studied and still controversial. In this study, 48 deformation-controlled cyclic simple shear tests were performed on BS and CS silt samples mixed with 5%, 15% and 30% by weight of Krk085, Krk042 and Krk025 sands in constant-volume conditions to determine the liquefaction potential of silty sands. The tests were carried out at 30% and 50% relative density and under 100 kPa effective stress. The results revealed that the liquefaction potential of silty sand increases with increasing average particle size ratio (D_50sand / d_50silt) of the mixture for a fixed silt content. Furthermore, for identical base sand, the liquefaction potentials of coarse grained sands increase with increasing silt content, while the respective potentials of fine grained sands generally decrease. However, this situation may vary depending on the silt grain structure and is affected by the nature of the fine grains. In addition, the variation of the void ratio interval was shown to provide a good intuition in determining the liquefaction potentials of silty sands, while the intergranular void ratio alone does not constitute a criterion for determining the liquefaction potentials of silty sands.

• Transactions on Electrical and Electronic Materials
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• v.15 no.5
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• pp.257-261
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• 2014

Multilayered CdTe/PSS films were prepared by the electrostatic self-assembly method in an aqueous medium. Positively-charged cadmium telluride (CdTe) nanoparticles and anionic polyelectrolyte, poly (sodium 4-styrene sulfonate) (PSS) were assembled alternately in order to build up a multilayered film structure. A linear proportion of absorbance to the number of bilayers suggests that an equal amount of CdTe was adsorbed after each dipping cycle, which resulted in the buildup of a homogenous film. The binding energies of elements (Cd and Te) in multilayered CdTe/PSS film shifted from those of the CdTe nanoparticles in the pure state. This result indicates that the interfacial electron densities were redistributed by the strong electrostatic interaction between the oppositely-charged CdTe and PSS. Electrochemical properties of the multilayered CdTe/PSS films were studied in detail by cyclic voltammetry (CV).

• Journal of Korean Society of Steel Construction
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• v.15 no.2
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• pp.207-217
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• 2003

The Concrete Filled Steel Tube (M) Column has excellent structural capacities that are in accordance with the interaction effect between the steel tube and concrete. CFT structure has been focussed on a struc tural system for high-rise buildings. The purpose of this study is to evaluate the strength and deformation capacities of CFT columns that are subject to constant axial and cyclic lateral load. The test parameters are diameters to the thickness ratio of the steel tube, axial load ratios, and the shapes of the tube. Total eighteen specimens were fabricated to clarify the energy absorption capacity of the CFT columns. Experimental results were summarized for their ultimate strengths and deformation capacities.

• Bulletin of the Korean Chemical Society
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• v.31 no.5
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• pp.1267-1269
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• 2010

The pure crystalline $Li_{1.1}V_{0.9}O_2$ powder has been prepared by a simple solid state reaction of $Li_2CO_3$ and $V_2O_3$ precursors under nitrogen gas containing 10 mol % hydrogen gas flow. The structure of $Li_{1.1}V_{0.9}O_2$ powder was analyzed using Xray diffraction (XRD) and scanning electron microscope (SEM). The stoichiometric $Li_{1.1}V_{0.9}O_2$ powder was used as anode active material for lithium secondary batteries. Its electrochemical properties were investigated by cyclic voltammetry and constant current methods using lithium foil electrode. The observed specific discharge capacity and charge capacity were 360 mAh/g and 260 mAh/g during the first cycle, respectively. In addition, the cyclic efficiency of this cell was 72.2% in the first cycle. The specific capacity of $Li_{1.1}V_{0.9}O_2$ anode rapidly declines as the current rate increases and retains only 30 % of the capacity of 0.1C rate at 1C rate. The crystallinity of the $Li_{1.1}V_{0.9}O_2$ anode decrease as discharge reaction proceeds. However, the relative intensity of main peaks was almost recovered when the cell was charged up to 1.5 V.

• Steel and Composite Structures
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• v.21 no.1
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• pp.157-175
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• 2016

It was found that the lateral stiffness changes obvious at the transfer position of the section configuration from SRC to RC. This particular behavior leads to that the transfer columns become as the important elements in SRC-RC hybrid structures. A comprehensive study was conducted to investigate the seismic behavior of SRC-RC transfer columns based on a low cyclic loading test of 16 transfer columns compared with 1 RC column. Test results shows three failure modes for transfer columns, which are shear failure, bond failure and bend failure. Its seismic behavior was completely analyzed about the failure mode, hysteretic and skeleton curves, bearing capacity deformation ability, stiffness degradation and energy dissipation. It is further determined that displacement ductility coefficient of transfer columns changes from 1.97 to 5.99. The stiffness of transfer columns are at the interval of SRC and RC, and hence transfer columns can play the role of transition from SRC to RC. All specimens show similar discipline of stiffness degradation and the process can be divided into three parts. Some specimens of transfer column lose bearing capacity swiftly after shear cracking and showed weak energy dissipation ability, but the others show better ability of energy dissipation than RC column.

• Bulletin of the Korean Chemical Society
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• v.35 no.5
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• pp.1523-1528
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• 2014

Silicon quantum dots (Si QDs) were synthesized by etching silicon nanopowder with aqueous hydrofluoric acid (HF) and nitric acid ($HNO_3$). Then, the hydride-terminated Si QDs (H-Si QDs) were functionalized by 1- octadecene (ODE). By only controlling the etching time, the maximum luminescence peak of octadecylterminated Si QDs (ODE-Si QDs) was tuned from 404 nm to 507 nm. The average optical gap was increased from 2.60 eV (ODE-Si QDs-5 min) for 5 min of etching to 3.20 eV (ODE-Si QDs-15 min) for 15 min of etching, and to 3.40 eV (ODE-Si QDs-30 min) for 30 min of etching. The electron affinities (EA), ionization potentials (IP), and quasi-particle gap (${\varepsilon}^{qp}_{gap}$) of the Si QDs were determined by cyclic voltammetry (CV). The quasi-particle gaps obtained from the CV were in good agreement with the average optical gap values from UV-vis absorption. In the case of the ODE-Si QDs-30 min sample, the difference between the quasi-particle gap and the average optical gap gives the electron-hole Coulombic interaction energy. The additional electronic levels of the ODE-Si QDs-30 min and ODE-Si QDs-15 min samples determined by the CV results are interpreted to have originated from the Si=O bond terminating Si QD.

• Bulletin of the Korean Chemical Society
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• v.29 no.6
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• pp.1229-1232
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• 2008

The surface structure, electrochemical behavior, and wetting property of self-assembled monolayers (SAMs) formed by dioctyl diselenide (DODSe) on Au(111) were investigated by scanning tunneling microscopy (STM), cyclic voltammetry (CV), and contact angle measurements. In contrast to the formation of well-ordered SAMs by octanethiol on Au(111), the SAMs formed by DODSe have a disordered phase and many unusual vacancy islands (VIs). In addition, the formation of DODSe SAMs is largely influenced by the solution concentration used. DODSe SAMs formed in 5 $\mu$ M and 50 $\mu$ M solutions have two mixed domains consisting of missing-row ordered phases and disordered phases, while DODSe SAMs formed in 1 mM and 5 mM solutions have only disordered phases with an abnormally high VI fraction of 22-24%. We also found that the wetting property and electrochemical behavior of DODSe SAMs on Au(111) are markedly influenced by the formation of ordered SAMs and the density of VIs.

• Bulletin of the Korean Chemical Society
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• v.27 no.5
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• pp.733-738
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• 2006

Nucleophilic addition reactions of p-substitutedbenzylamines $(XC _6H_4CH _2NH _2)$ to $\alpha$-phenyl-$\beta$-thiophenyl-acrylonitriles ($YC _4SH _2CH=C(CN)C_6H_4$Y') have been studied in acetonitrile at 25.0, 30.0, and 35.0 ${^{\circ}C}$. The reactions take place in single step in which the $C_\beta$ -N bond formation and proton transfer to $C_\alpha$ of $\alpha$-phenyl-$\beta$-thiophenylacrylonitriles occur concurrently with four-membered cyclic transition structure. These mechanistic conclusions are drawn based on (i) the large negative $\rho$x and large positive $\rho$Y' values and also large magnitude of $\rho$X, (ii) the negative sign and large magnitude of the cross-interaction constants ($\rho$XY), (iii) the normal kinetic isotope effects ($k_H/k_D$ > 1.0), and (iv) relatively low $\Delta H ^\neq$ and large negative $\Delta S ^\neq$ values.

• Structural Engineering and Mechanics
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• v.62 no.3
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• pp.281-289
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• 2017

Damping value has considerable influence on the dynamic and seismic behaviors of bridges. However, currently the constant damping ratios that are prescribed by most bridge seismic design codes can't truly represent the complicated damping character of actual structures. In this paper, a cyclic loading experiment was conducted to study the effect of stress amplitude on material damping of concrete to present an analyzing model of the material damping of concrete. Furthermore, based on the fundamental damping of structure measured under ambient vibration, combined with the presented stress-dependent material damping concrete, the seismic response of a bridge pier was calculated. Comparison between the calculated and experiment results verified the validity of the presented damping model. Finally, a modified design and analysis method for bridge was proposed based on stress-dependent damping theory, and a continuous rigid frame bridge was selected as the example to calculate the actual damping values and the dynamic response of the bridge under different earthquake intensities. The calculation results indicated that using the constant damping given by the Chinese seismic design code of bridges would overestimate the energy dissipation capacity of the bridge.