• 공업화학
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• 제25권2호
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• pp.147-151
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• 2014

많은 고분자 공정에서 고분자에서의 유기 용매와 같은 저분자 물질의 확산은 중요하다. 고분자에서의 저분자 물질의 이동은 중합 반응기의 효율성과 제조된 고분자의 특성을 결정한다. 공정을 설계하고 최적화하는데 중요한 물성값은 고분자/용매 상호확산 계수이다. 용매의 농도가 매우 낮은 무한희석 상태에서의 고분자/용매 계의 무한확산계수를 측정하기 위해서 capillary column inverse gas chromatography (CCIGC) 기법이 흔히 사용된다. 이 기법을 사용하면 비교적 짧은 시간에 확산계수와 분배계수를 측정하는 것이 가능하다. 본 연구에서는 CCIGC 기법을 사용해서 styrene/butadiene/styrene (SBS) 블록 공중합체에서 환형 구조를 가지는 용매의 확산계수와 분배계수를 다양한 온도 범위에서 측정하였다.

• 비파괴검사학회지
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• 제36권2호
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• pp.121-129
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• 2016

As the lifespan of concrete structures increases, their load carrying capacity decreases owing to cyclic loads and long-term effects such as creep and shrinkage. For these reasons, there is a necessity for stress state monitoring of concrete members. Particularly, it is necessary to evaluate the concrete structures for behavioral changes by using a technique that can overcome the measuring limitations of usual ultrasonic nondestructive evaluation methods. This paper proposes the use of a nonlinear ultrasonic method, namely, nonlinear resonant ultrasonic spectroscopy (NRUS) for the measurement of nonlinearity parameters for stress monitoring. An experiment compared the use of NRUS method and a linear ultrasonic method, namely, ultrasonic pulse velocity (UPV) to study the effects of continuously increasing loads and cyclic loads on the nonlinearity parameter. Both NRUS and UPV methods found a similar direct relationship between load level and that parameter. The NRUS method showed a higher sensitivity to micro-structural changes of concrete than UPV method. Thus, the experiment confirms the possibility of using the nonlinear ultrasonic method for stress state monitoring of concrete members.

• Steel and Composite Structures
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• 제10권3호
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• pp.245-260
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• 2010

In this paper, experimental and theoretical investigations on the response and collapse of 310 stainless steel tubes with different diameter-to-thickness ratios subjected to cyclic bending are discussed. The tube-bending device and curvature-ovalization measurement apparatus were used to conduct the experiment. The endochronic theory combined with the principle of virtual work and finite element software, ANSYS, were used to simulate the moment-curvature and ovalization-curvature relationships. It is shown that although the two methods lead to good simulation of the moment-curvature relationship, the endochronic theory combined with the principle of virtual work has the better simulation of the ovalization-curvature response when compared with experimental data and the simulation by ANSYS. In addition, the theoretical formulations proposed by Kyriakides and Shaw (1987) and Lee et al. (2001) were used to simulate the controlled curvature-number of cycles to produce buckling relationship. It is shown that the theoretical formulations effectively simulate the experimental data.

• Smart Structures and Systems
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• 제24권6호
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• pp.759-768
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• 2019

In nuclear fusion reactors, the key structural component (i.e., the plasma-facing component) undergoes high heat flux cyclic loading. To ensure the safety of fusion reactors, an experimental study on the temperature-induced creep of stainless steel under heat flux cyclic loading was performed in the present work. The strains were measured using a stereo digital image correlation technique (3D-DIC). The influence of the heat haze was eliminated, owing to the use of a vacuum environment. The specimen underwent heat flux cycles ($500^{\circ}C-1000^{\circ}C$) with different mechanical preloads (0 kN, 10 kN, 30 kN, and 50 kN). The results revealed that, for a relatively large preload (for example, 50 kN), a single temperature cycle can induce a residual strain of up to $15000{\mu}{\varepsilon}$.

• 한국수소및신에너지학회논문집
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• 제19권2호
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• pp.163-170
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• 2008

Carbon nanofibers with nano-sized structures were evaluated as a active material using supercacitor electrode which could store electrochemical energy reversibly. A feasibility of EDLC electrode was estimated with specific surface area measurement by BET method and mesopore structure of carbon nanofiber surface could be explained electrochemical absorption-desorption in aqueous electrolyte. A capacitance of carbon nanofiber electrode was increased gradually, depending on the ratio of Ketjenblack as a conducting material. Ketjen Black $20{\sim}25\;wt.%$ ratio in electrode was observed a suitable amount of conducting material by cyclic voltametry results.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 춘계학술대회 논문집 센서 박막재료 반도체재료 기술교육
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• pp.43-46
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• 2002

We have investgated the photoisomerization using light irradiation 8A5H-phospholipid( L-$\alpha$-dimyristoylphosphatidylcholine[DMPC], L-$\alpha$-dilauroylphosphatidylcholine[DLPC]mixture LB film accumulated by monolayer on an ITO. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in $NaClO_{4}$ solution at a variable concentration and variable number layers LB film. The scan rate was 100mV/s.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2002년도 춘계학술대회 논문집
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• pp.140-144
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• 2002

In this paper, the plastic zone size ahead of the crack tip of DENT specimen and the crack growth length under cyclic loading were measured by ESPI system. These results of the plastic zone size measured by ESPI system were compared with the plastic zone size proposed by Irwin. The results of tile crack growth length measured by it were also compared with them measured by the image analysis system. It is confirmed that it is possible to measure the plastic zone and crack growth length.

• 한국염색가공학회지
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• 제20권5호
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• pp.41-46
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• 2008

Recently, computational calculation of molecular energy potentials and electrochemical reduction/oxidation behaviors are of very importance in view point of prediction of dye's properties such as energy levels and bandgaps of absorption. This can be influenced by their different constituents or substituents in chromogen molecules. Structural conformations and properties with computational modeling calculation are numerically simulated, which are fully or partly based on fundamental laws of physics. In addition, cyclic voltammetric measurement was used to obtain the experimental redox potential values, which were compared to the computed simulation values.

• 한국염색가공학회지
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• 제25권1호
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• pp.7-12
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• 2013

The energy levels are very important to investigate properties of organic dye materials. These values of energy levels can be calculated and compared with absorption spectra, cyclic voltammetric measurement and computer simulative calculation. In this study, absorption and emission changes were observed by complexation between rhodamine 6G based dye and mercury. This is related to spirolactam ring system of rhodamine 6G based dye. According to structural change of this dye, HOMO and LUMO energy levels were investigated and determined by their values with different approaches.

• Journal of Microbiology and Biotechnology
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• 제15권6호
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• pp.1392-1396
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• 2005

Proteolytic digestion and CD measurement of wild-type and mutant cyclic AMP receptor proteins (CRPs) were performed either in the presence or absence of cyclic nucleotide. Results indicated that transition of a structural change to the hinge region by the binding of cAMP to the anti site was required for the binding of cAMP to the syn site near the hinge region and, although the occupancy of cAMP in the anti site increased the protein stability, CRP adopted more a stable conformation by the binding of cAMP to the syn site.