• 제목/요약/키워드: Cyclic Measurement

검색결과 250건 처리시간 0.019초

탄소나노튜브 전극의 전기화학적 특성 (Electrochemical Properties of Carbon Nano-Tube Electrode)

  • 이동윤;구보근;이원재;송재성;김현주
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제54권4호
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    • pp.139-143
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    • 2005
  • For application of carbon nano-tube (CNT) as a counter electrode materials of dye-sensitized solar cell (DSSC), the electrochemical behavior of CNT electrode was studied, employing cyclic-voltammetry (C-V) and impedance spectroscopy. Fabrication of CNT-paste and formation of CNT-counter electrode for characteristic measurement have been carried out using ball-milling and doctor blade process, respectively. Unit cell for measurements was assembled using Pt electrode, CNT electrode, and iodine-embedded electrolyte. Field emission-scanning electron microscopy (FE-SEM) was used for structural investigation of CNT powder and electrode. Sheet resistance of electrode was measured with 4-point probe method. Electrochemical properties of electrode, C-V and impedance spectrum, were studied, employing potentiogalvanostat (EG&G 273A) and lock in amplifier (EG&G 5210). As a results, the sheet resistance of CNT electrode is almost similar to that of F-doped SnO2 (FTO) coated glass substrate as approximately 10 ohm/sq. From C-V and impedance spectroscopy measurements, it was found that CNT electrode has high reaction rate and low interface reaction resistance between CNT surface and electrolyte. These results provides that CNT electrode were superior to that of conventional Pt electrode. Particularly, the reaction rate in the CNT electrode is about thrice high than Pt electrode. Therefore. CNT electrode is to be good candidate material for counter electrode in DSSC.

Electro-Micromechanical 시험법을 이용한 Ni Nanowire Strands 강화 고분자 복합재료의 Sensing과 계면 물성 평가 (Sensing and Interfacial Evaluation of Ni Nanowire Strands/Polymer Composites using Electro-micromechanical Technique)

  • 김성주;정진규;박종만
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2005년도 추계학술발표대회 논문집
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    • pp.141-144
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    • 2005
  • Sensing and interfacial evaluation of Ni nanowire strands/polymer composites were investigated using Electro-micromechanical technique. Electro-micromechanical techniques can be used as sensing method for micro damage, loading, temperature of interfacial properties. Using Ni nanowire strands/silicone composites with different content, load sensing response of electrical contact resistivity was investigated under tensile and compression condition. The mechanical properties of Ni nanowire strands with different type/epoxy composites were measured using uniformed cyclic loading and tensile test. Ni nanowire strands/epoxy composites showed humidity and temperature sensing within limited ranges, 20 vol% reinforcement. Some new information on temperature and humidity sensing plus loading sensing of Ni nanowire strands/polymer composites could be obtained from the electrical resistance measurement as a new concept of the nondestructive interfacial evaluation.

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흡입포트형상에 따른 모터링엔진내 압축과정 난류특성 연구 (The Effect of Intake Port Configurations on the Turbulence Characteristics During Compression Stroke in a Motored Engine)

  • 강건용;이진욱;정석용;백제현
    • 대한기계학회논문집
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    • 제18권4호
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    • pp.920-932
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    • 1994
  • The combustion phenomena of a reciprocating engine is one of the most important processes affecting performance and emissions. One effective way to improve the engine combustion is to control the motion of the charge inside a cylinder by means of optimum induction system design, because the flame speed is mainly determined by the turbulence at compression(TDC) process in S.I. engine. It is believed that the tumble and swirl motion generated during intake breaks down into small-scale turbulence in the compression stroke of the cycle. However, the exact nature of their relationship is not well known. This paper describes cycle resolved LDV measurement of turbulent flow inside the cylinder of a 4-valve engine under motoring(non-firing) conditions, and studies the effect of intake port configurations on the turbulence characteristics using following parameters ; Eulerian temporal autocorrelation coefficient, turbulence energy spectral density function, Taylor micro time scale, integral time scale, and integral length scale.

Wave shape analysis of seismic records at borehole of TTRH02 and IWTH25 (KiK-net)

  • Kamagata, Shuichi
    • Earthquakes and Structures
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    • 제18권3호
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    • pp.297-312
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    • 2020
  • The KiK-net by NIED is a vertical array measurement system. In the database of KiK-net, singular pulse waves were observed in the seismic record at the borehole of TTRH02 during the mainshock (the magnitude of Japan Meteorological Agency (MJ) 7.3, MW 6.8) and aftershock (Mj 4.2) of Tottori-ken Seibu earthquake in 2000. Singular pulse waves were also detected in the seismic records at the borehole of IWTH25 during the Iwate-Miyagi Nairiku earthquake in 2008 (MJ 7.2, MW 6.9). These pulse waves are investigated by using the wave shape analysis methods, e.g., the non-stationary Fourier spectra and the double integrated displacement profiles. Two types of vibration modes are discriminated as the occurrence mechanism of the singular pulse waves. One corresponds to the reversal points in the displacement profile with the amplitude from 10-4 m to 10-1 m, which is mainly related to the fault activity and the amplification pass including the mechanical amplification (collision) of the seismograph in the casing pipe. The other is the cyclic pulse waves in the interval of reversal points, which is estimated as the backlash of the seismograph itself with the amplitude from 10-5 m to 10-4 m.

Al-Cu-Li-Mg-Ag-Zr합금의 시효에 따른 전기화학적 분극 거동과 공식특성 (Pitting Characteristics and Electrochemical Polarization Behaviors in Al-Cu-Si-Mg-Ag-Zr Alloys with Ageing)

  • 민병철;정동석;손태원;조현기
    • 열처리공학회지
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    • 제9권2호
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    • pp.103-111
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    • 1996
  • In this paper, we studied on both electrochemical polarization behaviors and pitting characteristics of ultra high strength Al-Cu-Li-Mg-Ag-Zr alloys(named C1 and C2) and 2090 alloy according to their treatments in the deaerated 3.5% NaCl, using by the potentiodynamic and the potentiostatic method, SEM micrograph and surface roughness including depth of pitting attack. With the cyclic polarization curves, the hysteresis of the C1 and C2 alloys appeared more remarkably than that of the 2090 alloy, because of precipitation microstructural difference between C1, C2 alloys and 2090 alloy. In the pitting experiments, the correlations between pitting growth and aging conditions were analyzed with the SEM micrograph and measurement of the pit depth.

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염료감응형 태양전지의 상대전극 재료로서 탄소나노튜브의 전기화학적 특성 (Electrochemical Properties of Carbon Nano-tube as the Counter Electrode of Dye-sensitized solar cell)

  • 김현주;이동윤;구보근;이원재;송재성;이대열
    • 한국전기전자재료학회논문지
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    • 제17권10호
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    • pp.1090-1094
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    • 2004
  • Studies on porous oxide electrode, dye and electrolyte for dye-sensitized solar cells have been intensively carried out until now. However, counter electrode have not been much studied so far. Accordingly, it is needed to investigate new counter electrode materials with superior catalyst property and to substitute for Pt electrode. In this case, carbon nano-tubes (CNTs) are one of alternatives for counter electrodes as following merits: low resistivity, excellent electron emission property, large surface area and low cost due to development of mass production technique. Such advantages gave us to select multiwalled CNTs (MWCNT) as counter electrode for dye-sensitized solar cell. Also, cyclic voltammetry and impedance spectroscopy were used to investigate electrochemical properties of both CNT electrode and Pt electrode. It was found that sheet resistance of CNT electrode was similar to that of Pt electrode, also, electrochemical properties of CNT electrode was superior to that of Pt electrode on the basis on the measurement of CV and impedance spectrum. It was found that CNT is likely to be a very promising electrode material for dye solar cells.

The Concept of the Future and the New Paradigm of the Fifth Spiral: State, Business, Science, Society and Informatization

  • Sabden, Orazaly
    • The Journal of Asian Finance, Economics and Business
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    • 제5권4호
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    • pp.173-185
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    • 2018
  • At a turn of the third millennium the world storms and quickly changes. It became difficult to expect what expects us tomorrow. The most important are questions of recovery from the crisis and rescue of mankind from forthcoming global changes: warming of climate, water and food problems, social, economic and political conflicts that are shaking the world and other various cataclysms, accidents, negative processes. It puts before mankind the problem which never solved by our civilization. All this is caused by ignoring of objective economic laws, laws of wildlife and also by violation of cyclic development management's laws. In article the concept of strategy of mankind's survival in XXI and next centuries, the principles of creation of planetary house of universal civilization for post-industrial world based on spirituality scientific and technological revolutions, ecology, space exploration, economy and world safety are considered. Introduction of uniform universal measurement of currency for the whole world in the form of "power" is offered. Important aspect of a research is theoretical postulate on integrated innovative society. The author puts forward a new paradigm of government on a basis of 5 spirals. The basic model of forced development of small and medium business, including 9 projects, is developed.

고온/저 가습 운전을 위한 고분자 전해질 연료전지용 전극 개발 (Developement of a PEFC electrodes under the high temperature and low humidified conditions)

  • 류성관;최영우;박진수;임성대;양태현;김한성;김창수
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.149-149
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    • 2009
  • Generally, Nafion ionomer is used in the polymer electrolyte fuel cell (PEFC) electrodes to achieve high power density. At the high temperature operation of PEFC, however, ionic conductivity of Nafion remarkably decreased due to the evaporation of water in Nafion polymer. Recently, many researchers have focused on using the Ionic Liquids(ILs) instead of water in Nafion polymer. ILs have intrinsic properties such as good electrochemical stability, high ionic conductivity, and non-flammability. Especially, ILs play a crucial role in proton conduction by the Grottuss mechanism and act as water in water-free Nafion polymer. However, it was found that the ILs was leached out of the polymer matrix easily. In this study, we prepared membrane electrode assemblies with various contents of ILs. The effect of ILs in the electrode of each designed was investigated by a cyclic voltammetry measurement and the cell performance obtained through a single cell test using H2/Air gases. Electrodes with different contents of ILs in catalyst layer were examined at high temperature and low humidified condition.

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폐쇄성 수면 무호흡 증후군과 상기도 저항 증후군의 진단적 및 임상적 차이 (Diagnostic and Clinical Differences in Obstructive Sleep Apnea Syndrome and Upper Airway Resistance Syndrome)

  • 최영미
    • 수면정신생리
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    • 제18권2호
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    • pp.63-66
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    • 2011
  • It has been controversial whether upper airway resistance syndrome (UARS) is a distinct syndrome or not since it was reported in 1993. The International Classification of Sleep Disorders classified UARS under obstructive sleep apnea syndrome (OSAS) in 2005. UARS can be diagnosed when the apnea-hypopnea index (AHI) is fewer than 5 events per hour, the simultaneously calculated respiratory disturbance index (RDI) is more than 5 events per hour due to abnormal non-apneic non-hypopneic respiratory events accompanying respiratory effort related arousals (RERAs), and oxygen saturation is greater than 92% at termination of an abnormal breathing event. Although esophageal pressure measurement remains the gold standard for detecting subtle breathing abnormality other than hypopnea and apnea, nasal pressure transducer has been most commonly used. RERAs include phase A2 of cyclical alternating patterns (CAPs) associated with EEG changes. Symptoms of OSAS can overlap with UARS, but chronic insomnia tends to be more common in UARS than in OSAS and clinical symptoms similar with functional somatic syndrome are also more common in UARS. In this journal, diagnostic and clinical differences between UARS and OSAS are reviewed.

FFT analysis of load data during field operations using a 75-kW agricultural tractor

  • Ryu, Myong-Jin;Chung, Sun-Ok;Kim, Yong-Joo;Lee, Dae-Hyun;Choi, Chang-Hyun;Lee, Kyeong-Hwan
    • 농업과학연구
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    • 제40권1호
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    • pp.53-59
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    • 2013
  • Analysis of load data during field operations is highly important for optimum design of power drive lines for agricultural tractor. Objective of the paper was to analyze field load data using FFT to determine frequency and the energy levels of meaningful cyclic patterns. Rotary tillage, plowing, baling, and wrapping operations were selected as major field operations of agricultural tractor. An agricultural tractor with power measurement system was used. The tractor was equipped with strain-gauge sensors to measure torque of four driving axles and a PTO axle, speed sensors to measure rotational speed of the driving axles and an engine shaft, pressure sensors to measure pressure of hydraulic pumps, an I/O interface to acquire the sensor signals, and an embedded system to calculate power requirement. In rotary tillage, calculated frequency was decreased as travel speed increased. In baler operation, calculated frequency was increased as PTO speed was increased. The calculated peak frequency levels and expected levels were similar. Results of the study would provide information on power utilization patterns and on better design of power drive lines.