• Title/Summary/Keyword: Cyclic Corrosion Test

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The Effect of Heat Input on Grooving Corrosion Behavior in the Welds of Electric Resistance Welding Steel Pipe (ERW 강관 용접부의 홈부식거동에 미치는 입열량의 영향)

  • Lee, B.W.;Lee, J.S.;Park, H.S.
    • Journal of Power System Engineering
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    • v.11 no.3
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    • pp.41-46
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    • 2007
  • The microstructure and electrochemical analysis of welds of electric resistance welding(ERW) pipe were investigated. The direction of metal flow line in HAZ of ERW pipe shifted to the inner(or outer) surface of pipe by plastic deformation during welding. The lowest heat input welds of ERW pipe was showed crack by liquid penetrant testing. Accelerated corrosion test by constant current density of 20mA/$cm^{2}$ developed groove at the welds of ERW pipe and the measured grooving factors were about $1.2{\sim}1.5$. Corrosion potential of base metal obtained by cyclic polarization in artificial sea water(3.5wt.% NaCl solution) was 100mV higher than that of weld metal of ERW pipe.

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Effects of Surface Modification with Amino Terminated Polydimethylsiloxane(ATP) on the Corrosion Protection of Epoxy Coating

  • Shon, MinYoung
    • Corrosion Science and Technology
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    • v.8 no.3
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    • pp.103-109
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    • 2009
  • An epoxy coating was designed to give a hydrophobic property on its surface by modifying it with three types of Amino Terminated Polydimethylsiloxane (ATP), and then effects of the modification on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protectiveness of the modified epoxy coating were examined using FT-IR spectroscopy, hydrothermal cyclic test, and impedance test. The surface of epoxy coating was changed from hydrophilic to hydrophobic property due primarily to a phase separation tendency between epoxy and modifier by the modification. The phase separation tendency is more appreciable when modified by ATP with higher molecular weight ATP at higher content. Water transport behavior of the modified epoxy coating decreased more in that with higher hydrophobic surface property. The resistance to localized corrosion of the modified epoxy coated carbon steel was well agreed with its water transport behavior and hydrophobic tendency.

An Evaluation of Corrosion Protective Systems for Reinforcing Steel in Concrete (콘크리트 구조물의 철근 방식성능 실험평가)

  • Hur, Jun;Hong, Gi-Suop;Oh, Sung-Mo;Jang, Ji-Won;Choi, Eung-Kyu;Choi, Oan-Chul
    • Proceedings of the Korea Concrete Institute Conference
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    • 1997.10a
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    • pp.275-280
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    • 1997
  • An experimental study to evaluate corrosion protection systems was undertaken with 47 reinforced concrete slab specimens subjected to cyclic wet and dry saltwater exposure. Corrosion measurements included monitoring marcrocell corrosion currents, which are generally accepted in United States practice. Test results indicate that specimens containing 2 kg/$\textrm{m}^3$ of NaCl an exposed to a 10 percent of NaCl show high values of corrosion currents. For the specimens with water repellent membrane currents kept relatively low numerical values, while test specimens with surface corrosion inhibitor hyprotective systems show high values of corrosion currents. No clear indication of the corrosion inhibitor protective systems might be due to the extremely high chloride exposure of the specimens, which has brought the accelerated corrosion. It would be expected that evaluation of the corrosion protective systems need long-term measurement with specimen exposed les chloride but simulating the real condition.

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Development of Durable Reliability Assessment Methods for Heavy Duty Coatings

  • Kim, Seung-Jin;Jung, Ho;Yang, In-Mo;Tanaka, Takeyuki
    • Corrosion Science and Technology
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    • v.4 no.4
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    • pp.155-163
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    • 2005
  • Heavy duty coating are required to have minimum durable period of 15 years under average usage environment because these paints are coated with purpose of anti-corrosion, antifouling, plastering etc. Onto steel structures constructed upon land and sea and other ferrous structures of electric power generation plants, electricity transmission towers, large structures of various plants, etc. Therefore we tried to estimate heavy duty coating longevity through reliability evaluation method and used combined cyclic anti-conrrosion test method composed of drying, moisturizing and salt spray as for accelerated life test to estimate longevity. Accelerated life test hours to heavy duty coating of first grade (with longevity not less than 15 years) specification may be obtained from troubleless test hours $t_n=\frac{B_p}{n^{1/\beta}}\left[\frac{1n(1-CL)}{1n(1-p)} \right]^{1/\beta}=19.671$ (yr) where shape parameter $\beta=1.1$, confidence level CL=80 %, warranty life $B_{10}=15$ yr and sampling size n=10 (2 sets). Because acceleration factor {AF} found by accelerated test is 41.7, accelerated life test hours required may be represented about 4,132 hr so that if this amount of hours is converted to number of cycles(6 hr/cycle) of complex cycle corrosion resistance test then the amount is tantamount about 690 cycles. That means if there does not occur trouble failure (with defect factor sum not more than 20) during when there is performed 690 cycles of combined cyclic anti-corrosion test to heavy duty coating specimen then it signifies that there can be warranted longevity $B_{10}$ of 15 yr under condition of confidence level CL=80 %.

Estimation of Critical Chloride Threshold Value in Concrete by the Accelerated Corrosion Test

  • Vicho, Victor C.;Bae, Su-Ho;Park, Jae-Im;Lee, Kwang-Myong;Kim, Jee-Sang;Jung, Sang-Hwa
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.05b
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    • pp.201-204
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    • 2006
  • It should be noted that the critical chloride threshold level is not considered to be a unique value for all conditions. This value is dependent on concrete mix proportions, cement type and constituents, presence of admixtures, environmental factors, reinforcement surface conditions, and other factors. In this study, the accelerated corrosion test for reinforcing steel was conducted by electrochemical and cyclic wet and dry seawater method, respectively and during the test, corrosion monitoring by half-cell potential method was carried out to detect the time to initiation of corrosion for individual test specimen. For this purpose, lollypop and right hexahedron test specimens were made for 31%, 42%, and 50% of W/C, respectively, and then the accelerated corrosion test for reinforcing steel was executed. It was observed from the test that the time to initiation of corrosion was found to be different with the water-cement ratio and accelerated corrosion test method, respectively and the critical chloride threshold values were found to range from 0.91 to $1.47kg/m^3$.

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Accelerated Prediction Methodologies to Predict the Outdoor Exposure Lifespan of Galvannealed Steel

  • Kim, Ki Tae;Yoo, Young Ran;Kim, Young Sik
    • Corrosion Science and Technology
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    • v.18 no.3
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    • pp.86-91
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    • 2019
  • Generally, atmospheric corrosion is the electrochemical degradation of metal that can be caused by various corrosion factors of atmospheric components and weather, as well as air pollutants. Specifically, moisture and particles of sea salt and sulfur dioxide are major factors in atmospheric corrosion. Using galvanized steel is one of the most efficient ways to protect iron from corrosion by zinc plating on the surface of the iron. Galvanized steel is widely used in automobiles, building structures, roofing, and other industrial structures due to their high corrosion resistance relative to iron. The atmospheric corrosion of galvanized steel shows complex corrosion behavior, depending on the plating, coating thickness, atmospheric environment, and air pollutants. In addition, corrosion products are produced in different types of environments. The lifespans of galvanized steels may vary depending on the use environment. Therefore, this study investigated the corrosion behavior of galvannealed steel under atmospheric corrosion in two locations in Korea, and the lifespan prediction of galvannealed steel in rural and coastal environments was conducted by means of the potentiostatic dissolution test and the chemical cyclic corrosion test.

Effects of Curing Agent on the Corrosion Protection of Diglycidyl Ether Bisphenol-A Based Epoxy Coating

  • Shon, MinYoung;Kwon, HyukSang
    • Corrosion Science and Technology
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    • v.7 no.6
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    • pp.344-349
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    • 2008
  • Epoxy coatings were prepared to give a different corrosion protection by reacting it with two different kinds of curing agent, and then effects of the curing agents on the structure, surface hydrophobic tendency, water transport behavior and hence corrosion protection of epoxy coatings were examined using hygrothermal cyclic test, and impedance analysis. In the results of EIS, the corrosion protection of epoxy coating cured by polyamide shows better than epoxy coating cured by polyamide epoxy adduct. It was well agreed with its water transport behavior and hydrophobic tendency.

Experimental and numerical studies on the cyclic behavior of R/C hollow bridge piers with corroded rebars

  • Cardone, D.;Perrone, G.;Sofia, S.
    • Earthquakes and Structures
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    • v.4 no.1
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    • pp.41-62
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    • 2013
  • A comprehensive experimental program of cyclic tests on 1:3-scale models of bridge piers is going to be carried out at the Laboratory of Structures and Materials of the University of Basilicata. The testing models include eight RC single shaft piers with hollow circular cross section. Four piers have been realised using corroded steel rebars. In this paper, the results of preliminary numerical simulation analyses of the cyclic behaviour of the piers, carried out with Opensees using fiber-based models, are presented. Pull-out and lap-splice effects of steel rebars have been taken into account in the numerical analyses. First, the experimental specimens and the test set up are presented. Next, the results of the numerical analyses are discussed. In the numerical analyses, different configurations and levels of corrosion have been considered. The effective stiffness and equivalent damping of the piers is reported as a function of pier ductility and pier drift.

An Experimental Investigation of the Application of Artificial Neural Network Techniques to Predict the Cyclic Polarization Curves of AL-6XN Alloy with Sensitization

  • Jung, Kwang-Hu;Kim, Seong-Jong
    • Corrosion Science and Technology
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    • v.20 no.2
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    • pp.62-68
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    • 2021
  • Artificial neural network techniques show an excellent ability to predict the data (output) for various complex characteristics (input). It is primarily specialized to solve nonlinear relationship problems. This study is an experimental investigation that applies artificial neural network techniques and an experimental design to predict the cyclic polarization curves of the super-austenitic stainless steel AL-6XN alloy with sensitization. A cyclic polarization test was conducted in a 3.5% NaCl solution based on an experimental design matrix with various factors (degree of sensitization, temperature, pH) and their levels, and a total of 36 cyclic polarization data were acquired. The 36 cyclic polarization patterns were used as training data for the artificial neural network model. As a result, the supervised learning algorithms with back-propagation showed high learning and prediction performances. The model showed an excellent training performance (R2=0.998) and a considerable prediction performance (R2=0.812) for the conditions that were not included in the training data.

Corrosion Behavior of Titanium for Implant in Simulated Body Fluids (인공 체액 조건에서 임플랜트용 티타늄 소재의 부식 특성)

  • 이중배;최기열
    • Journal of the Korean institute of surface engineering
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    • v.37 no.2
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    • pp.110-118
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    • 2004
  • The corrosion of pure titanium (CP- Ti Grade 2) and titanium alloy (Ti6Al4V ELI) were studied under various conditions of simulated body fluids. The static immersion test and the electrochemical test were performed in accordance with ISO 10271 : 2001. For the electrochemical test, the open circuit potential was monitored as a function of time, and the cyclic polarization curve was recorded. The corrosion resistance was evaluated from the values of corrosion potential, passivation current density, breakdown potential, and the shape of hysteresis etc. The effects of alloy type, surface condition, temperature, oxygen, and constituents in the fluids such as acid, chloride were estimated. Both specimens had extremely low dissolution rate in the static immersion test. They showed strong passivation characteristics in the electrochemical test. They maintained negligible current density throughout the wide anodic potential range. The passive layer was not broken up to 2.0 V (vs. SCE). The hysteresis and the shift of passivation potential toward the anodic direction was observed during the reversed scan. The passivation process appeared to be accelerated by oxygen in air or that dissolved in the fluids. The passivation also proceeded without oxygen by the reaction of constituents in the fluids. Acid or chloride in the fluids, specially later weakened the passive layer, and then induced higher passivation current density and less shift of passivation potential in the reversed scan. CP-Ti Grade 2 was more reactive than Ti6Al4V ELI in the fluids containing acid or chloride, but thicker layer produced on its surface provided higher corrosion resistance.