• Korean Chemical Engineering Research
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• v.57 no.1
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• pp.5-10
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• 2019

In this study, electrochemical characteristics of artificial graphite coated with petroleum pitch using solvent method as anode material of lithium ion battery were investigated. As the solvent, n-hexane, toluene, tetrahydrofuran and quinoline were used. The surface of the prepared anode material was analyzed by SEM and TEM. Also the electrochemical performances of the prepared anode materials were performed by constant current first charge/discharge, cycle, cyclic voltammetry and impedance tests in the electrolyte of $LiPF_6$ dissolved inorganic solvents (EC:DEC=1:1 vol%). The coating thickness of the prepared graphite was about 100-500 nm and the graphite coated with THF solvent had a smoother surface than that using other solvents. It was found that pitch-coated graphite (THF) show the low initial irreversible capacity (51 mAh/g), the high discharge capacity (360 mAh/g) and coulombic efficiency (99%).

• Journal of ILASS-Korea
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• v.23 no.4
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• pp.175-184
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• 2018

Emission characteristics of regulated (NOx, PM, CO, NMHC) and unregulated (VOCs, aldehydes, PAHs) air pollutants were investigated for diesel heavy duty buses equipped with different after-treatment systems (DPF+EGR and SCR) under urban driving cycle. The combustion temperature and the working temperature of SCR catalysts were important to make impact on NOx emissions, whereas PM emissions were low. The alkane groups dominated NMVOCs emissions, making 42.6~59.4% of sum of the NMVOCs emissions. Especially, alkane emissions of DPF+EGR-equipped vehicle included DOC had 14.9~15.5% higher than those of SCR-equipped vehicle due to low efficiency of oxidation catalyst. In the case of individual NMVOCs, n-nonane and propylene emissions highly occupied for DPF+EGR and SCR, respectively. Formaldehyde emissions among aldehydes were the highest and PAHs emissions were hardly detected except naphthalene and phenanthrene. The NMHC speciation has been shown to be the highest of the formaldehyde ranged 20.8~21.5%. The results of this study will be contributed to establish Korean HAPs emission inventory for automobile source.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2014.05a
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• pp.582-584
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• 2014

Conventional Web crawlers are reducing overhead burden on the server to ensure the integrity of data optimization measures have been continuously developed. The amount of data growing exponentially faster among those data, then the data needs to be collected should be used to the modern web crawler is the indispensable presence. In this paper, suggested that the existing Web crawler and Web crawler approach efficiency comparison and analysis. In addition, based on the results, compared to suggest an optimized technique, Web crawlers, data collection cycle dynamically reduces the overhead of the server system was designed for. This is a Web crawler approach will be utilized in the field of the search system.

• Advances in Energy Research
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• v.6 no.1
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• pp.75-90
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• 2019

Anthropogenic greenhouse gas emissions are rising rapidly despite efforts to curb release of such gases. One long term potential solution to offset these destructive emissions is the capture and storage of carbon dioxide. Partially depleted hydrocarbon reservoirs are attractive targets for permanent carbon dioxide disposal due to proven storage capacity and seal integrity, existing infrastructure. Optimum well completion design in depleted reservoirs requires understanding of prominent geomechanics issues with regard to rock-fluid interaction effects. Geomechanics plays a crucial role in the selection, design and operation of a storage facility and can improve the engineering performance, maintain safety and minimize environmental impact. In this paper, an integrated geomechanics workflow to evaluate reservoir caprock integrity is presented. This method integrates a reservoir simulation that typically computes variation in the reservoir pressure and temperature with geomechanical simulation which calculates variation in stresses. Coupling between these simulation modules is performed iteratively which in each simulation cycle, time dependent reservoir pressure and temperature obtained from three dimensional compositional reservoir models in ECLIPSE were transferred into finite element reservoir geomechanical models in ABAQUS and new porosity and permeability are obtained using volumetric strains for the next analysis step. Finally, efficiency of this approach is demonstrated through a case study of oil production and subsequent carbon storage in an oil reservoir. The methodology and overall workflow presented in this paper are expected to assist engineers with geomechanical assessments for reservoir optimum production and gas injection design for both natural gas and carbon dioxide storage in depleted reservoirs.

• Journal of Korean Society on Water Environment
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• v.35 no.1
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• pp.35-42
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• 2019

Urbanization has led to extreme changes in land use on urban watersheds. Most cities are becoming residential, commercial and industrial areas, making infiltration and storage of rainfall less favorable. The demand for LID (Low Impact Development) technology is increasing in order to mitigate this water cycle distortion and return to existing hydrological conditions. The LID technique is effective in reducing runoff by permeating the urban impervious area. However, considering the limit of the installation area and the financial requirement of the installation, there is not much research on the linkage of each LID component technology for optimum efficiency according to the appropriate scale. In this study, the effects of the LID facilities applied to the target site were simulated using the SWMM model, suggesting the optimal linkage method considering interconnectivity, and applying the effects as an existing installation of individual facilities. The water balance at the time of application of the LID technology, short-term and long-term rainfall event were compared. Also, the individual application and the linkage application were compared with each other. If each component technology has sufficient processing size, then linkage application is more effective than individual application.

• Journal of Korean Society on Water Environment
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• v.34 no.6
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• pp.669-677
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• 2018

Torrential rain and drought are repeated due to the increase in the unpredictable fluctuating of rainfall patterns. It is time for stabilize water resource management in terms of disaster prevention. Distributed control from sources is needed to minimize damages caused by torrential rains and droughts. Rain barrel can be used to reduce the runoff as they collect and store rainwater. In response to this situation, Seoul Metropolitan Government and other local governments implemented a project to support the installation of rain barrel and provided 90% of the cost of installing it in private areas. However, with limited budget, it is difficult to distribute rainwater to the city which is mostly covered by private areas. In this study, Samho-dong, Ulsan, where pilot projects of water cycle leading city are underway, analyzed the effects of reducing the runoff with respect to the amount of rainwater that can be used, and analyzed the economics of recoverable investment cost when installed. From the analysis, it was established that it is possible to show sufficient efficiency with a small capacity without the need to install large rain barrel effectively in the private sector, and to support the installation cost of less than 70 percent of the rainwater can be recovered.

• Korean Journal of Materials Research
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• v.29 no.5
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• pp.322-327
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• 2019

Hole carrier selective MoOx film is obtained by atomic layer deposition(ALD) using molybdenum hexacarbonyl[$Mo(CO)_6$] as precursor and ozone($O_3$) oxidant. The growth rate is about 0.036 nm/cycle at 200 g/Nm of ozone concentration and the thickness of interfacial oxide is about 2 nm. The measured band gap and work function of the MoOx film grown by ALD are 3.25 eV and 8 eV, respectively. X-ray photoelectron spectroscopy(XPS) result shows that the $Mo^{6+}$ state is dominant in the MoOx thin film. In the case of ALD-MoOx grown on Si wafer, the ozone concentration does not affect the passivation performance in the as-deposited state. But, the implied open-circuit voltage increases from $576^{\circ}C$ to $620^{\circ}C$ at 250 g/Nm after post-deposition annealing at $350^{\circ}C$ in a forming gas ambient. Instead of using a p-type amorphous silicon layer, high work function MoOx films as hole selective contact are applied for heterojunction silicon solar cells and the best efficiency yet recorded (21 %) is obtained.

• Journal of the Korean Society of Propulsion Engineers
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• v.25 no.3
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• pp.62-80
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• 2021

The requirements for the next-generation propulsion system and for a good propellant have been summarized. The characteristics and effectiveness of kerosene, hydrogen, and methane, which are the fuels that are mainly attracting attention in Korea and abroad, were compared with each other. As a result of the comparison, methane was evaluated to be more advantageous than other fuels in reliability, cost, reusability, maintenance, eco-friendliness, safety, lifespan, technical difficulties, engine cycle selection, application of common bulkhead, and non-disassembly/reassembly delivery. And in terms of performance, the specific impulse of methane is higher than that of kerosene, so the efficiency of the launch vehicle can be increased. Methane's properties incluidng eco-friendliness, low-temperature combustion, long life, and maintenability make it beneficial for reuse and for the development of multi-purpose engines.

• Applied Chemistry for Engineering
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• v.22 no.5
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• pp.566-574
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• 2011

Coal gasifier is a key component for achieving high efficiency in integrated gasification combined cycle and indirect coal liquefaction. Although there have been several successful coal gasifiers that were commercially proven, many different design configurations are still possible for a simple and reliable gasifier operation. Four different gasifier design concepts of dry-feeding were compared in terms of residence time, exit syngas temperature and syngas composition. First, cold-flow simulation was applied to pre-select the configuration concepts, and the hot-flow simulation including chemical reactions was performed to compare the concepts at more actual gasifier operating conditions. There are many limitations in applying CFD method in gasifier design, particularly in estimating slag behavior and slag-tap design. However, the CFD analysis proved to be useful in comparing the widely different gasifier design concepts as a pre-selection tool.

• Journal of the Korea Institute of Information Security & Cryptology
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• v.30 no.6
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• pp.1217-1223
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• 2020

The Block cipher CHAM is lightweight block cipher for low-end processors, developed by National Security Research Institute from Korea. The mode of operation is necessity for efficient operation of block cipher, among them, the counter (CTR) mode has good efficiency because it is easy to implement and supporting parallel operation. In this paper, we propose the optimized implementation for block cipher CHAM-CTR. The proposed implementation can be skipped some rounds by pre-computation. Thus it has better calculating speed than existing CHAM. Also, this implementation pre-load some of round keys to registers, before entering round functions. It makes reduced 160cycles loading time for round key load. Finally, proposed implementation achieved higher performance about 6.8%, and 4.5% for fixed-key scenario, and variable-key scenario, respectively.