• Title/Summary/Keyword: Current density

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Effects of Process Variables on The Electrochemical Recovery of Palladium in A HCl Solution

  • Kim, Min-Seuk;Lee, Jae-Chun;Kim, Won-Baek
    • Resources Recycling
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    • v.14 no.1
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    • pp.55-63
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    • 2005
  • This study investigated the electrochemical recovery of palladium in a HCl solution that is used for palladium leaching. The high acidity of HCl solution and the low concentration of Pd ions increased the cathodic overpotential and reduced the limiting current density. Lowering the current density produced dense deposits; however, they were under high tensile stress. Raising the temperature affected both the densification and the stress, which enabled the attainment of dense Pd deposits under low stress. Lowering the current density and raising the temperature up to 70$^{\circ}C$ was recommended for the recovery of palladium as sound bulk Pd deposits. Current efficiency was over 85% at the initial stage of recovery may decrease the current efficiency, since a low Pd ion concentration results in a low limiting current density.

The effect of pulse current electrolysis on the composition and themicrostructure of Tin-Zinc electrodeposits (주석-아연 합금도금층의 조성 및 조직에 미치는 파형전류전해의 영향)

  • 예길촌;박성진;김대영
    • Journal of the Korean institute of surface engineering
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    • v.34 no.4
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    • pp.303-312
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    • 2001
  • Composition and microstructure of the tin-zinc alloys electroplated in gluconate bath were studied according to pulse current parameters. The cathode current efficiency increased with both the mean current density and the off-time decrease. Zinc content of the alloy deposits increased with increasing mean current density, while it decreased noticebly with increasing the off-time from 10-30ms to 100-150ms. The preferred orientation of the alloy deposits changed with the increase of peak current density in the sequence of (220)longrightarrow(220)+(420) or (220)+(420)+(321) mixed structure. The equiaxed grain size of the alloy increased with the increase of off-time and the decrease of mean current density.

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Critical Current Density Distribution Analysis of HTS Tape (고온초전도 테이프의 임계전류밀도 분포 해석)

  • 강준선;나완수;권영길;손명환;김석환
    • Proceedings of the Korea Institute of Applied Superconductivity and Cryogenics Conference
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    • 2002.02a
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    • pp.277-280
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    • 2002
  • It is well known that the critical current of a HTS tape has anisotropic characteristic in magnetic field. We are interested in critical current density distribution of a HTS tape. We assumed the experimentally obtained Ic-B curves do represent the local properties of HTS tapes and calculated the critical current density distribution of HTS tapes using numerical method. Also we predicted the critical current of the tapes.

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Switching current density for spin transfer torque magnetic random access memory with Dzaloshinskii-Moriya Interaction

  • Song, Kyungmi;Lee, Kyung-Jin
    • Proceedings of the Korean Magnestics Society Conference
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    • 2015.05a
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    • pp.78-79
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    • 2015
  • We investigate the switching current for various cell diameters and DM interaction. We find that the current density for switching can depend strongly on the cell size when the switching is governed by the domain wall motion. Moreover the switching current density is also strongly influenced by DM interaction. In the presentation, we will discuss the effect of domain wall formation and more various DMI constant on the switching current desity in detail.

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Sensitivity of Electroplating Conditions on Young's Modulus of Thin Film (니켈박막의 공정조건에 따른 탄성계수 변화)

  • Kim, Sang-Hyun
    • Journal of the Korean Society for Precision Engineering
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    • v.25 no.8
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    • pp.88-95
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    • 2008
  • Young's modulus of electroplated nickel thin film is systematically investigated using the resonance method of atomic force microscope. Thin layers of nickel to be measured are electroplated onto the surface of an AFM silicon cantilever and Young's modulus of plated nickel film is investigated as a function of process conditions such as the plating temperature and applied current density. It is found that Young's modulus of plated nickel thin film is as high as that of bulk nickel at low plating temperature or low current density, but decreases with increasing plating temperature or current density. The results imply that the plating rate increases as increasing the plating temperature or current density, therefore, slow plating rate produces a dense plating material due to the sufficient time fur nickel ions to form a dense coating.

The Limiting Current Density and the Regeneration of a Heterogeneous Ion Exchange Membrane in a Nickel Plating Rinse Waters Treatment Process by Electrodialysis (전기투석에 의한 니켈도금 폐수처리 공정에서 한계전류밀도와 불균질 이온교환막의 재생)

  • 윤용수
    • Journal of environmental and Sanitary engineering
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    • v.16 no.2
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    • pp.38-46
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    • 2001
  • In this work, the heterogeneous ion exchange membrane was used in a electrodialysis apparatus to treat a Ni planting rinse water because the heterogeneous ion exchange membrane was excellent efficiency as compared with low manufacturing cost, was easy to make, and had a good mechanical properties. For a regeneration of membrane and to obtain the optimal condition for a scale-up of apparatus after treating Ni plating rinse water, we would find about the limiting current density and the concentration polarization. When the Ni plating rinse water 150mg/L was treated with the electrodialysis apparatus using the heterogeneous ion exchange membrane, the limiting current density was about $1.49{\;}mA/\textrm{cm}^2$. And the limiting current density increased with the flow rate and concentration of Ni plating rinse water. We recognized that the used membrane could be reused by periodic backwashing because efficiency was constant when the membrane was backwashed after treating wastewater.

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Observation of local water content and current density in the PEMFC system (고분자 전해질 연료전지의 전류밀도와 국소 함수량 관찰)

  • Ko, Dong-Soo;Moon, Cheor-Ron;Choi, Gyung-Min;Kim, Duck-Jool;Jung, Ji-Hwan
    • 한국신재생에너지학회:학술대회논문집
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    • 2008.05a
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    • pp.69-72
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    • 2008
  • The local water contents and water transfer characteristics in the PEMFC system were investigated by numerical simulations and experiments. The performance of a lab-scale PEMFC is measured for fully humidified gases conditions and non-humidified ones. In order to observe the local water contents and water transfer characteristics inside PEMFC, the numerical simulation using CFD module on STAR-CD(es-pemfc) were conducted. The results show that the water content was increased as increasing current density, whereas it was decreased in high current density region. Then there was close correlation between high water content and internal temperature inside of MEA, and high current density was observed when internal temperature was dramatically increased.

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Distribution Analysis of Local Critical Temperature and Current Density in YBCO Coated Conductors using Low-temperature Scanning Laser Microscopy (저온 주사 레이저 현미경(LTSLM)을 이용한 YBCO 초전도 선재의 국소적 임계 온도 및 전류 밀도 분포 분석)

  • Park, S.K.;Cho, B.R.;Ri, H.C.
    • Progress in Superconductivity
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    • v.12 no.1
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    • pp.17-22
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    • 2010
  • Distribution of local critical temperature and current density in $YBa_2Cu_3O_{7-\delta}$ (YBCO) coated conductors was analyzed using a Low-temperature Scanning Laser Microscopy (LTSLM). We prepared YBCO coated conductors of various bridge types to study the spatial distribution of critical temperature and current density in single and multi bridges. An LTSLM system was modified for a detailed two-dimensional scan without shifting of the sample. We observed a spatial distribution of the critical temperature from the bolometric response, which arises from a focused laser beam at the sample near the superconducting transition. Also we studied the relation between the critical temperature and the current density.

Distribution Analysis of the Local Critical Temperature and Current Density in YBCO Coated Conductors using Low-temperature Scanning Laser and Hall Probe Microscopy (저온 주사 레이저 및 홀소자 현미경을 이용한 YBCO 초전도 선재의 국소적 임계 온도 및 전류 밀도 분포 분석)

  • Park, S.K.;Cho, B.R.;Park, H.Y.;Ri, H.C.
    • Progress in Superconductivity
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    • v.13 no.1
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    • pp.28-33
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    • 2011
  • Distribution of the local critical temperature and current density in YBCO coated conductors were analyzed using Low-temperature Scanning Laser and Hall Probe Microscopy (LTSLHPM). We prepared YBCO coated conductors of various bridge types to study the spatial distribution of the critical temperature and the current density in single and multi bridges. LTSLHPM system was modified for detailed linescan or two-dimensional scan both scanning laser and scanning Hall probe method simultaneously. We analyzed the local critical temperature of single and multi bridges from series of several linescans of scanning laser microscopy. We also investigated local current density and hysteresis curve of single bridge from experimental results of scanning Hall probe microscopy.

Electrodeposition Behavior of Ni-WC Composite Coatings with Variation of WC Particle Size (WC 분말 크기에 따른 Ni-WC 복합 도금층의 특성 거동에 관한 연구)

  • Kim, Dae-Geun;Lee, Jae-Ho
    • Journal of the Korean institute of surface engineering
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    • v.39 no.3
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    • pp.115-120
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    • 2006
  • The codeposition behavior of WC particles from an additive-free nickel sulfate and sulfamate solution has been investigated. Electroplating of Ni/WC composites was carried out at different current density with variation of WC particle size. The Guglielmi adsorption mechanism is applied to the electroplating of the fine WC in Ni matrix. The contents of WC in Ni composite coating were increased both by increasing current density and WC concentration in the bath. The hardness of Ni/WC composite coating at low current density is higher than that at high current density since finer WC particles dispersed through the coating. The codeposition behaviors of Co coated WC particles were also investigated. Conducting layer of particles promoted the codeposition behavior of Ni/WC-Co composite coatings.