• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.44-52
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• 2022

Epoxy resin has the disadvantage of being easily destroyed by instantaneous impact due to its high crosslinking density despite its high glass transition temperature (T_g) and excellent properties. To compensate for this, in this study, polyol was synthesized by ring opening polymerization of propylene glycol (PPG) diamine, Jeffamine D 2000 and propylene carbonate, and urethane modified epoxy was synthesized using this. The properties of the synthesized urethane modified epoxy were confirmed by FT-IR, H-NMR. To confirm the degree of improvement in impact resistance as an adhesive, a urethane modified epoxy adhesive was prepared by mixing a digylcidyl ether bisphenol A (DGEBA) with curing agent and curing accelerator. Properties test of urethane modified epoxy were shear strength, tensile strength and impact strength. As a result, excellent results were obtained in all test when the ratio of DGEBA : urethane modified epoxy was 8:2.

• Polymer(Korea)
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• v.27 no.2
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• pp.120-128
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• 2003

The effects of catalyst, accelerator and blend composition on the cure behavior of unsaturated polyester resin (UPE), vinyl ester resin (VE) and their blends were studied using differential scanning calorimetry(DSC). The DSC thermograms strongly depend on each variable. The result shows that the small exothermic peak at 115$^{\circ}C$ is due mainly to the UPE component in the UPE/VE blends and the large one at 134~138 $^{\circ}C$ is due mainly to the VE component. The results also indicate that the change of the DSC thermogram measured after each blend was exposed to high temperature 18$0^{\circ}C$ and the fast curing conditions of a few tens seconds provide useful information on understanding the thermal processing of a blend at high speed. The measurements of resin flow time represent that there are three distinct stages of cure in the UPE/VE blends: induction, transition and macro-gelation stages, as similarly reported for UPE by others earlier. The thermal stability and flexural properties of the cured UPE are significantly improved by blending it with the VE, depending on the composition.

• Polymer(Korea)
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• v.25 no.1
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• pp.63-70
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• 2001

The objective of this study was to investigate the effect of cure type on the processing and physical properties under conditions of similar stress-strain properties. On the carbon black filled natural rubber(NR) based compound, the induction time decreased, but the cure rate became fast with increasing loading of sulfur donor agent. Tensile strength was little affected on the curing type. However, elongation generally decreased with increasing accelerator. Effect of cure type on the blow-out properties was followings: CV

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.158-158
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• 2012

A new kind of organic-inorganic hybrid polymer, poly(tetraphenyl)silole siloxane (PSS), was invented and synthesized for realization of its unique charge trap properties. The organic portions consisting of (tetraphenyl)silole rings are responsible for electron trapping owing to their low-lying LUMO, while the Si-O-Si inorganic linkages of high HOMO-LUMO gap provide the intrachain energy barrier for controlling electron transport. Such an alternation of the organic and inorganic moieties in a polymer may give an interesting quantum well electronic structure in a molecule. The PSS thin film was fabricated by spin-coating of the PSS solution in THF organic solvent onto Si-wafer substrates and curing. The electron trapping of the PSS thin films was confirmed by the capacitance-voltage (C-V) measurements performed within the metal-insulator-semiconductor (MIS) device structure. And the quantum well electronic structure of the PSS thin film, which was thought to be the origin of the electron trapping, was investigated by a combination of theoretical and experimental methods: density functional theory (DFT) calculations in Gaussian03 package and spectroscopic techniques such as near edge X-ray absorption fine structure spectroscopy (NEXAFS) and photoemission spectroscopy (PES). The electron trapping properties of the PSS thin film of quantum well structure are closely related to intra- and inter-polymer chain electron transports. Among them, the intra-chain electron transport was theoretically studied using the Atomistix Toolkit (ATK) software based on the non-equilibrium Green's function (NEGF) method in conjunction with the DFT.

• Journal of the Korean GEO-environmental Society
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• v.9 no.5
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• pp.29-36
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• 2008

The shotcrete is a NATM technique as a major tunnel support for ground stability after tunnel excavation. Instead of a general concrete lining method, it is a trend for curtail of construction periods and reduction of construction expenses that required to use of the permanent shotcrete lining. This high-strength shotcrete is required to use as a permanent shotcrete lining. This brought out the solution of environmental pollution and harmfulness to human. Accordingly, in this study specimens for strength measurement were made to develop shotcrete possible to develop materials in early with cement mineral accelerator as NATM method construction. It was compared with existing shotcrete material, unconfined compression test, flexural strength test, antiwashout underwater test were experimented. The fish poison test was experimented to evaluate an influence of environment. As a results of the test, unconfined compressive strength and flexural strength were equivalent with 28-curing day strength of existing material. An antiwashout of research subject material was revealed excellently in antiwashout Underwater test. As a results of the fish poison, an evaluation research subject material was founded more environmentally friendly than existing shotcrete.

• Journal of the Architectural Institute of Korea Structure & Construction
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• v.35 no.9
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• pp.199-206
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• 2019

Experimental study on the durability characteristics to examine the feasibility of concrete with high water-tightness and self-healing performance to minimize maintenance of concrete for artificial ground is as follows. 1) When blending agent, swelling agents, and curing accelerator were added on the ternary system cement with blast-furnace slag fine particles and fly ash to give a self-healing property, higher blending strengths by 82% at design standard strength of 24MPa and by 74% at design strength of 30MPa, respectively could be obtained. 2) The permeability test for the specimens having high water-tightness and no shrinkage showed that the permeability was reduced at maximum of 98%. However, the permeability was decreased as the design strength was increased, showing the reduction rate of 87% at the design strength of 50MPa. 3) The depth of carbonation of blast-furnace slag and fly ash was increased in all the specimens compared with those of OPC only. However, as the material age was increased, carbonation penetration depth was decreased compared with the reference blend. 4) Compared with the reference blending using only OPC, the freeze-thaw resistance was higher in the case of blending with 40% of blast-furnace slag and 10% of fly ash at the design standard strength of 50MPa. In addition, the freeze-thaw resistance in general was superior in the design standard strength of 50MPa with the lower water-binder ratio (W/B) as compared with the design standard strength of 24MPa and 30MPa with the high water-binder ratios.

• Journal of the Korean GEO-environmental Society
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• v.18 no.12
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• pp.65-75
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• 2017

Flowability and strength with curing time of controlled low-strength material (CLSM) are required differently according to the construction purpose. In this paper, the flowability and strength were estimated from the mixing ratio of CLSM using multiple regression analysis to design the CLSM. The flow values and strength at 12 hrs and 7days were measured in accordance with the mixing ratio of CLSM which consists of 7 different materials, such as CSA expansive agent, ordinary Portland cement, fly ash, sand, silt, water, and accelerator. The multiple regression was performed with the proportions of each material of CLSM as independent variables and the measured properties as dependent variables using SPSS Statistics 23 which is a statistical analysis program. The regression coefficients were estimated from the first to third order equation models for the materials. From the results, the third order model for the flow values and the first order models for 12hrs and 7days strength are the most appropriate models. This study suggests that the mixing ratio required for constructions may be effectively estimated from the regression models about the characteristics of CLSM, before performing experimental tests.