• 폴리머
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• 제36권3호
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• pp.315-320
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• 2012

아크릴 공중합체의 구조와 다관능성 단량체의 관능성 및 함량을 조절하여 반도체 제조공정에 적합한 자외선 경화형 점착제를 제조하였다. 아크릴 공중합체는 점착력을 부여하는 기본수지로 사용되었고 다관능성 단량체는 광가교 특성으로 인하여 3차원 가교구조와 가교밀도를 변화시키기 위해 사용하였다. 아크릴 공중합체는 단량체 조성에서 2-ethylhexyl acrylate의 함량이 감소할수록 자외선 조사 후의 박리 점착력이 감소하였다. 광경화 특성을 갖는 다관능성 단량체의 탄소 이중결합 관능성이 증가할수록 자외선 조사 후 가교밀도가 증가하여 박리 점착력이 감소하였고 박리 후 웨이퍼 표면에 남게 되는 점착제 잔사물도 크게 감소하였다. 6관능성 단량체를 20 phr 포함하는 광가교형 감압점착제가 자외선 조사 전 점착력이 높고, 자외선 조사 후 박리 점착력이 낮고, 박리 후 웨이퍼 표면에 남게 되는 점착제 잔사물이 가장 적었다.

• 터널과지하공간
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• 제19권3호
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• pp.181-189
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• 2009

이 연구는 지보재로서 가장 널리 사용되고 있는 록 볼트와 새로운 지보 형태인 스파이럴 볼트에 대한 지보특성을 비교하여 두 지보재의 지보효과를 평가하는데 있다. 이를 위하여 시멘트-모르타르 그라우트의 양생기간이 7일과 28일에 대한 록 볼트와 스파이럴 볼트의 실내인발시험을 실시하였으며, 각 시험결과로부터 인발하중, 변위 그리고 구속압, 내부압, 전단응력 등을 각각 구하였다. 인발하중에 대한 변위의 관계를 보면 각각의 양생기간에 대해서 스파이럴 볼트의 변위가 록 볼트에 비해 크게 나타나는데, 이것은 록 볼트의 역학적 성질이 스파이럴 볼트보다 크기 때문인 것으로 사료된다. 또한 양생기간이 길 경우 두 지보재의 변위는 거의 동일하거나 감소하는 경향을 보이는데, 그 원인은 양생기간에 따라 그라우트의 압축강도가 증가하므로 지보재와 시멘트-모르타르 그라우트 사이의 부착력이 증가하기 때문으로 사료된다. 구속압을 비교한 결과 동일한 인발하중단계에서 스파이럴 볼트의 구속압이 록 볼트보다 크게 나타났다. 이러한 사실은 같은 조건하에 있는 지반이나 암반에 지보재를 설치 할 경우 시공성 측면에서 스파이럴 볼트가 록 볼트보다 지반이나 암반의 안정성을 확보하는데 더 효과적임을 지시한다. 이상의 결과를 종합해 볼 때 같은 조건하에 있는 지반이나 암반에 지보재를 설치할 경우 새로운 형태의 지보재인 스파이럴 볼트가 기존의 지보재인 록 볼트보다 인발하중과 구속압을 더 크게 발휘하는 것으로 사료된다. 아울러, 지보재에 있어서 경제성, 현장에서의 지보재 시공성 뿐만 아니라 지보재 설치 전후의 지반이나 암반의 안정성 측면 등을 고려할 때 스파이럴 볼트가 록 볼트에 비하여 더 효과적일 것으로 판단된다.

• 대한치과기공학회지
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• 제39권1호
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• pp.9-16
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• 2017

Purpose: The purpose of this study was to evaluate flexural strength, composite surface and fractured surface of three different indirect composite resins. Methods: Fifteen bar-shaped specimens ($25mm{\times}2mm{\times}2mm$) were fabricated for each FL group (Flow type and Light curing) and PLP group (Putty type and Light, Pressure curing) and PL group (Putty type and Light curing) according to manufacturer's instructions and ISO 10477. Fabricated specimens were stored in the distilled water for 24 hours at the temperature of $37^{\circ}C$. Three-point bending strength test was performed to measure flexural strength using universal testing machine at a crosshead speed of 1mm/min (ISO 10477). Surface and fractured surface of specimens were observed by digital microscope. Results were analyzed with Kruskal-wallis tests (${\alpha}=0.05$). Results: Mean (SD) of three different indirect composite resins were 83.38 (6.67) MPa for FL group, 139.90(16.53) MPa for PLP group and 171.72(16.74) MPa for PL group. Flexural strength were statistically significant (p<0.05). Differences were not observed at fractured surface among three groups. However, many pores over $100{\mu}m$ were observed at PL group in observing surface of specimen. Conclusion: Flexural strength of composite resins was affected by second polymerization method and content of inorganic filler.

• Journal of Advanced Marine Engineering and Technology
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• 제22권2호
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• pp.139-145
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• 1998

Filament winding method is widely used for composite fabrications using low viscosity liquid for-mation and processing asymmetrical structures of pressure vessel pipe rocket motor case etc. The filament winding method is affected by several parameters such as pot life of process time viscosi-ty of resin filament winding temperature and schedules curing condition and post curing condi-tion of resin. To develope high functional composite materials the rotation(5, 15, 20, 30rpm) of the winding machine was controlled by D.C motor. And the wiper to give proper tension was equipped between strand and resin bath. The resin is hooked by the design wiper. The adequate cure schedule was found by DSC. NOL ring test is carried out to investigate the basic physical properties such as design technology. The void contents in filament winding is generally higher than that of the prepreg laminated plate. These high contents of void can make a crack in resin in spite of low deformation. These problem was solved by giving tension in processing. To improve the characteristics of fiber volume fraction void contents resin/fiber bonding the winding speedc is changed under constant tension. It was found that resin impregnation was not different from in fiber contents void contents at the range of 0.5~1kg tension but it was found that resin was not impregnated at the above of 1.5kg tension. In burst test a pure PE liner was failed at a nozzle part under the $14kg/\textrm{cm}^2$ pressure but a pressure vessel of CNG was failed at a cylinder part under the $200kg/\textrm{cm}^2$ pressure.

• 한국복합재료학회:학술대회논문집
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• 한국복합재료학회 2001년도 춘계학술발표대회 논문집
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• pp.172-175
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• 2001

The co-cured Joining method, which is regarded as an adhesively bonded Joining method, is an efficient joining technique because both curing and bonding processes for the composite structures can be achieved simultaneously. It requires neither surface treatment onto the composite adherend nor an additional adhesive joining process because the excess resin, which is extracted from composite materials during consolidation, accomplishes the co-cured Joining process. Since the adhesive of the co-cured joint is the same material as the resin of the composite adherend, the analysis and design of the co-cured joint for composite structures are simpler than those of an adhesively bonded joint, which uses an additional adhesive. In this paper, effects of the manufacturing parameters, namely surface roughness, stacking sequence of the composite adherend, and manufacturing pressure in the autoclave during curing process, on the tensile load bearing capacity of the co-cured single lap joint will be experimentally investigated.

• Geomechanics and Engineering
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• 제10권1호
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• pp.77-94
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• 2016

Cyclic triaxial and resonant column tests were conducted to understand the beneficial effects of various grouted sands on liquefaction resistance and dynamic properties. The test procedures were performed on a variety of grouted sands, such as silicate-grouted sand, silicate-cement grouted sand and cement-grouted sand. For each type of grout, sand specimen was mixed with a 3.5% and 5% grout by volume. The specimens were tested at a curing age of 3, 7, 28 and 91 days, and the results of the cyclic stress ratio, the maximum shear modulus and the damping ratio were obtained during the testing program. The influence of important parameters, including the type of grout, grout content, shear strain, confining pressure, and curing age, were investigated. Results indicated that sodium silicate grout does not improve the liquefaction resistance and shear modulus; however, silicate-cement and cement grout remarkably increased the liquefaction resistance and shear modulus. Shear modulus decreased and damping ratio increased with an increase in the amplitude of shear strain. The effect of confining pressure on clean sand and sodium silicate grouted sand was found to be insignificant. Furthermore, a nonlinear regression analysis was used to prove the agreement of the shear modulus-shear strain relation presented by the hyperbolic law for different grouted sands, and the coefficients of determination, $R^2$, were nearly greater than 0.984.

• 한국콘크리트학회:학술대회논문집
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• 한국콘크리트학회 2006년도 추계 학술발표회 논문집
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• pp.397-400
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• 2006

Most of the civil structures in Korea and abroad have many kinds of damages when they are facing over-loaded traffics, long-term serviceability, and severe environmental conditions. Repair, rehabilitation, and retrofit are important for maintaining the serviceability of structures. In recent year, VES-LMC has been widely used as repair material for bridge deck repair and rehabilitation, because the VES-LMC has a various benefits such as traffic opening after 3 hours of curing, higher durability and bond strength. In case of any structure repaired or rehabilitated with VES-LMC, those were influenced capacity of bond between the base layer of slab and VES-LMC as well as physical properties of each other materials. The capacity of bond depended on purity of interface, micro cracks, curing of VES-LMC and so like. A kind of popular concrete repair technique, High pressure water jetting equipment is extremely efficient at removing damaged concrete. Removing damaged or poor quality concrete from sensitive structures such as bridge, tunnels, multi-story car parking decks and runways, using the high pressure water jetting could remove damaged or poor quality concrete remaining healthy and sound concrete. Accordingly, the purpose of this study is that it was to evaluate effect of hydrodemolition on the bond strength of VES-LMC overlay compared with effects of other method such as breaker, untreated. Also, it was evaluated the effect of surface moisture.

• Geomechanics and Engineering
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• 제23권2호
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• pp.151-163
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• 2020

Grouting method is an effective way of reinforcing cracked rock masses and plugging water gushing. Current grouting diffusion models are generally developed for horizontal cracks, which is contradictory to the fact that the crack generally occurs in rock masses with irregular spatial distribution characteristics in real underground environments. To solve this problem, this study selected a cement-sodium silicate slurry (C-S slurry) generally used in engineering as a fast-curing grouting material and regarded the C-S slurry as a Bingham fluid with time-varying viscosity for analysis. Based on the theory of fluid mechanics, and by simultaneously considering the deadweight of slurry and characteristics of non-uniform spatial distribution of viscosity of fast-curing grouts, a theoretical model of slurry diffusion in an oblique crack in rock masses at constant grouting rate was established. Moreover, the viscosity and pressure distribution equations in the slurry diffusion zone were deduced, thus quantifying the relationship between grouting pressure, grouting time, and slurry diffusion distance. On this basis, by using a 3-d finite element program in multi-field coupled software Comsol, the numerical simulation results were compared with theoretical calculation values, further verifying the effectiveness of the theoretical model. In addition, through the analysis of two engineering case studies, the theoretical calculations and measured slurry diffusion radius were compared, to evaluate the application effects of the model in engineering practice. Finally, by using the established theoretical model, the influence of cracking in rock masses on the diffusion characteristics of slurry was analysed. The results demonstrate that the inclination angle of the crack in rock masses and azimuth angle of slurry diffusion affect slurry diffusion characteristics. More attention should be paid to the actual grouting process. The results can provide references for determining grouting parameters of fast-curing grouts in engineering practice.

• 접착 및 계면
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• 제19권2호
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• pp.74-82
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• 2018

아크릴레이트 기반의 점착제를 가교 시키는 기술은 다양하게 소개되어 왔다. 본 연구에서는 에폭시 변성 단량체와 메틸아지리딘 가교제를 활용하여 높은 가교 밀도를 가지는 아크릴 구조체를 만들었다. 베이스구조체를 제조하기 위해서 빠른 제조 공정이 가능하고 무용제 공정이 가능한 UV 중합 기술을 활용했다. FT-IR, 경화거동 및 접착특성 평가를 통해 UV경화도 및 2차경화 온도에 따른 특성 변화를 확인하고자 하였다. 겔분율은 선경화 $800mJ/cm^2$, 120도 후 경화온도 조건에서 50%이상 확보할 수 있었으며, 180도 경화조건에서 80%이상 확보 할 수 있었다. 경화 시간이 길어짐에 따라 경화도가 100%에 도달하였으며 이를 통해 열경화를 통한 2차 경화가 효과적임을 확인 할 수 있었다.

• Tribology and Lubricants
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• 제26권5호
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• pp.297-302
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• 2010

This study is focused on the resin layer formation of UV imprinting process by changing imprinting pressure and period. The mold shape is made for the process of window open over the pattern transfer area and the imprinting period is assigned as the time just before the UV light curing. The residual layer is measured by changing the imprinting period and pressure magnitude, and the measured data of residual layer provides useful information for the design of the process conditions of imprinting processes.