• Title/Summary/Keyword: CuNi

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Grain Size Refinement in CuAlNi Shape Memory Alloy using Melt-spun Ribbon (급냉응고된 Ribbon을 이용한 CuAINi 형상기억합금의 결정미세화)

  • Choe, Yeong-Taek
    • 연구논문집
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    • s.22
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    • pp.127-139
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    • 1992
  • The mechnial properties such as fracture strength, ductility and fatigue strength of Cu shape memory alloy are lower than those of Ti-Ni SMA, because of their high elastic anisotropy and large grain size. And in order to improve the mechanical property of Cu SMA, some techniques such as casting method by addition of refining element, powder metallurgy and rapid solidification process have been studied on the refinement of the grain size of Cu SMA. This study was carried out to refine the grain size of CuAlNi SMA by applying the melt spinning method. According to this study, the conclusions are as follows; - grain size of the melt-spun ribbon was about $1\mum$ - there was not change in grain size, although increasing of hot pressing temperature -grain size of the hot-extruded specimen was about $30-40\mum$, it is more refiner than that of castings

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Power Loss and Electro-Magnetic Characteristics of Ni-Cu-Zn Ferrites (Ni-Cu-Zn페라이트의 損失과 磁性 特性)

  • Otsuki, E.;Kim, Jeong-Su
    • Resources Recycling
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    • v.13 no.6
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    • pp.37-42
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    • 2004
  • The power loss analysis was carried out for Ni-Cu-Zn ferrite sample with different content of NiO and ZnO. The power loss, Pcv decreases monotonically with increasing temperature and attains to a certain value at around 100~120 degrees Celsius. The frequency dependence of Pcv can be explained by Pcv~f$^n$, and n is independent of the frequency, f up to 1 MHz. The Pcv decreases with an increase in ZnO/NiO. The Pcv was separated to hysteresis loss(Ph) and residual loss(Pcv-Ph). The temperature characteristics and compositional dependence of Pcv can be attributed to the Ph, while Pcv-Ph is not affected by both temperature and ZnO/NiO. By analyzing temperature and composition dependence of Ph and initial permeability, ${\mu}_i$ like following equations could be formularized. ${\mu}_i{\mu}_0=I_s^2/(K_I+b{\sigma}_0{\lambda}_s)$ Wh=13.5(I$_s^2/{\mu}_i{\mu}_0)$ Where ${\mu}_0$ is permeability of vacuum, I$_s$ is saturation magnetization, K$_I$ is anisotropy constant, $s_0$ is internal heterogeneous stress, ${\lambda}_s$ is magnetostriction constant, b is unknown constant, and Wh is hysteresis loss per one cycle of excitation (Ph=Wh${\times}$f). Steinmetz constant of Ni-Cu-Zn ferrite, m=1.64~2.2 is smaller than that of Mn-Zn ferrites, which suggests the difference of loss mechanisms between these materials.

Power Loss and Electro-Magnetic Characteristics of Ni-Cu-Zn Ferrites (Ni-Cu-Zn페라이트의 손실과 자성 특성)

  • Otsuki E.;Kim Jeong-Su
    • Proceedings of the Korean Institute of Resources Recycling Conference
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    • 2004.12a
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    • pp.3-11
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    • 2004
  • The power loss analysis was carried out for Ni-Cu-Zn ferrite samples with different content of NiO and ZnO. The power loss, Pcv decreases monotonically wi increasing temperature and attains to a certain value at around $100\~120$ degrees Celsius. The frequency dependence of Pcv can be explained by $Pcv\~f^n$', and n is independent of the frequency, f up to 1MHz. The Pcv decreases with an increase in ZnO/NiO. The Pcv was separated to hysteresis loss, Ph and residual loss, (Pcv-Ph). The temperature characteristics and compositional dependence of Pcv can be attributed to the Ph, while (Pcv-Ph) is not affected by both temperature and ZnO/NiO. By analyzing temperature and composition dependence of Ph and initial permeability, ${\mu}^i$ following equations could be formularized. $${\mu}_i{\mu}o=I_x\;^2/(K_1+bs_ol_s)\;\;\;\;(1)$$ $Wh=13.5(I_s\;^2/{\mu}_i{\mu}_o)\;\;\;\;(2)$$ Were ${\mu}_o$ is permeability of vacuum, $I_s$ saturation magnetization, $K_1$ anisotropy constant, $S_o$ internal heterogeneous stress, $I_s$, magnetostriction constant, b unknown constant. Wh hysteresis loss per one cycle of excitation (Ph: Wh*f). Steinmetz constant of Ni-Cu-Zn ferrites, $m=1.64\~2.2$ is smaller than the one of Mn-Zn ferrites, which suggests the difference of loss mechanism between these materials.

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The Effect of LiBr Concentration on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 LiBr 농도의 영향)

  • Lim Uh Joh;Jeong Ki Cheol
    • Journal of the Korean Institute of Gas
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    • v.5 no.4 s.16
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    • pp.33-39
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    • 2001
  • This paper was studied on corrosion behavior of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the various concentration of lithium bromide solution, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze is carried out. And the corrosion behavior of materials forming absorption refrigeration systems is investigated. The main results are as following: 1) As concentration of lithium bromide solution increases, polarization resistance of materials of each kinds is low. And open circuit potential becomes less noble, the corrosion current density is high drained 2) Open circuit potential of SS 400 is less noble than that of Cu and Al-Ni bronze, corrosion current density of SS5 400 is high drained than that of Cu and Al-Ni bronze. 3) Anodic polarization of Cu and Al-Ni bronze in $62\%$ LiBr solution continues the active state. that of Cu and Al-Ni bronze in the natural sea water maintains the active state and the critical current for passivation appears.

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Effects of Shape Anisotropy on Memory Characteristics of NiFe/Co/Cu/Co Spin Valve Memory Cells (NiFe/Co/Cu/Co 스핀밸브 자기저항 메모리 셀에서 형상자기이방성이 메모리 특성에 미치는 영향)

  • 김형준;조권구;주승기
    • Journal of the Korean Magnetics Society
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    • v.9 no.6
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    • pp.301-305
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    • 1999
  • NiFe(60$\AA$)/Co(5$\AA$)/Cu(60$\AA$)/Co(30$\AA$) spin valve thin films were patterned into magnetoresistive random access memory (MRAM) cells by a conventional optical lithography process and their output and switching properties were characterized with respect to the cell size and geometry. When 1 mA of constant sense current was applied to the cells, a few or a few tens of mV of output voltage was measured within about 30 Oe of external magnetic field, which is an adequate output property for the commercializing of competitive MRAM devices. In order to resolve the problem of increase in the switching thresholds of magnetic layers with the downsizing of MRAM cells, a new approach using the controlled shape anisotropy was suggested and interpreted by a simple calculation of anisotropy energies of magnetic layers consisting of the cells. This concept gave a reduced switching threshold in NiFe(60$\AA$)/Co(5$\AA$) layer consisting of the patterned cells from about 15 Oe to 5 Oe and it was thought that this concept would be much helpful for the realization of competitive MRAM devices.

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Magnetic Properties of Nano-Sized CuNi Clusters

  • Jo, Y.;Jung, M.H.;Kyum, M.C.;Park, K.H.;Kim, Y.N.
    • Journal of Magnetics
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    • v.11 no.4
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    • pp.156-159
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    • 2006
  • We have studied the magnetic properties of the CuNi nanoparticles for three different sizes prepared by plasma and chemical techniques. The magnetization is enormously enhanced with decreasing the nanoparticle size. This enhanced magnetic moment shows almost inversely linear temperature dependence, which could be interpreted by the Langevin-type superparamagnetism. The field dependence exhibits ferromagnetic-like behavior with weak hysteresis, which could described in terms of uncompensated spin and/or surface anisotropy. In addition, the magnetic data suggest that the CuNi nanoparticles produced by the plasma method result in significantly less oxidized metallic nanoparticles than those prepared by other techniques.

Growth of the substrate crystals for $La_{2-x}Sr_{x}CuO_{4}$ thick films

  • Watauchi, Satoshi;Tanabe, Hideyoshi;Tanaka, Isao;Kojima, Hironao
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.4
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    • pp.384-386
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    • 1999
  • The distribution coefficients of Ni and Zn to the Cu site in $La_{2-x}Sr_{x}CuO_{4}$(LCO) were investigated to determine the suitable solvent composition ofr crystal growth of $La_{2}{Cu}_{1-x}{M}_{x}{O}_{4}$(M=NI, Zn)(LCMO), and were found to be 4.2 for NI and 0.66 for Zn, respectively. Single crystals of LCO, and LCMO of high homogeneity were grown by traveling solvent floating zone technique using suitable solvents. NO diamagnetic signals were observed for all substituted crystals. This fact suggests that crystals of LCO partially substituted by Ni or Zn are useful as substrate crystals.

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The Effect of Temperature on Corrosion of Absorption Refrigeration Systems Using $LiBr-H_2O$ Working Fluids ($LiBr-H_2O$계 흡수식냉동기의 부식에 미치는 온도의 영향)

  • 임우조;정기철
    • Journal of Advanced Marine Engineering and Technology
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    • v.26 no.1
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    • pp.125-131
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    • 2002
  • This paper was studied on the effect of temperature on corrosion of absorption refrigeration systems using $LiBr-H_2O$ working fluids. In the fresh water and 62 % lithium bromide solution at $70^{\circ}C$, polarization test of SS 400, Cu(C1220T-OL) and Al-Ni bronze was carried out. And polarization behavior, polarization resistance characteristics, corrosion rate(mmpy) and corrosion sensitivity of materials forming absorption refrigeration systems was considered. The main results are as following: (1) As the experimental temperature increase, the change of corrosion rate of Al-Ni bronze become duller than SS 400 and Cu in 62% lithium bromide solution. (2) According as corrosion environment is changed from fresh water to 62% lithium bromide solution, potential change of Cu and Al-Ni bronze become less noble than SS 400. (3) The corrosion sensitivity of Al-Ni bronze was duller than that of Cu and SS 400 in 62% LiBr solution.

The Role of Grain Boundary Diffusion in the Activated Sintering of Tungsten Powder (텅스텐 활성소결에서 입계확산의 역할)

  • 이재성
    • Journal of Powder Materials
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    • v.1 no.1
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    • pp.79-84
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    • 1994
  • The mechanism of activated sintering of tungsten powder was discussed in terms of diffusion and segregation of activator atoms at W grain boundaries. Shrinkage behaviours of W-0.2wt.% Ni, W-0.2wt.% Cu or pure W powder compacts during sintering at low temperatures of 900~ $1200^{\circ}C$ were investigated. It was found that the Cu additive inhibits sintering process causing lower densification than pure W compact while remarkable shrinkage occurred in the Ni added W powder. Such contrary effect was explained by comparing self diffusion processes along Ni or Cu segregated W boundaries in which Ni segregants enhance but Cu atoms retard the migration of W atoms at W boundaries.

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