• Title/Summary/Keyword: CuNi

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Piezoelectric Characteristics of Low-temperature Sintered PSN-PZT Ceramics as a Function of Zr/Ti Ratio (저온소결한 PSN-PZT 세라믹스의 Zr/Ti 비에 따른 압전특성)

  • 류주현;우원희;오동언;정영호;정광현;류성림
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.12S
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    • pp.1195-1199
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    • 2003
  • In this study, in order to develop the low temperature sintering ceramics for multilayer piezoelectric transformer, dielectric and piezoelectric properties of PSN-PZT[0.91Pb(Sb$\sub$1/2/Nb$\sub$1/2/)$\sub$0.03/(Zr$\sub$0.495/Ti$\sub$0.505/)$\sub$0.97/O$_3$-0.04Pb(Ni$\sub$1/2/W$\sub$1/2/)O$_3$+0.05BiFeO$_3$+0.3wt%MnO$_2$+0.6wt%CuO〕 ceramics were investigated according to Zr/Ti ratio. As Zr/Ti ratio is increased, electromechanical coupling factor(k$\sub$p/) and dielectric constant increased and then decreased after the ratio of Zr/Ti=50/50. Also, mechanical qualify factor(Q$\sub$m/) decreased and then increased after the ratio of Zr/Ti=50/50.

Size and Aspect Ratio Effects on the Magnetic Properties of a Spin-Valve Multilayer by Computer Simulation

  • Lim, S.H.;Han, S.H.;Shin, K.H.;Kim, H.J.
    • Journal of Magnetics
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    • v.5 no.3
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    • pp.90-98
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    • 2000
  • The change in the magnetic properties of a spin-valve multilayer with the structure IrMn (9 m)/CoFe (4 nm)/Cu (2.6 nm)/CoFe (2 nm)/NiEe (6 nm) is investigated as a function of the size and the aspect ratio. At a fixed aspect ratio (the length/width ratio) of 2, the magnetostatic interactions begin to affect the magnetic properties substantially at a spin-valve length of 5 $\mum$, and, at a length of 1 $\mum$, they become even more dominant. In the case of a fixed multilayer size (2.4 $\mum$) which is indicated by the sum of the length and the width, magnetization change occurs by continuous spin-reversal and M-H loops are characterized by no or very small hysteresis at aspect ratios smaller than unity, At aspect ratios greater than unity, magnetization change occurs by spin-flip resulting in squared hysteresis loops. A very large changes in the coercivity and the bias field is observed, and these results are explained by two separate contributions to the total magnetostatic interactions: the coercivity by the self-demagnetizing field and the bias field by the interlayer magnetostatic interaction field.

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Performance Evaluation of Multi Effect Distillation for Solar Thermal Desalination (태양열 해수담수화를 위한 증발식 다중효용 담수기 성능평가)

  • Joo, Hong-Jin;Kwak, Hee-Youl
    • 한국태양에너지학회:학술대회논문집
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    • 2011.04a
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    • pp.74-79
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    • 2011
  • This study was accomplished to evaluate the performance of Multi Effect Distillation(MED) for solar thermal desalination system. It was designed Multi effect distillation with $3m^3/day$ capacity and Shell&Tube type heat exchanger. Also, The effective heat transfer of Shell&Tube heat exchanger was used Cu(90%)-Ni(10%) corrugated tube. The parameters relating to the performance of Multi Effect Distillation are known as hot water flow rate. The experimental conditions for each parameters were $18^{\circ}C$ for sea water inlet temperature, $6m^3/hour$ sea water inlet volume flow rate, $75^{\circ}C$ for hot water inlet temperature, 2.4, 3.6, and $4.8m^3/hour$ for hot water inlet volume flow rate, respectively. The results are as follows, Development for Multi effect distillation was required about 40kW heat and 35kW cooling source to produce $3m^3/day$ of fresh water. And, Performance ratio of Development Multi effect distillation was about 2.0191.

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Suppression of Charge Recombination Rate in Nanocrystalline SnO2 by Thin Coatings of Divalent Oxides in Dye-Sensitized Solar Cells

  • Lee, Chae-Hyeon;Lee, Gi-Won;Kang, Wee-Kyung;Lee, Doh-Kwon;Ko, Min-Jae;Kim, Kyoung-Kon;Park, Nam-Gyu
    • Bulletin of the Korean Chemical Society
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    • v.31 no.11
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    • pp.3093-3098
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    • 2010
  • The core-shell $SnO_2$@AO (A=Ni, Cu, Zn and Mg) films were prepared and the effects of coatings on photovoltaic properties were investigated. Studies on X-ray photoelectron spectroscopy, energy dispersive X-ray analysis and transmission electron microscopy showed the formation of divalent oxides on the surface of $SnO_2$ nanoparticles. It was commonly observed that all the dye-sensitized core-shell films exhibited higher photovoltage than the bare $SnO_2$ film. Transient photovoltage measurements confirmed that the improved photovoltages were related to the decreased time constants for electron recombination.

Electrochemical Sensor for the Selective Determination of Prindopril Based on Phosphotungestic Acid Plastic Membrane

  • Zareh, Mohsen M.;Wasel, Anower M.;Alkreem, Yasser M. Abd
    • Bulletin of the Korean Chemical Society
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    • v.34 no.10
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    • pp.3088-3092
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    • 2013
  • A novel PVC membrane sensor for perindopril based on perindopril-phosphotungstate ion pair complex was prepared. The influence of membrane composition (i.e. percent of PVC, plasticizer, ion-pair complex, and kind of plasticizer), inner solution, pH of test solution and foreign cations on the electrode performance was investigated. The optimized membrane demonstrates Nernstian response ($30.9{\pm}1.0$ mV per decade) for perindopril cations over a wide linear range from $9.0{\times}10^{-7}$ to $1{\times}10^{-2}$ M at $25^{\circ}C$. The potentiometric response is independent of the pH in the range of 4.0-9.5. The proposed sensor has the advantages of easy preparation, fast response time. The selectivity coefficients indicate excellent selectivity for perindopril over many common cations (e.g., $Na^+$, $K^+$, $Mg^{2+}$, $Cu^{2+}$, $Ni^{2+}$, rhamnose, maltose, glycine and benzamide. The practical applications of this electrode was demonstrated by measuring the concentrations of perindopril in pure solutions and pharmaceutical preparations with satisfactory results.

Development of Multi Effect Distillation for Solar Thermal Seawater Desalination System (태양열 해수담수화 시스템을 위한 다중효용 담수기 개발)

  • Joo, Hong-Jin;Hwang, In-Seon;Kwak, Hee-Youl
    • Journal of the Korean Solar Energy Society
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    • v.31 no.1
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    • pp.1-7
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    • 2011
  • This study was accomplished to evaluate the performance of Multi Effect Distillation(MED) for solar thermal desalination system. It was designed Multi effect distillation with $3m^3$/day capacity and Shell&Tube type heat exchanger. Also, The effective heat transfer of Shell&Tube heat exchanger was used Cu(90%)-Ni(10%) corrugated tube. The parameters relating to the performance of Multi Effect Distillation are known as hot water flow rate. The experimental conditions for each parameters were $18^{\circ}C$ for sea water inlet temperature, $6m^3$/hour sea water inlet volume flow rate, $75^{\circ}C$ for hot water inlet temperature, 2.4, 3.6, and $4.8\;m^3$/hour for hot water inlet volume flow rate, respectively. The results are as follows, Development for Multi effect distillation was required about 40kW heat and 35kW cooling source to produce $3m^3$/day of fresh water. Based on the results of this study, It makes possible to secure economics of desalination system with solar energy which is basically needed development of high efficiency fresh water generator.

Tensile Deformation Behavior of Zr-based Bulk Metallic Glass Composite with Different Strain Rate (Zr 계 벌크 비정질 복합재의 변형률 속도에 따른 인장 변형 거동)

  • Kim, Kyu-Sik;Kim, Ji-Sik;Huh, Hoon;Lee, Kee-Ahn
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2009.05a
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    • pp.353-354
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    • 2009
  • Tensile deformation behavior with different strain rate was investigated. $Zr_{56.2}Ti_{13.8}Nb_{5.0}Cu_{6.9}Ni_{5.6}Be_{12.5}$ (bulk metallic glass alloy possessed crystal phase which was called $\beta$-phase of dendrite shape, mean size of $20{\sim}30{\mu}m$ and occupied 25% of the total volume) was used in this study. Maximum tensile strength was obtained as 1.74Gpa at strain rate of $10^2/s$ and minimum strength was found to be 1.6GPa at $10^{-1}/s$. And then, maximum plastic deformation occurred at the strain rate of $5{\times}10^{-2}/s$ and represented 1.75%, though minimum plastic deformation showed 0%. In the specific range of strain rate, relatively higher plastic deformation and lower ultimate tensile strength were found with lots of shear bands. The fractographical observation after tensile test indicated that vein like pattern on the fracture surface was well developed especially in the above range of strain rate.

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Removal of Some Metals in Drinking Water by Preparing Barley or Corn Tea (보리차 및 옥수수차 제조에 따른 음용수 중 일부 금속들의 제거)

  • 이수형;박송자;김희갑
    • Environmental Analysis Health and Toxicology
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    • v.16 no.1
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    • pp.35-41
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    • 2001
  • Barley or corn tea, which is usually prepared with municipal chlorinated tap water, is commonly consumed by the public as a substitute for the supplied water itself. This is because most people believe that harmful organic and inorganic compounds can be removed from the tap water by the adsorption mechanism during the tea preparation. In this study, three kinds of commercial grain tea materials-roasted barley grains, a tea bag containing barley grain pieces, and roasted corn grains-were tested for metal removal by preparing 1 liter of tea with deionized/distilled water according the manufacturer's recommended preparation procedures, assuming that the water is contaminated with eight selected metals at levels of 50$\mu\textrm{g}$/l. Of the tested teas, barley tea prepared with roasted grains showed the highest removal efficiency for Cu, As, Ni, Co, Pb, and Cd, ranging from 48 to 71%, followed by corn tea with roasted grains and barley tea with a tea bag. Cr was nearly maintained at the initial concentration in all kinds of tea. The Mn levels. however, were elevated during the tea preparation, particularly in both barley teas, probably because the metal was extracted into the water from the tea materials without significant adsorption. Therefore, it should be considered in the ingestion exposure analysis for metals that their concentrations are altered during the tea preparation with roasted barley or corn grain materials.

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Removal Process of Metallic Impurity for Silicon Surface Detergent by Ion Exchange (실리콘 표면처리에 있어서 이온교환 막에 의한 금속불순물의 제거공정)

  • Yeon, Young-Heum;Choi, Seung-Ok;Jeong, Hwan-Kyung;Nam, Ki-Dea
    • Journal of the Korean Applied Science and Technology
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    • v.16 no.1
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    • pp.75-81
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    • 1999
  • HF purification performance of an ion exchange membrane(IEM) was evaluated with 0.5% HF spiked with 10ppb of Fe, Ni and Cu nitrates. The result show that after less than five turnovers through an IEM, the metallic impurity concentration drops below 1ppb. The decrease rate can be fitted to a model assuming the experimental tanks to be continuously stirred tank reaction and that the metallic impurity concentration after the IEM is a function of the single-pass purification efficiency of the membrane, the concentration before purification and the metals desorbed form the IEM. The Concentration after purification was investigated up to a cumulative Fe loading of 300ppb in the 23 liter recirculated loop. It increases linearly vs. cumulative loading and can be explained by the Langmuir theory resulting in a purification efficiency at the equilibrium of close to 99.5% in this loading regime.

Mineral Contents of Edible Seaweeds Collected from Gijang and Wando in Korea (기장산과 완도산 식용해조류 중의 미네랄 함량)

  • Im, Yung-Geun;Choi, Jin-Seok;Kim, Dong-Soo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.39 no.1
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    • pp.16-22
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    • 2006
  • Mineral and heavy metal contents were determined in three brown edible seaweeds (sea mustard, Undaria pinnatifida; seaweed fusiforme, Hizikia fusiforme; sea tangle, Laminaria japonica) collected from Gijang and Wando in Korea, and two green seaweeds (sea lettuce, Enteromorpha prolifera; green laver, Monostroma nitidum) collected from Gijang. Seaweeds contained high proportions of ash (13.8-24.8%) and sulfate (1.08-3.25%). In brown seaweeds, ash contents (24.5-24.8%) were higher than in green seaweeds (13.8-15.2%). The differences of mineral contents were remarkable in both Gijang and Wando and in 5 various kinds of seaweeds. Brown seaweeds contained higher amounts of both macro-minerals (657-13,947 mg/100 g; Ca, Mg, Na, K) and trace elements (0.27-12.98 mg/100 g; Fe, Al, Zn, Mn, Cr, Cu, Ni), and green seaweeds also had relatively higher amounts of both macro-minerals (233-5,279 mg/100 g) and trace elements (0.26-10.61 mg/100 g).