• 제목/요약/키워드: Cu-S

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진공증착에 의해 제조된 $CuInS_2$ 박막의 제작 및 특성 (Fabrication and Characteristics of $CuInS_2$ thin films produced by Vacuum Evaporation)

  • 양현훈;김영준;소순열;정운조;박계춘;이진;정해덕
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 추계학술대회 논문집 광주전남지부
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    • pp.68-70
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    • 2006
  • $CuInS_2$ thin films were synthesized by sulpurization of Cu/In Stacked elemental layer deposited onto glass Substrates by vacuum furance annealing at temperature 200[$^{\circ}C$]. And structural and electrical properties were measured in order to certify optimum conditions for growth of the ternary compound semiconductor $CuInS_2$ thin films with non-stoichiometry composition. $CuInS_2$ thin film was well made at the heat treatment 200 [$^{\circ}C$] of SLG/Cu/In/S stacked elemental layer which was prepared by thermal evaporator, and chemical composition of the thin film was analyzed nearly as the proportion of 1:1:2. Physical properties of the thin film were investigated at various fabrication conditions substrate temperature, annealing and temperature, annealing time by XRD, FE-SEM and hall measurement system. At the same time, carrier concentration, hall mobility and resistivity of the thin films was $9.10568{\times}10^{17}[cm^{-3}]$, $312.502[cm^2/V{\cdot}s]$ and $2.36{\times}10^{-2}[{\Omega}{\cdot}cm]$, respectively.

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Hot Wall Epitaxy(HWE)법에 의한 $CuAlSe_2$ 단결정 박막 성장과 광발광 특성 (Photoluminescience Properties and Growth of $CuAlSe_2$ Single Crystal Thin Film by Hot Wall Epitaxy)

  • 이상열;홍광준
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.1
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    • pp.386-391
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    • 2003
  • Sing1e crystal $CuAlSe_2$ layers were grown on thoroughly etched semi-insulating GaAs(100) substrate at $410^{\circ}C$ with hot wall epitaxy (HWE) system by evaporating $CuAlSe_2$source at $680^{\circ}C$. The crystalline structure of the single crystal thin films was investigated by the photoluminescence(PL) and double crystal X-ray diffraction (DCXD). The carrier density and mobility of single crystal $CuAlSe_2$ thin films measured with Hall effect by van der Pauw method are $9.24{\times}10^{16}\;cm^{-3}$ and $295\;cm^2/V{\cdot}\;s$ at 293 K, respectively. The temperature dependence of the energy band gap of the $CuAlSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)\;=\;2.8382\;eV\;-\;(8.86\;{\times}\;10^{-4}\;eV/K)T^2/(T\;+\;155K)$. After the as-grown single crystal $CuAlSe_2$ thin films were annealed in Cu-, Se-, and Al-atmospheres, the origin of point defects of single crystal $CuAlSe_2$ thin films has been investigated by PL at 10 K. The native defects of $V_{Cd}$, $V_{Se}$, $Cd_{int}$, and $Se_{int}$ obtained by PL measurements were classified as donors or accepters. And we concluded that the heat-treatment in the Cu-atmosphere converted single crystal $CuAlSe_2$ thin films to an optical n-type. Also, we confirmed that Al in $CuAlSe_2/GaAs$ did not form the native defects because Al in single crystal $CuAlSe_2$ thin films existed in the form of stable bonds.

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고효율 전동기용 Cu Rotor의 반응고 성형과 공정변수 제어 (Process Control and Thixoforming of Cu Rotor for High Efficiency Motors)

  • 정우성;이상용;신평우
    • 소성∙가공
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    • 제14권7호
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    • pp.642-648
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    • 2005
  • Rotor in small-medium induction motor has been usually manufactured by aluminum diecasting. In order to improve the efficiency of induction motors, newly developed Cu-Ca alloys have been investigated. The electrical conductivity in the Cu alloys containing Ca less than $1.0wt\%$ was higher than $80\%$ IACS. Cu-Ca alloy is desirable for the thixoforming process because it has wide semi-solid range over $150^{\circ}C$. In this study, Cu-rotor with thixoforming process was developed to replace the conventional aluminum diecasting rotor. Analysis was performed for the microstructure of thixoforming rotor. Effect of incomplete filling on the efficiency of induction motor was discussed.

고효율 전동기용 Cu Rotor의 반응고 성형과 공정변수 제어 (Process Control and Thixoforming Cu Rotor for High Efficiency Motors)

  • 정우성;이상용;신평우
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 2005년도 춘계학술대회 논문집
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    • pp.233-236
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    • 2005
  • Rotor in small-medium induction motor has been usually manufactured by aluminum diecasting. In order to improve efficiency of induction motors, newly developed Cu-Ca alloys have been investigated. The electrical conductivity in the Cu alloys containing Ca less than $1.0wt\%$ was higher than $80\%$ IACS. Cu-Ca alloy is desirable for the thixoforming process because it has wide semi-solid range over $150^{\circ}C$. In this study, Cu-rotor with thixoforming process was developed to replace the conventional aluminum diecasting rotor. Analysis microstructure of thixoforming rotor. effect of incomplete filling defect on the efficiency of induction motor was discussed.

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$Bi_2Sr_2CaCu_2O_{8+\delta}$ 고온초전도체의 d-파 대칭성 증거로서의 $Pb/Bi_2Sr_2CaCu_2O_{8+\delta}$접합 투과전도특성 (Tunneling Characteristics in $Pb/Bi_2Sr_2CaCu_2O_{8+\delta}$ Junctions as an Evidence for a d-wave Order Parameter Symmetry in $Bi_2Sr_2CaCu_2O_{8+\delta}$ Superconductors)

  • Chang, Hyun-Sik;Lee, Hu-Jong
    • Progress in Superconductivity
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    • 제2권2호
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    • pp.65-70
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    • 2001
  • $Pb/Bi_2Sr_2CaCu_2O_{8+\delta}$-single-crystal junctions with the tunneling direction along the c axis of the crystal were fabricated to obtain an s-wave-superconductor/d-wave-superconductor Josephson junctions. The tunneling R (T) curves and current-voltage characteristics show distinct features which can be explained only under the assumption that the order parameter of high-$T_c/Bi_2Sr_2CaCu_2O_{8+{\delta}}$ superconductors has a pure d-wave symmetry, which is in contrast to the case of $YBa_2Cu_3O_{7+{\delta$}}$erconductors where a minor s-wave component is also present..

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$Cu_2/CdS$ 태양전지 제작 및 그 특성연구 (Fabrication of $Cu_2/CdS$ solar cell and its characteristics)

  • 유평렬;김현숙;이재윤;강창훈;박은옥;정태수;김택성;양동익;신영진
    • 한국결정성장학회지
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    • 제7권2호
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    • pp.315-323
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    • 1997
  • 수직승화방법을 이용하여 시료의 용융점 미만의 온도에서 CdS 단결정을 성장하였다. 분말법을 이용한 X-ray 실험으로부터 구한 CdS 단결정의 격자상수 값은 $a_0=4.139\AA$, $c_0=6.719\AA$이었다. 성장된 CdS 단결정과 CuCl 용액을 사용하여 $Cu_2$S/CdS 태양전지를 제작한 후 2분 동안 공기중에서 $250^{\circ}C$로 열처리한 후 light-to-dark J-V cross over effect를 측정하였다. 측정된 Voc, Jsc, Vop와 fill factor값은 각각 0.40 volt, $4.2mA/\textrm{cm}^2$, 0.31 volt,$3.8mA/\textrm{cm}^2$, 0.68이었으며, 효율은 3.8 %를 나타내었다. 제작된 태양전지의 spectral response는 광발광 실험으로부터 498 nm (2.49eV)와 585 nm (2.12 eV)에서 그 peak가 나타남을 확인하였다.

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Al-Cu-Mg 합금의 석출입자, 특히 S-상 입자들에 의한 변형장의 LACBED 관찰 (LACBED Observation of Strain Fields due to Precipitates, Especially S-Phase Particles in Al-Cu-Mg Alloy)

  • 김황수
    • Applied Microscopy
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    • 제37권2호
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    • pp.123-133
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    • 2007
  • Al합금(Al-2.5Cu-1.5Mg wt.%)의 석출물 특히 S-상석출입자 $(Al_2CuMg)$ 부근의 변형장 (strain fields)에 대해 LACBED 관찰 연구가 처음으로 수행되었다. 변형장 강도에 대한 정량적 분석을 위해서는 대응되는 LACBED패턴 시뮬레이션 필요하다. 이를 위해 S-입자에 대해서 형태가 단순한 $a_s$-축을 가진 원기둥 모양을 갖고 변형장의 격자변위 벡터가 이 축에 수직 방향을 갖는다고 가정했다. 이런 단순한 모델을 가지고 변형장에 대한 관찰 패턴과 시뮬레이션 사이 합리적인 일치를 얻었다. 그러나 합금의 초기 시효 단계에서는 의미 있는 변형장이 관측되지 않았다. 따라서 이 실험의 결과로 예상되는 것은 합금의 최대 경도를 갖는 시료에는 S-상 석출 입자들이 Al-모체에 복잡한 변형장 그물망을 만들고 이것이 합금 경도에 기여 할 것으로 사료된다.

Brightness Improvement of ZnS:Cu Powder Electroluminescence by Mixed Layer

  • Lee, Jong-Chan;Park, Dae-Hee
    • KIEE International Transactions on Electrophysics and Applications
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    • 제4C권2호
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    • pp.64-67
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    • 2004
  • In this paper, to discover the brightness improvement of ZnS:Cu powder electroluminescence (EL), a new structure is proposed in which phosphor and dielectric are mixed between electrodes. Dielectric and phosphor material are BaTiO$_3$ and ZnS:Cu, respectively. The effect of the mixed layer on EL sample is considered the improvement of source efficiency. Although the number of electrons introduced into the phosphor increases only modestly, the high electric field region of phosphor grains increases comparatively in the characteristics of brightness-voltage. Furthermore, the relaxation occurs through leading and trailing edge pairs, which is relatively efficient in characteristics of decay time. With these results, we found that the brightness of newly proposed ZnS:Cu powder electroluminescence was 167.24 cd/$m^2$ at ac voltage of 100V and frequency of 400Hz.

ZnS:Cu 형광체의 전계 발광 및 가속열화 특성 (Electroluminescent and Accelerated Aging Properties of ZnS:Cu Phosphor)

  • 이종찬;황명근;박대희
    • 한국조명전기설비학회:학술대회논문집
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    • 한국조명전기설비학회 2001년도 학술대회논문집
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    • pp.13-16
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    • 2001
  • In this paper, the emission and aging properties of ZnS:Cu electroluminescent device were experiment respectively at room temperature and 7$0^{\circ}C$ relative humidity 100%. ZnS:Cu and BaTiO$_3$were respectively used for phosphor and dielectric. While AC 100V on 400Hz frequency were applied to the devices at room temperature and 70$_3$relative humidity 100%, the change of brightness were measured and compared. The surface of aged devices were investigated by scanning electron microscope. With the continuously operated environment of room temperature and 7$0^{\circ}C$ relative humidity 100%, the decay time were measured and the dark spot and aging status on the surface of the device were investigated. ZnS:Cu electroluminescent properties were deteriorated by the Increased temperature and humidity. Also the deteriorated properties were confirmed by the brightness and surface chanties of device, and the aging mechanism from the simulation on sulfur vacancy and deep tracts density.

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