• Title/Summary/Keyword: Cu dopant

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First-principles Study on Magnetism of Cu in GaN

  • Kang, Byung-Sub;Heo, Chul-Min;Lyu, Kwang-Kwyun;Yu, Seong-Cho
    • Journal of Magnetics
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    • v.14 no.3
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    • pp.114-116
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    • 2009
  • The electronic properties of Cu or Pd-doped GaN at several concentrations are examined using the full-potential linear muffin-tin orbital method. For ($Cu_{0.055}Ga_{0.945}$)N, the model reveals a magnetic moment of $1.47{\mu}B$ per supercell. The range of concentrations that are spin-polarized should be restricted within narrow limits. A paramagnetic to ferromagnetic phase transition is found to occur at a Cu concentration of 5.55%.

Study on the reducibility of substituted $LaFeO_3$ (치환된 $LaFeO_3$의 환원반응성에 대한 연구)

  • Jeon, Hyun-Pyo;Lee, Sang-Beom
    • The Journal of Natural Sciences
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    • v.15 no.1
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    • pp.35-46
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    • 2005
  • $LaFeO_3$ and substituted $LaFeO_3$ mixed oxides were prepared by Citrate and Cyanide method in air $850^{\circ}C$/24h. These oxides of orthorhombic perovskite were characterized by XRD and IR, but substituted $LaFeO_3$ with 0.5mol Cu at B site was not obtained single phase. Also, reduction reaction of un-substituted $LaFeO_3.17$ were two steps but each site substituted oxides were three steps reactions. These means that new reduction step of each site substituted oxides were atributed tot dopant.

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Piezoelectric and Dielectric Characteristics of Low Temperature Sintering PMN-PNN-PZT Ceramics according to the addition of dopant (불순물 첨가에 따른 저온소결 PMN-PNN-PZT 세라믹스의 압전 및 유전특성)

  • Lee, Sang-Ho;Lee, Chang-Bae;Jeong, Gwang-Hyeon;Yoo, Joo-Hyun;Hong, Jae-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.11a
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    • pp.33-34
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    • 2005
  • In this study, in odor to develop low temperature sintering multilayer piezoelectric actuator and ultrasonic vibrator, PMN-PNN-PZT ceramics were fabricated using $Li_2CO_3$ and $Na_2CO_3$ as sintering aids and their piezoelectric and dielectric characteristics were investigated according to the addition of dopant CuO and $Fe_2O_3$, respectively. The CuO added PMN-PNN-PZT ceramics improved mechanical quality factor Qm due to the acceptor doping effect. And also, $Fe_2O_3$ reacted as softner in this composition system in addition to the increase of grain size and sinterability. Taking into consideration electromechanical coupling factor kp of 0.62, dielectric constant $\varepsilon_r$, of 1275, Piezoelectric $d_{33}$ constant of 377[pC/N] and mechanical quality factor Qm of 975, it was concluded that the ceramics with the $Fe_2O_3$, added composition sintered at 900[$^{\circ}C$] were best for the multilayer piezoelectric actuator and ultrasonic vibrator application.

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Phonon-Assisted Electron Hopping Conduction in the Uranium Doped One-Dimensional Antiferromagnet Ca2CuO3

  • Thanh, Phung Quoc;Yu, Seong-Cho;Nhat, Hoang-Nam
    • Journal of Magnetics
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    • v.13 no.4
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    • pp.132-135
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    • 2008
  • The authors studied the conduction mechanism in an uranium doped low dimensional magnetic system $Ca_2CuO_3$. This system exhibits the S=1/2 quasi 1D antiferromagnetic chains of -Cu-O- with strong magnetic coupling, and demonstrates continuous semiconductor-like behavior with constant covalent insulator character. This paper identifies the conduction is due to thermally activated phonon-assisted electron hopping between dopant uranium sites. The parameter a, the characteristic for hopping probability, was determined to be 0.18 ${\AA}^{-1}$. This value manifests a relatively stronger hopping probability for $Ca_2CuO_3$ as compared with other uranium doped ceramics.

Embargo Nature of CuO-PANI Composite Against Corrosion of Mild Steel in Low pH Medium

  • Selvaraj, P. Kamatchi;Sivakumar, S.;Selvaraj, S.
    • Journal of Electrochemical Science and Technology
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    • v.10 no.2
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    • pp.139-147
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    • 2019
  • Incorporation of CuO nanoparticles during the polymerization of aniline in the presence of ammonium peroxydisulphate as an oxidizing agent and sodium salt of dodecylbenzene sulphonic acid as dopant as well as surfactant yielded water soluble CuO-PANI composite. Comparison of recorded spectra like FTIR, XRD and SEM with reported one confirm the formation of the composite. Analysis by gravimetric method exposes that the synthesized composite is having resistivity against corrosion, with slight variation in efficiency on extending the time duration up to eight hours in strong acidic condition. OCP measurement, potentiodynamic polarization and EIS studies also confirms the suppression ability of composite against corrosion. Riskless working environment could be provided by the synthesized composite during industrial cleaning process.

Coulometric Titration Study on the Nonstoichiometry in Copper Doped Cobaltous Oxide ((${Co_{1-x}}{Cu_x}$)$_{1-\delta}$ O (전하적정법에 의한 (${Co_{1-x}}{Cu_x}$)$_{1-\delta}$ O의 산소 부정비량 측정)

  • ;Michael Schroeder;Manfred Martin
    • Journal of the Korean Ceramic Society
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    • v.37 no.8
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    • pp.799-804
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    • 2000
  • Coulometric titration experiments have been done for copper doped cobaltous oxide (Co1-xCux)1-$\delta$ O with various dopant concentrations. We present the obtained experimental data and compare our results to those of previous thermogravimetric investigation. The experimental data are fitted by theoretical calculations based on various defect models. For this modeling, we considered different types fo major defects like copper in substitutional and interstitial lattice sites as well as copper vacancy. We also introduced the copper evaporation effect during titration experiment into our consideration.

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Characteristic of Cu-Ag Added Thin Film on Molybdenum Substrate for an Advanced Metallization Process (TFT-LCDs에 적용 가능한 Cu-Ag 박막에 대한 Mo 기판 위에서의 특성조사)

  • Lee, H.M.;Lee, J.G.
    • Korean Journal of Materials Research
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    • v.16 no.4
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    • pp.257-263
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    • 2006
  • We have investigated the effect of silver added to Cu films on the microstructure evolution, resistivity, surface morphology, stress relaxation temperature, and adhesion properties of Cu(Ag) alloy thin films deposited on Mo glue layer upon annealing. In addition, pure Cu films deposited on Mo has been annealed and compared. The results show that the silver in Cu(Ag) thin films control the grain growth through the coarsening of its precipitates upon annealing at $300^{\circ}C{\sim}600^{\circ}C$ and the grain growth of Cu reveals the activation energy of 0.22 eV, approximately one third of activation energy for diffusion of Ag dopant along the grain boundaries in Cu matrix (0.75 eV). This indicates that the grain growth can be controlled by Ag diffusion along the grain boundaries. In addition, the grain growth can be a major contributor to the decreased resistivity of Cu(Ag) alloy thin films at the temperature of $300^{\circ}C{\sim}500^{\circ}C$, and decreases the resistivity of Cu(Ag) thin films to $1.96{\mu}{\Omega}-cm$ after annealing at $600^{\circ}C$. Furthermore, the addition of Ag increases the stress relaxation temperature of Cu(Ag) thin films, and thus leading to the enhanced resistance to the void formation, which starts at $300^{\circ}C$ in the pure Cu thin films. Moreover, Cu(Ag) thin films shows the increased adhesion properties, possibly resulting from the Ag segregating to the interface. Consequently, the Cu(Ag) thin films can be used as a metallization of advanced TFT-LCDs.

Colored Cubic Zirconia(CCZ) Single Crystal Growth by Skull Method (SKull법에 의한 Colored Cubic Zirconia(CCZ)단결정 성장)

  • 김석호;최종건;정대식;오근호
    • Journal of the Korean Ceramic Society
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    • v.25 no.5
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    • pp.443-448
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    • 1988
  • Colored Cubic Zircona(CCZ) single crystals were grown by the skull melting method. The grown crystals were doped with up to 0.1wt% transition (Cu, Ni, Co, Ti, Fe, Mo, Cr, V, Mn) metal ions on ZrO2-Y2O3(9.5~10mol%) and their Optical transmission spectra(λ=300~800nm)data were obtained. Various colors were pronounced due to dopant effects in the grown Crystals.

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Unidirectional Solidification of $Bi_2Te_{2.55}Se_{0.45}$ using a VGF Method (VGF법을 이용한 $Bi_2Te_{2.55}Se_{0.45}$의 일방향 응고에 관한 연구)

  • 김영희;김기수;김수룡;정상진;이윤주;박동선
    • Korean Journal of Crystallography
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    • v.14 no.2
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    • pp.62-66
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    • 2003
  • The preparation of n-type thermoelectric material of Bi₂ Te/sub 2.55/Se/sub 0.45/ doped with CuBr₂ was carried out using a vertical gradient freezing method. With this method, unidirectional solidified Bi₂Te/sub 2.55/Se/sub 0.45/ has been obtained. XRD analysis demonstrated that Bi₂/sub 2.55/Se/sub 0.45/ 5 ingot has grown with prefer orientation of (0 1 5) face. Seebeck coefficient and electrical conductivity were measured as functions of temperature in the range of 373 K to 523 K on the sample which prepared via VGF method.

Novel Electrical Dopants for High Performance OLEDs

  • Leem, Dong-Seok;Lee, Jae-Hyun;Kim, Jang-Joo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.1311-1314
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    • 2008
  • We have developed new electrical dopants of rhenium oxide ($ReO_3$) and cupper iodide (CuI) as p-dopants and rubidium carbonate ($Rb_2CO_3$) as an n-dopant, respectively. $ReO_3$ has advantage of low temperature evaporation (about $300^{\circ}C$) with enhanced device stability. Various kinds of high performance organic light emitting diodes have been realized, including bottom emission, tandem, and top-emission OLEDs.

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