• Journal of the Korean Geosynthetics Society
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• v.13 no.2
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• pp.59-67
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• 2014

The amount of the contaminants that can be adsorbed on the drain was evaluated for the effective remediation of the contaminated soil, and the contaminants adsorptivity of the drain was evaluated by comparing the isothermal adsorption model after carrying out the contaminants adsorption test of the reactants coated on the surface of the drain. The reactant used in the experiment is a natural zeolite, and the contaminants are copper, lead and cadmium. The results that Freundlich and Langmuir adsorption isotherm model are compared to the adsorption amount according to the change of the initial concentration by the contaminants. As a result of the component analysis, because Si, Al and O are contained approximately 28%, 11% and 48%, respectively, it is identified that the material coated on the surface of the drain is the component of the zeolite which is the reactant for the adsorption of the heavy-metal (Cu, Pb, Cd) contaminants. The heavy-metal adsorption kinetic of the zeolite which is the reactant was decreased in order of lead, copper and cadmium. The important factor of the performance evaluation of the adsorbent is the reaction rate, and if zeolite is used as the reactant in the relationship between the maximum amount of adsorption and reaction rate, it can be utilized as the design factor that determine the removal order of the complex heavy-metal. In other words, because the maximum adsorption quantity of lead is smaller compared to copper but the reaction rate is relatively fast, it can be primarily removed, and copper can be removed after removing the lead. It was analyzed that Cadmium can be finally removed after that other heavy-metal is removed.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2015.07a
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• pp.179-180
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• 2015

The variety of organic and inorganic pollutants are introduced to coastal sediment and making highly contaminated due to rapid development of industralization and economic development. Numerous contaminants are release into marine sediment and it significantly affect marine aquatic environment. In the present study stated the optimize the biostimulant ball (BSB) in coastal sedimentand stabilse the heavy metals present in the sediment. The effective variables like BSB size, distance and month variables on Cu stabilization was determined by using Response surface methodology(RSM). The analysis of variance (ANOVA) and coefficient determination (R2) of Cu reduction 0.9610 and maximum stabilisation was obtained in 3cm ball size and 5.5cm distance and 4 month interval time. This result revealed that the BSB in effective for Cu reduction in coastal sediment.

• Journal of the Korean Geotechnical Society
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• v.24 no.6
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• pp.17-25
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• 2008

Permeable reactive barriers (PRBs) technology can be applied to contaminated groundwater remediation. It is necessary to select adequate reactive material according to contaminant characterization. In groundwater. In this research, the reaction between reactive material and heavy metal contaminants was estimated through batch test. Reactive material was slag, which has been produced in Gwangyang power plant, and heavy metal contaminants were cadmium, lead and copper. Batch test consisted of two testes: 1) sorption equilibrium test and 2) sorption kinetic test. Sorption equilibrium test was performed for estimating slag sorption capacity against contaminants. And sorption kinetic test was performed for slag sorption rate with contaminants species, contaminants initial concentration and sulfate. Sorption capacity and sorption rate were affected by contaminant species. Sorption rate increased with increasing initial concentration in lead and copper but decreased with increasing initial concentration in cadmium. Sorption rate increased in existing sulfate. In low concentration, film diffusion was domain mechanism, and in high concentration, particle diffusion was domain mechanism.

• Journal of Korean Society on Water Environment
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• v.28 no.4
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• pp.615-623
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• 2012

In this study, we evaluate the corrosion indexes (CI) such as Langelier Index (LI), Larson ratio (LR), Ryznar saturation index (RSI), Aggressiveness index (AI) of water quality for raw water, treated water and water in distribution reservoir at major eight drinking water treatment plants (DWTPs) in Korea. By analyzing secondary contamination of tap water, the variation of secondary contaminants was investigated with regard to pipe materials, aging and corrosion index (CI). In addition, we suggested an appropriate CI applicable water quality and the management plan for CI monitoriing. All CI showed corrosive water quality, and they did not change significantly in the distribution network. However, Copper (Cu), iron (Fe) and zinc (Zn) concentrations as secondary contaminants increased through the distribution network. Among CI, LI was most sensitive to changes in raw water quality and drinking water treatment. Also, it has high correlations with other indexes such as RSI, AI. Therefore, LI is considered as an appropriate CI to the domestic water quality. Based on these result, we propose LI as a drinking water quality standard to control the pipe corrosion from DWTPs.

• Carbon letters
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• v.10 no.2
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• pp.114-122
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• 2009

Crushed, depitted peach stones were impregnated activated with 50% $H_3PO_4$ followed by pyrolysis at $500^{\circ}C$. Two activated carbons were produced, one under its own evolved gases during pyrolysis, and the second conducted with air flow throughout the carbonization stage. Physicochemical properties were investigated by several procedures; carbon yield, ash content, elemental chemical analysis, TG/DTG and FTIR spectra. Porosity characteristics were determined by the conventional $N_2$ adsorption at 77 K, and data analyzed to get the major texture parameters of surface area and pore volume. Highly developed activated carbons were obtained, essentially microporous, with slight effect of air on the porous structure. Oxygen was observed to be markedly incorporated in the carbon matrix during the air treatment process. Cation exchange capacity towards Cu (II) and Cd (II) was tested in batch single ion experimental mode, which proved to be slow and a function of carbon dose, time and initial ion concentration. Copper was up taken more favorably than cadmium, under same conditions, and adsorption of both cations was remarkably enhanced as a consequence of the air treatment procedure. Sequestration of the metal ions was explained on basis of the combined effect of the oxygen functional groups and the phosphorous-containing compounds; both contributing to the total surface acidity character.

• Journal of Soil and Groundwater Environment
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• v.20 no.4
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• pp.83-89
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• 2015

Soil samples collected in an area of Gahak Mine were investigated for the characterization of mineralogical and physicochemical properties of contaminants in soils. It is found that soils in the study area are contaminated by lead (Pb), copper (Cu), zinc (Zn), cadmium (Cd), in which their concentrations are 595.3 mg/kg, 184.9 mg/kg, 712.8 mg/kg, and 10.64 mg/kg, respectively. All the concentrations exceed the concern criteria of Korean standard. Upon distribution patterns of metals identified by the sequential extraction procedure, our results show that more than 50% of metals are found as a residual type, and 30% are accounted for the association of Fe/Mn oxides. Interestingly, XRD results show that minium (Pb₃O₄) and cuprite (Cu₂O) are identified in the soil samples, suggesting that the sources of the contaminants for Pb and Cu are these minerals. In SEM images, tens of µm of Pb oxides and Pb silicate-minerals are observed. We, therefore, note that the contamination of metals in the study area results from the direct influx and disturbance of tailings. Our findings indicate that the characterization of physicochemical and mineralogical properties of contaminated soils is a critical factor and plays an important role in optimizing recovery treatments of soils contaminated in mine development areas.

• Korean Journal of Environmental Agriculture
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• v.33 no.4
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• pp.239-244
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• 2014

BACKGROUND: Heavy metals contamination of soils in the vicinity of abandoned mines in South Korea has been investigated. However, PAHs contamination rarely has been studied. Both heavy metals and PAHs concentrations have been measured in this study. METHODS AND RESULTS: The samples of soil and sediment were collected from the vicinities of three abandoned coal mines and two abandoned metal mines for analysis of heavy metals contaminants and PAHs concentration from April to September 2012. After preparation of these samples following the Korean standard test method for soils, the concentrations of heavy metals contaminants and PAHs were measured using ICP-OES and GC-MS, respectively. It was observed that the concentration of Arsenic was above the concern level based on 'area 1' suggested by Korean soil conservation law, resulting that Arsenic is the main contaminant in these areas. Also Cd, Cu, Pb and Zn were observed as a partial contaminants. The concentrations of other investigated components including benzo(a)pyrene were less than the concern level. CONCLUSION: The correlation observed between Arsenic (as main contaminant) and PAHs concentrations suggested that the contaminant source and pathway are different for each other. The effect of mine activity on PAHs concentration was rarely observed.

• Journal of Soil and Groundwater Environment
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• v.23 no.2
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• pp.30-39
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• 2018

Soil contamination survey was conducted during March - July, 2017 to obtain soil contamination profile of 16 organic and inorganic contaminants in Hanam industrial complex located in Gwangju, Korea. The concentrations of all surveyed contaminants except Cd showed were within 0.3~1.5 times of their natural background levels. Cd showed concentrations as high as 6.9 times of the background level, signifying the influence of the metal processing facilities in the complex. The concentrations of Zn, Pb and Hg in areas nearby industrial facilities were 1.3~5.5 times higher than those within the facility and green area. The concentration of Cu in the green area was 1.4~2.9 times higher than in other areas. The Soil Pollution Index (SPI) analysis revealed 54% of the total area belong to first-grade soil, 43% to second-grade, and 3% to third-grade. The Enrichment Factor (EF) of Zn, Pb, and Cd were 9.2, 15.6, and 88.5, respectively, indicating high accumulation and contamination of the soil with Cd.

• Journal of the Korean Geotechnical Society
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• v.15 no.6
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• pp.57-69
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• 1999

This study investigates the existing theoretical backgrounds for bearing capacity determination according to the plasticity of soils when unsymmetrical surcharge is loaded on polluted soft soils. It also investigates the behavior of the displacement and bearing capacity by unsymmetrical surcharge on the Polluted soft soils. by comparing the analytical results and the actual measurements performed through the model test. Model tests were carried out as follows : soil tank, bearing frame and bearing plate are made for the test ; the water content in soil tank was kept constant while the contaminants in natural soils and polluted material were gradually increased ; unsymmetrical surcharge is increased at regular intervals and then the amounts of settlement, lateral displacement and upheaval are observed. In conclusion, the value of critical surcharge was expressed as $q_{ cr}= 2.78_{Cu}$ which was similar to those $Tschebotarioff(q_{cr}=3.0_{Cu)$ and $Meyerhof(q_{cr}=(B/2H+\pi/2_{Cu})$ had proposed. The value of ultimate capacity was expressed as $q_{ult}=4.84_{Cu}$ which was similar to that of Prandtl.

• Journal of Environmental Health Sciences
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• v.18 no.2
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• pp.19-25
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• 1992

The study was carried out to investigate the correlation between the heavy metals emitted by the motor vehicles with the heavy traffic road side environment (soil, leave, bark, ambient air). The Pb, Cu, Zn contents in road side soil sand leaves, barks from Ginkgo, biloba and ambient air adjacent to the heavy traffic road side from June to August, 1992 Suwon city were analyzed by Atomic absorption spectrometry and Inductively coupled plasma emission spectrophotometry. The results were as follows: 1) The high levels of heavy metals concentration were Pb, at city-terminal in soil (186 $\mu$g/g), Cu, at city-terminal in soil (221 $\mu$g/g), Zn, at city-terminal in ambient air (252 $\mu$g/m$^{3}$). 2) The low leves of heavy metals concentration were Pb, at North-gate in ambient air (1.65$\mu$g/m$^{3}$), Cu, at North-gate in ambient air (4 $\mu$g/m$^{3}$), Zn, at North-gate in ambient air (15.31$\mu$g/m$^{3}$). 3) The regional distribution of Pb, Cu, Zn in road side soils, leaves and barks from Ginkgo, biloba, ambient air show high levels in turn, city4erminal, Guan Sean Dong, South gate, North gate. 4) The concentration of heavy metals (Pb, Cu, Zn) in soils, leaves, barks, ambient air was highly correlated with the traffic volume of the sampling sites (r=0.64~0.96). To conclude that the high levels of Pb, Cu, Zn contaminations were positively related to motor vehicles-borne pollutants and road side soils, trees, ambient air adjacent to a high density building area with low road coverage and heavy traffic volume were reflected strongly by the hazardous pollutants emitted by motor vehicles.