• 제목/요약/키워드: Cu Alloy

검색결과 1,269건 처리시간 0.03초

TFT-LCDs 게이트 전극에 적용한 Cu(Mg) 합금 박막의 건식식각 (A Dry-patterned Cu(Mg) Alloy Film as a Gate Electrode in a Thin Film Transistor Liquid Crystal Displays (TFT- LCDs))

  • 양희정;이재갑
    • 한국재료학회지
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    • 제14권1호
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    • pp.46-51
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    • 2004
  • The annealing of a Cu(4.5at.% Mg)/$SiO_2$/Si structure in ambient $O_2$, at 10 mTorr, and $300-500^{\circ}C$, allows for the outdiffusion of the Mg to the Cu surface, forming a thin MgO (15 nm) layer on the surface. The surface MgO layer was patterned, and successfully served as a hard mask, for the subsequent dry etching of the underlying Mg-depleted Cu films using an $O_2$ plasma and hexafluoroacetylacetone [H(hfac)] chemistry. The resultant MgO/Cu structure, with a taper slope of about $30^{\circ}C$ shows the feasibility of the dry etching of Cu(Mg) alloy films using a surface MgO mask scheme. A dry-etched Cu(4.5at.% Mg) gate a-Si:H TFT has a field effect mobility of 0.86 $\textrm{cm}^2$/Vs, a subthreshold swing of 1.08 V/dec, and a threshold voltage of 5.7 V. A novel process for the dry etching of Cu(Mg) alloy films, which eliminates the use of a hard mask, such as Ti, and results in a reduction in the process steps is reported for the first time in this work.

금속 생체재료를 위한 Sn 함량에 따른 Zr-7Cu 합금설계 (Zr-7Cu Alloy Design According to Sn Content for Bio-Metallic Materials)

  • 김민석;김정석
    • 한국재료학회지
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    • 제31권12호
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    • pp.690-696
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    • 2021
  • The purpose of this study is to develop a zirconium-based alloy with low modulus and magnetic susceptibility to prevent the stress-shielding effect and the generation of artifacts. Zr-7Cu-xSn (x = 1, 5, 10, 15 mass%) alloys are prepared by an arc melting process. Microstructure characterization is performed by microscopy and X-ray diffraction. Mechanical properties are evaluated using micro Vickers hardness and compression test. The magnetic susceptibility is evaluated using a SQUID-VSM. The average magnetic susceptibility value of the Zr-7Cu-xSn alloy is 1.176 × 10-8 cm3g-1. Corrosion tests of zirconium-based alloys are conducted through polarization test. The average Icorr value of the Zr-7Cu-xSn alloy is 0.1912 ㎂/cm2. The elastic modulus value of 14 ~ 18 GPa of the zirconium-based alloy is very similar to the elastic modulus value of 15 ~ 30 GPa of the human bone. Consequently, the Sn added zirconium alloy, Zr-7Cu-xSn, is very interesting and attractive as a biomaterial that reduces the stress-shielding effect caused by differences of elastic modulus between human bone and metallic implants. In addition, this material has the potential to be used in metallic dental implants to effectively eliminate artifacts in MRI images due to low magnetic susceptibility.

아말감과 이종(異種)금속의 거리에 따른 부식에 대한 고찰 (A Study on Corrosion according to Distance between Amalgam and Dissimilar Metals)

  • 김주원;정은경
    • 치위생과학회지
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    • 제4권3호
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    • pp.103-109
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    • 2004
  • 본 실험은 제조회사 매뉴얼과 통법에 의해서 Amalgam 합금, Ni-Cr alloy의 Crown용 Verabond, Denture용 Talladium $^{TM}alloy$로 각각 24개의 총 72의 시편을 하악 제1대구치근 원심 치관 폭경과 임상에서의 MOD cavity를 고려하여 제작하였고 인공 타액 80ml를 담은 200ml 용 비이커에 시편을 넣어 0mm, 7mm, 40mm 거리에서 7일 후 갈바닉 부식을 측정하였다. 유리금속은 유도 플라즈마 방출 분광기(Inductively Coupled Plasma - Atomic Emission Spectrometer(ICP-AES, JY-50P, VG Elemental Co. France)로 전해액내의 Cu, Ag, Ni, Cr, Sn, Zn, Hg를 정량 분석했으며 그 결과 다음과 같은 결론을 얻었다. 첫째, Cu, Sn, Ag, Hg, Zn은 아말감이 금 합금과 접촉했을 때가 크라운용 Ni-Cr alloy와 덴쳐용 Talladium alloy 보다 아주 많이 유리 했으며 금 합금이 구강조직과 생체 적합성이 가장 좋다지만 아말감과 함께 있을 때 가장 불리 했슴을 알 수 있었다. 둘째, 아말감이 금 합금과 접촉했을 때, 금 합금의 조성에서 Ni, Cr 같은 중금속이 함유되지 않았기 때문인지 전혀 유리되지 않았으나 Sn은 조성에는 없었지만 $227.1{\pm}18.0035{\mu}g/cm^2$나 유리 되었고 Hg도 유리되었는데 이는 아말감 자체의 유리 물질임을 추측할 수 있었다. 셋째, 아말감 합금과 금 합금 사이에서의 0mm, 7mm, 40mm 거리에서는 Cu, Ag는 유의성이 있었으며 Hg는 유의성이 없었다. 이는 금합금은 절대 아말감과 같이 사용해서 안되며 이종 보철물 사이의 거리에 관계없이 사용을 금해야 하는 것으로 사료된다. 넷째, 아말감합금이 Crown용 Ni-Cr 합금과 접촉했을 때 아말감의 Ag이 유리 되지 않았으며 Zn, Ni, Sn, Hg, Cu의 순으로 유리되었다. 0mm, 7mm, 40mm 거리에 따라서 유의성이 있었다. Hg는 유리 되지 않았지만 중금속인 Ni, Cr은 유리되었고 반대 악궁이나 거리가 떨어져 있으면 접촉보다 Hg의 유리가 적었다. 다섯째, 아말감합금이 Denture용 Talladium alloy 합금과 접촉했을 때 0mm, 7mm, 40mm 거리에서도 유의성이 있었다. 0mm, 7mm, 40mm 거리에 따라서 유의성이 있었다. Hg는 유리 되지 않았지만 중금속인 Ni, Cr은 유리되었고 반대 악궁이나 거리가 떨어져 있으면 접촉보다 Hg의 유리가 적었다. 여섯째, 인공 타액에서 접촉 시 Amalgam alloy와 Gold, Verabond, Talladium alloy의 Cu, Sn, Ag, Hg, Zn, Ni, Cr의 ICPES 검사 결과 Cu, Hg가 유의성을 있었다. 일곱째, 인공타액에서 아말감합금과 두 비귀금속인 Ni-Cr alloy(crown용), Denture용 Talladium alloy가 접촉한 경우 거리에 따른 Hg, Ni, Cr의 유리 부산물에서 유의성을 확인했다.

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엔진 마운트 브라켓용 다이캐스팅 Al-Si-Cu 합금의 미세조직과 기계적 특성 (Microstructural and Mechanical Characteristics of Al-Si-Cu Die Casting Alloy for Engine Mount Bracket)

  • 천인범;홍승표;김정석
    • 열처리공학회지
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    • 제27권6호
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    • pp.281-287
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    • 2014
  • Microstructural and mechanical characteristics of Al-6Si-2Cu alloy for engine mount bracket prepared by gravity casting (as-cast) and die-casting (as-diecast) process have been investigated. For the microstructural characterization, the inductively coupled plasma mass spectrometry (ICP-MS), optical microscope (OM), scanning electron microscope (SEM) and electron probe microanalysis (EPMA) analyses are conducted. For the intermetallic phases, the X-ray diffraction (XRD) and energy dispersive spectroscopy (EDS) are also conducted with quantitative and qualitative analysis. Micro Vickers hardness and static tensile test are achieved in order to measure mechanical properties of alloys. Secondary dendrite arm spacing (SDAS) of as-cast and as-diecast show 37um and 18um, respectively. A large amount of coarsen eutectic Si, $Al_2Cu$ intermetallic phase and Fe-rich phases are identified in the Al-6Si-2Cu alloy. Mechanical properties of gravity casting alloy are much higher than those of die-casting alloy. Especially, yield strength and elongation of gravity casting alloy show 2 times higher than die-casting alloy. After shot peening, shot peening refined the surface grains and Si particles of the alloys by plastic deformation. The surface hardness value shows that shot peening alloy has higher value than unpeening alloy.

Ni기 비정질 벌크합금의 제조와 기계적 성질 (Fabrication and Mechanical Properties of Ni-based Amorphous Bulk Alloys)

  • 김성규
    • 한국주조공학회지
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    • 제22권6호
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    • pp.288-292
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    • 2002
  • Ni-base amorphous alloys were manufactured using melt-spinning and Cu-mold die casting methods. Amorphous formability, the supercooled liquid region before crystallization and mechanical properties were examined. The reduced glass transition temperature and the supercooled liquid region of $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$alloy were 0.621 and 46 K respectively. $Ni_{51} Nb_{20} Zr_9 Ti_9 Co_8 Cu_3$ alloy was produced in the rod shape 3mm diameter using the Cu-mold die casting. Hardness, compression strength, elongation and elastic modulus of the alloy were 850 DPN, 2.75 GPa, 1.8% and 150 GPa respectively. Moreover, compression strength of 2.75 GPa was the highest value in the amorphous bulk alloy produced up to now.

저온 주조법을 응용한 Al-Zn-Mg-Cu 합금의 반응고 성형 (Semi-Solid Forming of Al-Zn-Mg-Cu Alloy Applying Low-Temperature Casting Process)

  • 김정민;김기태;정운재
    • 한국주조공학회지
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    • 제22권2호
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    • pp.82-88
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    • 2002
  • Al-5.5Zn-2.5Mg-l.5Cu semi-solid slurry was prepared by cooling the liquid metal with a low superheat to a solid and liquid co-existing temperature. Relatively round solid particles could be obtained in the slurry through the simple process. The prepared slurry was deformed into the metallic mold by a press and the mechanical properties of obtained specimens were investigated. Mold filling ability of the alloy slurry was also investigated and compared with that of A356 alloy. Al-Zn-Mg-Cu alloy showed lower mold filling ability than A356 alloy probably because small amount of eutectic phase is present and the heat of fusion generated during solidification is smaller than that of A356 alloy.

분무성형 및 반응분무성형법으로 제조된 분산강화 동합금의 항복강도에 미치는 분산상의 영향 (The Effect of Dispersoid on Yield Strength of Dispersion Strengthened Cu Alloys Fabricated by Spray Forming and Reactive Spray Forming)

  • 이종상;정재영;이언식;박우진;안상호;김낙준
    • 한국소성가공학회:학술대회논문집
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    • 한국소성가공학회 1999년도 압출 및 인발 심포지엄
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    • pp.38-46
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    • 1999
  • Dispersion strengthened Cu alloys have been manufactured by spray forming and also by reactive spray forming, followed by hot extrusion of the spray deposited billets. The size of dispersed particles in the reactive spray formed alloy was much finer than that in the spray formed alloy. That was because the dominant chemical reaction between Ti and B had occurred in Cu-Ti-B alloy melt in spray forming while it had occurred after deposition of droplets in reactive spray forming. The yield strength of the reactive spray formed alloy was greater than that of the spray formed alloy. To understand the mechanism responsible for this observed strengthening, the yield strength of two Cu alloys were analyzed using the dislocation pile-up model and Orowan mechanism, which were fairly consistent with the experimental results. Increase in yield strength of reactive spray formed alloy relative to spray formed alloy was largely attributed to nano-scale TiB dispersoids.

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Cu50-Fe50 합금의 제조 및 특성평가 (Fabrication and characterization of Cu50-Fe50 alloy)

  • 이정일;딜리람;팽종민;조현수;양수민;류정호
    • 한국결정성장학회지
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    • 제28권4호
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    • pp.175-178
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    • 2018
  • 구리 금속은 높은 열전도도로 heat sink 혹은 heat exchanger로 널리 사용되고 있다. 그러나 이에 반하여 낮은 인장강도와 사용온도 한계를 가지고 있다. 따라서 높은 열전도도, 낮은 제작비와 함께 우수한 기계적 특성이 요구된다. 본 연구에서는 이를 위하여 동철합금($Cu_{50}-Fe_{50}$ alloy)를 고주파 가열로를 이용하여 제조하고 그 특성을 조사하였다. 제조된 동철합금은 Cu, ${\alpha}$-Fe, ${\gamma}$-Fe 결정구조를 기진 dendrite 미세구조를 보여주었다. 제조된 동철합금은 XRD, FE-SEM, EDS 및 XRF를 이용하여 결정구조 및 미세구조를 분석하였으며 전력공급 접점용 소재로서의 적합성을 확인하고자 하였다.

Cu-1.6Co-0.38Si 합금의 열처리에 따른 경도 및 전기전도도의 변화 (Hardness and Electrical Conductivity Changes according to Heat Treatment of Cu-1.6Co-0.38Si Alloy)

  • 곽원신;이시담
    • 열처리공학회지
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    • 제33권5호
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    • pp.226-231
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    • 2020
  • The Cu-Co-Si alloy shows high strength by forming precipitates by aging precipitation heat treatment of supersaturated solid solution treated with solution treatment such as Cu-Ni-Si alloy, and the Co2Si precipitated phase is dispersed in the copper matrix. The effect of aging treatment on the microstructure, mechanical and electrical properties of Cu-Co-Si alloys for electronic devices was investigated. As a results of SEM/EDS analysis, it was found that Co2Si precipitates of 30~300 nm size were distributed in grains. By performing the double aging treatment, it was possible to improve the strength and electrical conductivity by dispersing the fine precipitate evenly.

Cu-5% Sn합금(合金)의 주조조직(鑄造組織)에 미치는 도형재(塗型材)의 영향(影響)에 관(關)한 연구(硏究) (Effect of Mold Coatings on the Macrostructures of Cu-5%Sn Alloy)

  • 최영승;최창옥
    • 한국주조공학회지
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    • 제5권3호
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    • pp.19-26
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    • 1985
  • This study has been carried out to examine into wettability of Cu-5%Sn alloy in $Al_2O_3$, MgO, $SiO_2$ and graphite, respectively and investigated into the change in macrostructure of Cu-5%Sn alloy according to kind and mixing rate of mold-coating. The results obtained from the experiment are summerized as follows; 1. Cu Cu-5%Sn alloy, wettabilities of $Al_2O_3$ and MgO were good, on the other hand, wettabilities of $SiO_2$ and graphite were bad. 2. The fine equiaxed zone was created because of the role of $Al_2O_3$ and MgO as preferential nucleation sites. 3. Notwithstanding change of mixing rate of $SiO_2$ in mold coating the equixed zone was not created. 4. The area of equiaxed zone was varied according to mixing rate in the case of using $Al_2O_3$ and MgO in mold-coating.

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