• 한국세라믹학회지
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• 제26권3호
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• pp.305-314
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• 1989

Effect of pH variation in starting solution for the making of hydroxyapatite powder was studied in relation to the sinterability of the powder and their mechanical properties of the sintered hydroxyapatite ceramics. The sinterability of hydroxyapatite powder prepared at different pH was found to be improved with increase in pH value of the starting solutions. Thus the powders prepared from the higher pH solutions including 10.5, 11.0 and 11.5 could be well densified almost upto theoretical density by firing for 1 hr at 1,00$0^{\circ}C$. But the powder based on pH 10 exhibited less sinterability even being fired at much higher temperature of 1,10$0^{\circ}C$, it gave only 90-95% of theoretical density. On the other hand the powder prepared on the lowest pH value 9.5 could not be well densified and it could obtain only 78% of theoretical density even by firing at 1,30$0^{\circ}C$ for 1hr. It was found that prismatic crystals of whitlockite were always included in the sintered bodies based on the lower pH values as a minority crystalline phase together with the major crystalline phase of hydroxyapatite and its inclusion might impair the sinterability of powder. However in the case of the higher pH, the powder contained only hydroxyapatite as a crystalline phase on sintering without any minorities. The sphere shape of crystals might help effectively the densification of the bodies. The best mechanical properties could be obtained from the body of pH 11 sintered at 1,10$0^{\circ}C$, which gave 99.5% of theoretical density, 662Kg/$\textrm{mm}^2$ of vickers hardness and 1,352Kg/$\textrm{cm}^2$ of diameteral compression strength.

• 한국식품과학회지
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• 제51권5호
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• pp.432-437
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• 2019

본 연구에서는 국내에서 육종된 쌀품종의 전분에 대한 분자 및 결정구조을 밝히고 이와 같은 결과들이 상전이 특성에 미치는 영향을 조사하였다. 새미면 전분은 아밀로스 함량이 가장 높았으며, 다른 쌀전분에 비해 상대적으로 아밀로펙틴의 짧은 사슬(DP 6-12)과 평균사슬길이, 치반점도와 최종점도, 호화온도와 엔탈피, 2차 상전이인 ${T_g}^{\prime}$이 유의적으로 높았으며, 반대로 최고점도와 강하점도, ice melting 온도와 엔탈피가 유의적으로 낮았다. 아밀로스 함량이 가장 낮은 선향흑미는 다른 전분에 비해 유의적으로 높은 ice melting 엔탈피를 나타냈고 ${T_g}^{\prime}$이 높았다. 결과적으로 쌀 전분의 상전이 특성은 분자 및 결정 구조에 큰 영향을 받는 것을 확인할 수 있었다.

• 한국재료학회지
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• 제12권11호
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• pp.880-882
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• 2002

We have prepared magnetic thin films of FeSiB by sputtering and examined microstructure and magnetic properties of the annealed films in order to investigate the feasibility of the films to microsensor application. Effects of vacuum annealing on the magnetic properties of $Fe_{84}$$Si_{6}$$B_{10}$ films have been examined as a function of temperature. The heating rate and the holding time were 10 K/min and 1 hour, respectively. Vacuum condition was held during cooling to prevent oxidation of the films. The coercivity did not show any noticeable change (~1500 A/m), although the grain size of the crystalline phase in the annealed films increased gradually up to about 16 nm until 673 K. However, both the grain size and the coercivity increased steeply when the annealing temperature increased over 723 K. Since the saturation magnetization is closely related to the phase evolution, the variation of the saturation magnetization of the annealed films was similar to that of the ribbon materials; the thin films were transformed from amorphous to crystalline with $\alpha$-(Fe,Si) phase by increasing annealing temperature.

• 한국전기전자재료학회논문지
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• 제24권12호
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• pp.982-987
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• 2011

In this study, $Ge_8Se_{(2+x)}Te_{(6-x)}$ thin film amorphous-to-crystalline phase-change rate was evaluated in using a nano-pulse scanner. The focused laser beam with a diameter <10 ${\mu}m$ was illuminated in the power (P) and pulse duration (t) ranges of 1-31 mW and 10-460 ns, respectively, with subsequent detection of the responsive signals reflected from the film surface. We also evaluated the material characteristics, such as optical absorption and energy gap, crystalline phases, and sheet resistance of as-deposited and annealed films. The result of experiments showed that the thermal stability of the Ge-Se-Te film is largely improved by adding Se.

• Applied Microscopy
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• 제26권2호
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• pp.235-241
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• 1996

Amophization and decomposition behaviour in $Mg_{62}Cu_{26}Y_{12}$ alloy prepared by melt spinning method and wedge type metal mold casting method have been investigated by a detailed transmission electron microscopy. Amorphous phase has formed in melt-spun ribbon. In the case of the wedge type specimen, however, the amorphous phase has formed only around the tip area within about 2 mm thickness. The remaining part of the wedge type specimen consists of crystalline phases, $Mg_{2}Cu\;and\;Cu_{2}Y$. The supercooling for crystallization behaviour of the amorphous $Mg_{62}Cu_{26}Y_{12}$ alloy, ${\Delta}T_x$ has been measured to be about 60 K. Such a large undercooling of the crystallization bahaviour enables formation of the amorphous phase in the $Mg_{62}Cu_{26}Y_{12}$ alloy under the cooling rate of $10^{2}K/s$. The amorphous $Mg_{62}Cu_{26}Y_{12}$ has decomposed into crystalline phases, $Mg_{2}Cu\;and\;Cu_{2}Y$ after heat treatment at $170^{\circ}C\;and\;250^{\circ}C$.

• Metals and materials international
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• 제24권6호
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• pp.1285-1292
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• 2018

Microstructural properties of as-grown and annealed CoCrFeMnNi high entropy alloy (HEA) oxynitride thin films were investigated. The CoCrFeMnNi HEA oxynitride thin film was grown by magnetron sputtering method using an air gas, and annealed under the argon plus air flow for 5 h at $800^{\circ}C$. The as-grown film was homogeneous and uniform composed of nanometer-sized crystalline regions mixed with amorphous-like phase. The crystalline phase in the as-grown film was face centered cubic structure with the lattice constant of 0.4242 nm. Significant microstructural changes were observed after the annealing process. First, it was fully recrystallized and grain growth happened. Second, Ni-rich region was observed in nanometer-scale range. Third, phase change happened and it was determined to be $Fe_3O_4$ spinel structure with the lattice constant of 0.8326 nm. Hardness and Young's modulus of the as-grown film were 4.1 and 150.5 GPa, while those were 9.4 and 156.4 GPa for the annealed film, respectively.

• Elastomers and Composites
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• 제54권1호
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• pp.14-21
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• 2019

Main-chain/side-chain liquid crystalline polymers (MCSCLCPs) combined with an azobenzene group and a cholesteryl group were synthesized to impart light and temperature sensitivity to the polymer. The polymers were designed with the azobenzene unit as the mesogenic group of the main-chain and various compositions of the azobenzene and cholesteryl units as the mesogenic group of the side-chain. The chemical structures and physical properties of the synthesized polymers were investigated by Fourier transform infrared spectroscopy, proton nuclear magnetic resonance spectroscopy, differential scanning calorimetry, thermogravimetric analysis, polarized optical microscopy, and ultraviolet-visible (UV-Vis) spectroscopy. All the MCSCLCPs were amorphous and exhibited enantiotropic liquid crystal phases; these polymers achieved the nematic phase with increasing content of the azobenzene group and exhibited the cholesteric phase with weak liquid crystallinity as the content of the cholesteryl group was increased. Furthermore, the polymers containing the azobenzene group showed photoisomerization when exposed to UV-Vis light, and the CP-A3C7 and CP-A5C5 polymers exhibited thermochromism in the temperature range of the liquid crystal phase.

• Macromolecular Research
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• 제17권5호
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• pp.313-318
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• 2009

The side chain liquid crystal triblock copolymers (TBCs), which underwent phase transitions below their decomposition temperature, were prepared by copolymerization of poly(n-butyl acrylate) and a comonomer containing the mesogenic azobenzene group. The physical properties of TBCs in the distinctive transition temperature ranges were investigated in terms of the liquid crystal (LC) content in the copolymers. The phase transition temperatures traced optically, thermally and rheologically were well coincided one another and clearly exhibited the phase transition of smectic-nematic-isotropic with increasing temperature. In the smectic phase, increasing temperature made the liquid crystal system more elastic, but viscosity (${\eta}'$) remained almost constant. In the nematic phase, increasing temperature abruptly decreased ${\eta}'$ and G', ultimately leading to isotropic phase. Both smectic and nematic phases exhibited Bingham viscosity behavior but the former gave much greater yield stress at the same LC content.

• 문화기술의 융합
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• 제9권3호
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• pp.587-592
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• 2023

CoCl₂·6H₂O 수용액을 결정성셀룰로오스에 함침시켜 건조한 후, 하소, 소성을 통하여 산화코발트(Co₃O₄·CoO) 초미세입자를 합성하였다. 합성된 코발트 산화물 입자의 결정구조 및 표면구조를 주사전자현미경(SEM)과 X-선회절분석(XRD)으로 조사하였다. CoCl₂·6H₂O 수용액을 함침시키는 매개체로 사용한 결정성셀룰로오스(crystalline cellulose)는 470℃ 정도에서 열분해 되었고, Co₃O₄ 결정상은 350℃에서 생성되기 시작하였다. Co₃O₄ 결정상은 500℃까지 유지되었으며, 500℃ 이상의 온도에서는 CoO 결정상으로 변화하는 것을 알 수 있었다. 열처리 온도가 증가함에 따라 산화코발트 입자의 크기가 커지는 현상이 나타났으며, 900℃ 이상의 온도에서는 입자간 용융이 일어나는 것이 관찰되었다. 하소온도 700℃ 이하의 온도에서 입자크기 2-10㎛의 Co₃O₄와 CoO의 초미세입자가 생성되는 것을 확인하였다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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• pp.139.2-139.2
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• 2016

Electrons and phonons in chalcogenide-based materials play are important factors in the performance of an optical data storage media and thermoelectric devices. However, the fundamental kinetics of carriers in chalcogenide materials remains controversial, and active debate continues over the mechanism responsible for carrier relaxation. In this study, we investigated ultrafast carrier dynamics in an multilayered $\{Sb(3{\AA})/Te(9{\AA})\}n$ thin film during the transition from the amorphous to the crystalline phase using optical pump terahertz probe spectroscopy (OPTP), which permits the relationship between structural phase transition and optical property transitions to be examined. Using THz-TDS, we demonstrated that optical conductance and carrier concentration change as a function of annealing temperature with a contact-free optical technique. Moreover, we observed that the topological surface state (TSS) affects the degree of enhancement of carrier lifetime, which is closely related to the degree of spin-orbit coupling (SOC). The combination of an optical technique and a proposed carrier relaxation mechanism provides a powerful tool for monitoring TSS and SOC. Consequently, the response of the amorphous phase is dominated by an electron-phonon coupling effect, while that of the crystalline structure is controlled by a Dirac surface state and SOC effects. These results are important for understanding the fundamental physics of phase change materials and for optimizing and designing materials with better performance in optoelectronic devices.