• 제목/요약/키워드: Crystal field

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액정 매질내의 풀러린 입자의 Dielectrophoretic force를 이용한 전자종이 디스플레이의 연구 (Research on electricnic paper-like displays using dielectrophoretic force of fullerene particles immersed in liquid crystal medium)

  • 김미경;김미영;김성민;;이명훈;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2009년도 춘계학술대회 논문집
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    • pp.57-58
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    • 2009
  • The dynamics of nano or micro sized-particles in liquid crystal (LC) medium under an external electric field is of theoretical and technological interest. A fullerene of 10 wt% was doped into the LC medium and its electric field induced motion was controlled by both in-plane and vertical electric fields. In the proposed device, pixel electrode I and pixel electrode II were designed consecutively on the bottom substrate and common electrode on the top of the substrate. When the electric field was applied, the fullerenes start to move in direction of applied electric field. The dark, grey and white states in the proposed device can be obtained by suitable combination of the polarity of applied electric field at pixel electrode I, pixel electrode II and common electrode. The dynamical motions of fullerene particles in LC medium suggest that fullerene can be designed for electronic-paper like displays.

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Reactive sputtering법에 의한 PZT 박막 증착후 냉각시 산소분압의 영향에 관한 연구 (Effects of changing the oxygen partial pressure in cooling after deposition of PZT thin films by reactive sputtering)

  • 이희수;오근호
    • 한국결정성장학회지
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    • 제6권3호
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    • pp.406-414
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    • 1996
  • 본 연구에서는 금속타겟을 이용한 반응성 스퍼터링법을 이용하여 PZT 박막 증착후 냉각시 산소분압에 따른 박막의 상형성 거동 및 전기적 특성에 미치는 영향을 고찰하였다. 냉각시 산소분압의 감소에 따라 박막 표면의 휘발에 기인하여 표면거칠기는 증가하였고 입성장은 거의 일어나지 않았다. 산소분압이 증가할수록 각형비가 보다 우수한 hysteresis 특성을 얻을 수 있었고 산소분압이 감소함에 따라 remanent polarization과 retained polarization이 감소하였으며, 항전계의 감소가 관찰되었다. 산소분압에 따른 유전율-전압 특성 측정에서 산소분입이 감소함에 따라 internal bias field의 증가가 관찰되었으며, 유전율도 조금씩 감소하였다. Field accelerated retention 시험결과 냉각시 산소분압이 감소함에 따라 nonswitched polarization의 증가가 관찰되었고 bias time이 증가함에 따라 nonswitched polarization이 감소하였다.

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Hot Wall Epitaxy(HWE)법에 의한 CuAlSe2 단결정 박막의 성장과 가전자대 갈라짐에 대한 광전류 연구 (Photocurrent Study on the Splitting of the Valence Band and Growth of CuAlSe2 Single Crystal Thin Film by Hot Wall Epitaxy)

  • 박창선;홍광준;박진성;이봉주;정준우;방진주;김현
    • 센서학회지
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    • 제13권2호
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    • pp.157-167
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    • 2004
  • A stoichiometric mixture of evaporating materials for $CuAlSe_{2}$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $CuAlSe_{2}$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $680^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $CuAlSe_{2}$ single crystal thin films measured with Hall effect by van der Pauw method are $9.24{\times}10^{16}cm^{-3}$ and $295cm^{2}/V{\codt}s$ at 293 K, respectively. The temperature dependence of the energy band gap of the $CuAlSe_{2}$ obtained from the absorption spectra was well described by the Varshni's relation, $E_{g}(T)$ = 2.8382 eV - ($8.68{\circ}10^{-4}$ eV/K)$T^{2}$/(T + 155 K). The crystal field and the spin-orbit splitting energies for the valence band of the $CuAlSe_{2}$ have been estimated to be 0.2026 eV and 0.2165 eV at 10 K, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_{5}$ states of the valence band of the $CuAlSe_{2}$. The three photocurrent peaks observed at 10 K are ascribed to the $A_{1-}$, $B_{1-}$, and $C_{1-}$ exciton peaks for n = 1.

Hot Wall Epitaxy(HWE)법에 의한 BaAl2Se4 단결정 박막 성장과 광전도 특성 (Growth and Optical Conductivity Properties for BaAl2Se4 Single Crystal Thin Film by Hot Wall Epitaxy)

  • 정준우;이기정;홍광준
    • 센서학회지
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    • 제24권6호
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    • pp.404-411
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    • 2015
  • A stoichiometric mixture of evaporating materials for $BaAl_2Se_4$ single crystal thin films was prepared from horizontal electric furnace. To obtain the single crystal thin films, $BaAl_2Se_4$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $410^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $BaAl_2Se_4$ single crystal thin films measured from Hall effect by van der Pauw method are $8.29{\times}10^{-16}cm^{-3}$ and $278cm^2/vs$ at 293 K, respectively. The temperature dependence of the energy band gap of the $BaAl_2Se_4$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)=3.4205eV-(4.3112{\times}10^{-4}eV/K)T^2/(T+232 K)$. The crystal field and the spin-orbit splitting energies for the valence band of the $BaAl_2Se_4$ have been estimated to be 249.4 meV and 263.4 meV, respectively, by means of the photocurrent spectra and the Hopfield quasicubic model. These results indicate that the splitting of the ${\Delta}so$ definitely exists in the ${\Gamma}_5$ states of the valence band of the $BaAl_2Se_4/GaAs$ epilayer. The three photocurrent peaks observed at 10 K are ascribed to the $A_1$-, $B_1$-exciton for n =1 and $C_{31}$-exciton peaks for n=31.

$CuInSe_2$ 단결정 박막 성장과 광전류 특성 (Properties of Photocurrent and Growth of $CuInSe_2$ single crystal thin film)

  • S.H. You;K.J. Hong
    • 한국재료학회:학술대회논문집
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    • 한국재료학회 2003년도 춘계학술발표강연 및 논문개요집
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    • pp.83-83
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    • 2003
  • The stochiometric mix of evaporating materials for the CuInSe$_2$ single crystal thin films was prepared from horizontal furnace. To obtain the single crystal thin films, CuInSe$_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the Hot Wall Epitaxy (HWE) system. The source and substrate temperature were 62$0^{\circ}C$ and 41$0^{\circ}C$, respectively. The crystalline structure of single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of CuInSe$_2$ single crystal thin films measured from Hall effect by van der Pauw method are 9.62$\times$10$^{16}$ cm$^{-3}$ , 296 $\textrm{cm}^2$/V.s at 293 K, respectively From the photocurrent spectrum by illumination of perpendicular light on the c-axis of the CuInSe$_2$ single crystal thin film, we have found that the values of spin orbit splitting ΔSo and the crystal field splitting ΔCr were 6.1 meV and 175.2 meV at 10 K, respectively. From the photoluminescence measurement on CuInSe$_2$ single crystal thin film, we observed free excition (Ex) existing only high quality crystal and neutral bound exiciton (D$^{\circ}$,X) having very strong peak intensity. Then, the full-width-at -half-maximum(FWHM) and binding energy of neutral donor bound excition were 7 meV and 5.9 meV, respectivity. By Haynes rule, an activation energy of impurity was 59 meV.

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Computer Interface를 이용한 핵 사중극 공명 Gaussmeter의 제작 (Construction of the NQR Gaussmeter using Computer Interface)

  • 김혜진;신종필;조성호;김창석
    • 한국자기학회지
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    • 제5권2호
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    • pp.99-102
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    • 1995
  • 전기장 기울기 텐서가 축대칭인 결정에 대칭인 방향으로 자기장을 가하면 핵사중극공명에 미치는 Zeeman 효과에 의하여 두 개의 분리된 공명진동수가 측정된다. 이 때 가해준 자기장과 두 공명진동수 간의 차이는 서로 비례하며, ${(CH_{2})}_{6}N_{4}$ 단결정의 $^{14}N$ 원자핵에 대한 비례상수는 0.16 mT/kHz 이다. 핵 사중극 공명장치 와 개인용 컴퓨터를 interface 하여 핵 사중극 공명신호의 모습을 모니터에 표시하여 측정되는 두 공명신호의 진동수 차이로 자기장을 직접 읽을 수 있도록 하였다. 여기로부터 핵 사중극 공명 Gaussmeter를 이용하여 실험적으로 측정한 최저 자기장은 0.20 mT 였다.

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유전율 이방성이 양인 액정을 이용한 Fringe-Field Driven 수평 배향셀의 위상지연값 연구 (Study on Retardation Value of Fringe-Field Driven Homogeneously Aligned Nematic Liquid Crystal Cell using Liquid Crystals with Positive Dielectric Anisotropy)

  • 정송희;김향율;송성훈;이승희
    • 한국전기전자재료학회논문지
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    • 제17권3호
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    • pp.305-310
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    • 2004
  • We have studied the optimal phase retardation value of a homogeneously aligned liquid crystal (LC) driven by fringe-field when using the LC with positive dielectric anisotropy. In general, the transmittance of a homogeneous aligned LC cell under crossed polarizer is maximum when a twist angle of LC by in-plane rotation is 45$^{\circ}$ with polarizer and the cell retardation becomes λ/2. However, the device using the LC with positive dielectric anisotropy does not follow this since the degree of rotation of the LC is dependent on electrode position and in addition the LCs tilt up along the fringe-field. At the center of common and pixel electrode, the LC is most twisted around a middle position of a cell whereas at the edge position of pixel electrode, the LC is most twisted near bottom surface of a cell. Consequently, the optimal phase retardation of the device becomes much larger than λ/2 and the transmittance can be described using the combination of the in-plane switching and twisted nematic mode.

유전율 이방성이 음인 액정을 이용한 fringe-field driven Twisted Nematic 모드의 전기광학 특성 (Electrode-Optic Characteristics of Fringe-field driven Twisted Nematic Mode using a Liquid Crystal with Negative Dielectric Anisotropy)

  • 송일섭;신성식;송성훈;김향율;이종문;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1054-1057
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    • 2003
  • We have studied $90^{\circ}$ twisted nematic (TN) mode driven by fringe electric field, where two polarizers are parallel each other such that the cell shows a black state before a voltage is applied. According to the studies by computer simulation for a LC with negative dielectric anisotropy, the LC twists perpendicular to the horizontal field direction of fringe electric field and the degree of tilt angle is very low, when a voltage is applied. Therefore, the new device exhibits wide viewing angle characteristic due to in-plane switching and high transmittance since the LC director aligns parallel to the polarizer axis.

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3차원 유한요소법을 이용한 TFT-LCD 액정에서의 공간 전기장 분포 특성 분석 (Characteristic Analysis of Spacial Electric Field Distribution in Liquid Crystal of TFT-LCD Panel)

  • 정상식;김남경;김동훈;노민호;이규상
    • 한국자기학회지
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    • 제22권3호
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    • pp.91-96
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    • 2012
  • 복잡한 전극 구조를 갖는 TFT-LCD 패널의 픽셀 사이의 간섭효과를 고려하여 액정에서의 공간 전기장 분포를 정밀하게 예측할 수 있는 멀티 픽셀 기반의 3차원 유한요소 수치해석 모델을 구축하였다. 이를 토대로 패널 내 다양한 전극 불량 조건에 대한 액정에서의 공간 전기장 분포 특성을 정상 상태와 비교 분석 하였다. 이러한 수치모사 결과와 기존 광학적 패널 검사장비의 불량검출 결과를 간접 비교함으로써 제안한 3차원 유한요소 수치모델의 타당성을 검증하였다.

유전율 이방성이 양인 액정을 사용한 FFS 모드에서의 스플레이 탄성상수에 따른 투과율 연구 (The effect of splay elastic constant on the transmittance of fringe-field switching using a liquid crystal with positive dielectric anisotropy)

  • 김태현;이지연;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.518-519
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    • 2005
  • We have studied the transmittance of fringe-filed switching(FFS) using a liquid crystal with positive dielectric anisotropy. Generally, FFS having positive dielectric anisotropy has less transmittance than FFS using negative dielectric anisotropy. FFS mode transmittance depends on horizontal director deformation, however fringe filed is composed of vertical and horizontal field. Vertical field in the middle of electrode suppresses the transmittance of FFS mode, especially when we use positive one. So, it is important to prevent the LC director from the effect of vertical field. We changed the splay elastic constant and checked the transmittance. The transmittance of FFS having positive dielectric anisotropy was improved. Less tilted LC directors improve the transmittance of FFS using positive dielectric anisotropy. We can improve the transmittance by using LC which have high splay elastic constant when another LC properties are equal.

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