• Economic and Environmental Geology
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• v.31 no.6
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• pp.473-483
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• 1998

The igneous rocks in the Goseong area are composed of the volcanic rocks (andesitic lapilli tuff and rhyodacite), Bulgugsa granites (Hornblende-biotite granite and two pyroxene granite) and intrusive andesites. In the variation diagrams of the trace and rare earth element contents and elemental ratios as well as the REE patterns, the three igneous rock types show different variational trends and patterns. The geochemical features represent that the igneous rocks in the area were formed from three different magmatic pulses. Two independently carried out Rb-Sr isotope experiments for the Goseong granites show that the whole rock ages and Sr initial ratios of the granites are $66.4{\pm}6.2Ma$, $0.70517{\pm}22(2{\sigma})$ and $71.3{\pm}6.8Ma$, $0.70506{\pm}18(2{\sigma})$, respectively. These results suggest that the granites magma originated from the lower crustal materials of igneous origin intruded into the area during the late Cretaceous period. Masan hornblende-biotite granite emplaced at the vicinity of the Goseong area is very similar to the Goseong granite in its mineral compositions, major, trace and rare earth element contents and patterns. The intruding age (100 Ma) of the Masan granite is order than that of the Geseong granite, however. The similarity of the geochemical natures but the contrast of the intruding ages between the Masan and Goseong granites possibly indicate that the magma generation from the same source materials occurred at a temporal interval of ca. 30 Ma.

• Economic and Environmental Geology
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• v.33 no.1
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• pp.61-75
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• 2000

Through modeling fault network using thin plate finite element technique in the San Andreas Fault system with slip rate over 1mm/year, as well as elevation, heat flow, earthquakes, geodetic data and crustal thickness, we compare the results with velocity boundary conditions of plate based on the NUVEL-1 plate model and the approximation of deformation in the Great Basin region. The frictional and dislocation creep constants of the crust are calculated to reproduce the observed variations in the maximum depth of seismicity which corresponds to the temperature ranging from $350^{\circ}C$ to $410^{\circ}C$. The rheologic constants are defined by the coefficient of friction on faults, and the apparent activation energy for creep in the lower crust. Two parameters above represent systematic variations in three experiments. The pattern of model indicates that the friction coefficient of major faults is 0.17~0.25. we test whether the weakness of faults is uniform or proportional to net slip. The geologic data show a good agreement when fault weakness is a trend of an additional 30% slip dependent weakening of the San Andreas. The results of study suggest that all weakening is slip dependent. The best models can be explained by the available data with RMS mismatch of as little as 3mm/year, so their predictions can be closely related with seismic hazard estimation, at least along faults where no data are available.

• Proceedings of the Korean Environmental Sciences Society Conference
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• 2003.11a
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• pp.61-64
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• 2003

This study was conducted to investigate the chemical characteristics of $PM^{10}$ at Anmyeon-do during the periods from January 1998 to December 2001. The $PM^{10}$ samples ($PM^{10}$) were collected by High Volume Air sampler (HVAS). The measured items were mass concentration of $PM^{10}$ with the major ions ($Cl^{-}$, ${SO_{4}}^{2-}$, ${NO_3}^{-}$, ${Mg}^{2+}$, ${Ca}^{2+}$, ${K}^{+}$etc.) and metallic elements (AI, Fe, Mn, Cr, Zn, Pb etc.). The chemical analysis of major ion components were made by Ion Chromatography (DX-500) and that of metallic elements were made by Inductively Coupled Plasma Spectrometer (ICP-AES, ICP-Mass). The average mass concentration of $PM^{10}$ increased substantially during the heavy dust periods (Asian Dust cases). For water-soluble ions, concentrations of ${Ca}^{2+}$, ${SO_{4}}^{2-}$ and ${NO_3}^{-}$ were remarkably enhanced. Concentrations and mass fraction of crustal elements such as Na, Mg, Ca, Fe, Mn were highly elevated, but those of pollution-derived heavy metals were appreciably decreased. The factor analysis was conducted in order to make the large and diverse data set as manageable levels and to qualitatively examine the relationship between the variables.

• Economic and Environmental Geology
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• v.26 no.4
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• pp.499-505
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• 1993

The Imgye hornblendites occur as intrusive sills or dykes within the mylonite zone developed along the contact boundary between Precambrian Jungbongsan granite and Cambrian Jangsan quartzite or Myobong slate formations. The hornlendites belong to the subalkaline and tholeiitic series. In tectonomagmatic discrimination diagrams such as $TiO_2-K_2O-P_2O_5$, 2Nb-Zr/4-Y and $TiO_2-10MnO-10P_2O_5$, the hornblendites are classified into continental- and island-arc tholeiites. The hornblendites show fractionated REE patterns with $(La/Yb)_{CN}$ ranging from 3.73-4.56. In incompatible element abundance variations, the hornblendites show distinctive positive and negative anomalies for Rb and Nb, respectively, and unfractionated patterns of immobile incompatible elements such as Y and Yb. The REE patterns of the hornblendites are also similar to those of typical continental back-arc tholeiites and those of the Precambrian Okbang amphibolites in the Socheon-meon, Bonghwa-gun. Accoiding to geochemical characteristics above-mentioned, the hornblendites seem to have been formed from tholeiitic magmas of depleted upper mantle source, contaminated by crustal material en route to continental back-arc basin.

• Economic and Environmental Geology
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• v.25 no.4
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• pp.435-446
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• 1992

REE, major and trace elements analyses of the Jurassic Daebo granite and Cretaceous Bulguksa granite were carried out to interpet their petrogenesis and relationships between petrogenesis and tectonics. Analytical results are summarized as follows. (1) $SiO_2$ content of the Bulguksa granite (aver. 74.6%) are significantly higher than those of the Daebo granite (aver. 68.1%). Major elements of $TiO_2$, $Al_2O_3$, $P_2O_5$, CaO, MgO, Total FeO, and trace elements of Co, V and Sr are negatively correlated with $SiO_2$. Incompatible elements such as Ba, Sr, Y, Zr and HREE are contained differently in the Bulguksa granites distributed in between Okchon folded belt and Kyongsang sedimentary basin. (2) Trace element abundances show a good discrimination between two goups of granitic rocks. Ba, Sr and V are enriched in Daebo granites, while Zn and Cr are depleted in them. (3) Jurassic granites have quite different Eu anomalies and REE patterns from those of Cretaceous granites: Large negative Eu anomaly in the former and mild or absent Eu anomaly in the latter. The large Eu negative of Cretaceous granitic rocks are interpreted as a differentiated product of fractional crystallization of granitic magma from the upper mantle. Meanwhile, the Daebo plutonic rocks was resulted from the partial melting of subcrustal material or crustal contamination during ascending granitic magma from the mantle. Senario of igneous activities of Mesozoic age in South Korea was proposed based on Kula-Pacific ridge subduction model.

• Korean Journal of Materials Research
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• v.19 no.7
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• pp.386-390
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• 2009

Niobium(Nb) and Tantalum(Ta) are rarely found apart in nature and never in the free state. The element niobium amounts to 3% of the crustal abundance. On the whole, the niobium capacitor showed somewhat more unstable characteristics than the commercial tantalum capacitors, but is nonetheless considered applicable as a future substitute for tantalum capacitors. In this study, niobium powder was made from potassium heptafluoroniobite($K_2NbF_7$) by using sodium(Na) as a reductant and KCl and KF as diluents based on the hunter sodiothermic reduction method.,In order to obtain a high surface area niobium powder via the sodiothermic reduction method, a certain amount of diluent, such as alkali metal halides selected from NaCl, KCl, KF and NaF, was added in the raw materials to be reduced. However, if a higher surface area of powder is required, more diluents need to be used in the said method in order to produce niobium powder. But when more diluents are used, the niobium powder will be contaminated with more impurities and the yield will also decreased.

• Journal of Korean Society for Atmospheric Environment
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• v.29 no.5
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• pp.553-573
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• 2013

This paper aims to give a summary and review of the research trend about subjects of Asian Dust (AD) storm in the last three decades. The AD research was focused on classification of synoptic scale data and finding inflow pathway in early stage. Recently, new approaches have been made to explain chemical composition, transportation, transboundary movement reaction of AD, using satellite data, 3D modeling, the aerosol time of flight mass spectroscopy, etc. During AD events, a large amount of dust particles flow into Korea and Japan from AD source areas, and they are highly likely to be mixed with toxic substances when air mass contained AD particles pass over seriously polluted areas. We concluded that, considering that AD events were classified into two cases according to the source area and pathway, the concentrations of crustal components did not increase at the initial stage of AD events, Whereas ammonium-sulfate, trace metal element, OC, EC relatively increased in the early stage. This explains AD events have the possibility of being accompanied with polluted air mass or particles. Also, we further need to compare and summarize the results of AD studies which already have been conducted, and prepare strategies for particle management, particularly for Black Carbon (BC) and Brown Carbon (BrC) which are considered to induce climate change effects.

• Journal of the Korean earth science society
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• v.34 no.2
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• pp.109-119
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• 2013

Duibaejae basalts from Goseong, Gangwon-do, are divided into the lower basalt and the upper basalt depending on the properties, such as occurrence, mineral compositions, and major and trace compositions of the basalts. The lower basalts have characteristics of agglomerate rocks as well as contain, crustal and mantle xenoliths, and olivine, pyroxene, and plagioclase xenocrysts. The upper basalts with columnar joints contain relatively more mantle xenolith and olivine xenocryst than the lower basalts. The major and trace element compositions suggest that the composition of the upper basalts is close to primary magma composition. Enrichment and depletion patterns of the trace and the rare-earth elements of the lower basalts are similar to those of the upper basalts, whereas the lower basalts are more LREE enriched than the upper basalts. The source magmas of the lower and upper basalts from Duibaejae volcanic edifice were generated from about 0.8-1.2% and 3.7-4.0% batch melting of garnet peridotite, respectively. The abundance of granite xenolith, and plagioclase and quartz xenocrysts with reaction rim indicates that the lower basalts, compared with upper basalts, might have been assimilated with the crustal materials during ascending to surface.

• Economic and Environmental Geology
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• v.24 no.4
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• pp.447-463
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• 1991

Petrological and chemical studies of Precambrian dikes in the southern Lake Superior region were conducted with the objects of evaluating magma source and constraining models for the paleo-tectonic environment. Forty-six samples were analyzed for major, trace, and rare earth elements. Chemical data of the studied dikes are typical of continental tholeiites and showing iron-enrichment fractionation trend. With wallrock contamination carefully evaluated, a series of tectonic discriminating methods utilizing immobile trace elements indicate that the source magma was a high-Ti tholeiitic basalt similar to present-day T-type MORB. Effect of chemical contamination from wallrock assimilation accmulates with increasing differentiation. Evolved rocks show LREE enriched patterns and have enhanced levels of LIL elements (e.g., Rb, K, Ba, Th), but low levels of high field strength elements (e.g., Nb, P, Ti) with respect to their neighboring elements. It is suggested from this study that this enrichment possibly due to a combination of a feature inherited from the subcontinental lithosphere and crustal contamination. Geochemical signatures of these rocks are distinctively different from those of arc-related volcanics. Comparisons with chemistries of modern magmas show a pattern of overlap between Within-plate and ocean-floor characteristics, and chemical signatures of these rocks favor a model of intrusion into a crustal environment undergoing lithospheric attenuation.

• The Journal of the Petrological Society of Korea
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• v.20 no.4
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• pp.191-206
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• 2011

The emplacement ages, whole-rock geochemistry and Sr-Nd isotopic compositions of granitoid rocks from Cheongju area, South Korea, were investigated for delineating their petrogenetic link to the Jurassic Daebo granitoid rocks. Zircon crystals were collected from the diorite, biotite granite and acidic dyke samples in a single outcrop. Cross-cutting relationships show that the emplacement of diorite was postdated by the intrusion of biotite granite. Both rocks have been subsequently intruded by acidic dyke. The U-Pb isotopic compositions of zircon from the diorite, biotite granite, and acidic dyke were measured using a SHRIMP-II ion microprobe, yielding the crystallization ages of $174{\pm}2Ma$, $170{\pm}2Ma$, and $170{\pm}5Ma$, respectively, with 95% confidence limits ($t{\sigma}$). The emplacement ages are consistent with those determined from the above relative ages. The major and trace element patterns of the rocks are consistent with those of the Jurassic Daebo granitoid rocks, possibly suggesting a subduction-related I-type granite. The geochemical signature is, however, betrayed by the Sr and Nd isotopic compositions of these rocks. The isotopic signatures suggest that the rocks were produced either by the partial melting of lower-crust or by the mantle-derived magma contaminated by the basement rocks during its ascent and/or emplacement. In addition, the inherited ages of zircons of the rocks (ca. 2.1, 1.8, 0.8 and 0.4 Ga) suggest a possible assimilation with crustal rocks from the Gyeonggi massif and Ogcheon metamorphic belt.