• Journal of the Semiconductor & Display Technology
• /
• v.11 no.1
• /
• pp.35-39
• /
• 2012

$YAlO_3:Tb{_x}^{3+}$ has been synthesized by a combustion process and the concentration x of Tb was varied from 0.001 and 0.05 mol% per mole of $YAlO_3$. The emission optical properties on the $YAlO_3:Tb{_x}^{3+}$ have been investigated by time-resolved photoluminescence spectra and decay curves of center wavelength. The emission color changes from blue to green with increasing the $Tb^{3+}$ concentration from x= 0.001 to 0.05 mole fraction in $YAlO_3$ host. This emission color change can be explained in terms of cross-relaxation processes. Decay curves of emission intensity indicate that the type of energy transfer is donor-acceptor transition.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.24 no.5 s.176
• /
• pp.1103-1114
• /
• 2000

Recent attempt to enhance the safety against collision reshaped the simple shell structures into the integrated complex shell structures. Moreover, due to various regulations continuously tightened for environment protection, weight reduction of automobiles becomes an increasingly important issue. Auto parts lightening is mainly accomplished by more reasonable design, adoption of lighter materials and miniaturization of the auto bodies. Focusing on the locally enhanced design approach among the above three ways, we here attempt to develop a patching optimization method, and also to determine the thicknesses of an integrated shell structure, both bringing a specified amount of stress relaxation. We first select a cross member as a patching optimization model. Based on the finite element stress calculations, we relieve the stress of cross member by patching in two ways-nonuniform thickness patching and optimized uniform thickness patching, the latter of which is more effective in a practical point of view for the preset amount of stress relaxation. Selecting a box type subframe as another finite element analysis model, we then determine the thickness of each part by axiomatic design approach for a preset amount of stress relaxation. The patching methodology and the axiomatic approach adopted in this work can be applied to the other complex shell structures such as center member and lower control arm.

• Korean Journal of Optics and Photonics
• /
• v.1 no.2
• /
• pp.149-154
• /
• 1990

Energy transfer in $Tb^{3+}$-doped borosilicate glasses has been studied by the analysis of fluorescence intensities and lifetimes of $^5D_3$ and $^5D_4$ states as a function of Tb3+ concentration. It is shown that as the $Tb^{3+}$ concentration is increased the cross-relaxation produces high population of the $^5D_4$ state at the expense of $^5D_3$. It is also found that this interaction is predominantly dipole-dipole transition with critical distance of 13 A. The critical distance for energy transfer $^5D_4$$^5D_4$ which is responsible for the quenching of 5D4 emission at high concentratron of Tb3+ ions is 4.5 A.

• Steel and Composite Structures
• /
• v.44 no.6
• /
• pp.753-768
• /
• 2022

In this study, a graphical automatic system is developed in order to investigate the stress redistribution of structural members in a steel cable-stayed bridge. The generalized Maxwell model is selected for stress relaxation estimation, and it is carefully verified and applied to all the cable members of a steel cable-stayed bridge to investigate its stress relaxation. A set of stress relaxation parameters in all cables is determined using the fmincon optimization function. The stress redistribution of the steel cable-stayed bridge is then analyzed using ABAQUS. To shorten the investigation time, all the aforementioned phases are built up to be an automatic system. The automatic system is then employed to investigate the effect of cable cross-section areas and girder spans on stress redistribution. The findings from these studies show that the initial tension in the cables of a steel cable-stayed bridge should be kept to less than 55% of the cable's ultimate strength to reduce the effect of cable stress relaxation. The cable space in a steel cable-stayed bridge should be limited to 15,000 mm to minimize the effect of cable stress relaxation. In comparison to other structural members of a steel cable-stayed bridge, the girders experience a significant stress redistribution.

• Bulletin of the Korean Chemical Society
• /
• v.21 no.11
• /
• pp.1077-1084
• /
• 2000

The dipolar effect of neighboring protons that are not directly bonded to the carbon of interest on coupled carbon-13 relaxation in a simple organic molecule has been studied by comparing the relaxation behaviors of labeled carbon-13 in $Br13CH_2COOH$ with those in $BrCH_213COOH.$ Various pulse sequences, such as coupled inversion recovery pulse sequence, J-negative and J-positive pulse sequence, and nonselective and selective proton ${\pi}pulse$ sequence, were employed to perform the required coupled spin relaxation experiments. To gain information on various spectral densities, including that of dipolar-CSA cross correlation, the experiments were performed on two different spectrometers, operating, respectively, at 50.31 and 125.51MHz for 13C. The magnitude of CH dipolar spectral densities for $BrCH_213COOH$ was found to be about 8% of those for $Br13CH_2COOH$, which means the effect due to the protons not directly bonded to the carbon of interest is small but not completely negligible.

• Bulletin of the Korean Chemical Society
• /
• v.15 no.7
• /
• pp.553-559
• /
• 1994

Dynamics of $CH_2CI$ group in ${\alpha},2,6$-trichlorotoluene dissolved in $CDCl_3$ was studied by observing various relaxation modes for $^{13}C$ under proton undecoupled condition. Partially relaxed $^{13}C$ spectra were obtained at $34^{\circ}C$ as a function of evolution time after applying various designed pulse sequences to this $AX_2$ spin system. It was found that nonlinear regression analysis of the relaxation data for these magnetization modes could provide the information about dipolar and spin-rotational auto-correlation and cross-correlation spectral densities for fluctuation of the $^{13}C-^1H$ internuclear vector in $CH_2Cl$ group. The results show that the effect of cross-correlation is comparable in magnitude to that of auto-correlation and the relaxation in this spin system is dominated by dipolar mechanism rather than spin-rotational one. From the resulting spectral density data we could calculate the bond angle ${\angle}HCH\;(105.1$^{\circ}$) and elements of the rotational diffusion tensor for $CH_2Cl$ group.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2003.07b
• /
• pp.968-971
• /
• 2003

Due to a low efficiency of phosphor with large Stoke shift in Vacuum Ultra Violet (VUV) excitation environment, new PDP phosphors which can be excited in UV excitation environment need to be developed. In this study, $Zn_2SiO_4:Tb$ phosphor was synthesized by solid-state reaction method at $1300^{\circ}C$ with varying Tb concentration, and its cross relaxation effect was observed by Photoluminescence (PL) measurement. In order to decrease $^5D_3{\to}7F_j$ transition with blue emission in $Zn_2SiO_4:Tb$ phosphor, Dy, co-activator element, was added to $Zn_2SiO_4:Tb$ phosphor. In 254nm excitation environment, broad-emission peak was observed around 524nm, green emission.

• Journal of the Korean Chemical Society
• /
• v.20 no.5
• /
• pp.340-350
• /
• 1976

Linear response theory is proposed to be applied for theoretical description of the phenomena in mechanical spectroscopy of solid high polymers below glass transition temperatures. The energy dissipation by sample is given in terms of certain time correlation functions. It is shown that the result leads to the result by Kirkwood on the energy loss and relaxation of cross-linked polymers, if the Liouville operator is replaced by the diffusion equation operator of Kirkwood. An approximation method of calculating the correlation functions is considered in order to show a way to calculate relaxation times. Using the approximation method, we consider a double-well potential model for energy relaxation, in order to see a connection between the present theory and a model theory used in mechanical energy relaxation phenomena of solid polymers containing pendant cyclohexyl groups at low temperature.

• Proceedings of the Korean Ceranic Society Conference
• /
• 2003.10a
• /
• pp.21.1-21
• /
• 2003

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
• /
• v.3 no.4
• /
• pp.23-27
• /
• 2010

This paper performs emotion classification test to find out the best parameter of electroencyphalogram(EEG) signal. Linear predictor coefficients, band cross-correlation coefficients of fast Fourier transform(FFT) and autoregressive model spectra are used as the parameters of 10-channel EEG signal. A multi-layer neural network is used as the pattern classifier. Four emotions for relaxation, joy, sadness, irritation are induced by four university students of an acting circle. Electrode positions are Fp1, Fp2, F3, F4, T3, T4, P3, P4, O1, O2. As a result, the Linear predictor coefficients showed the best performance.