• Title/Summary/Keyword: Cross-reaction

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The Reaction Probability and the Reaction Cross-section of N + O2→ NO + O Reaction Computed by the 6th-order Explicit Symplectic Algorithm

  • He, Jianfeng;Li, Jing
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.1976-1980
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    • 2006
  • We have calculated the reaction probability and the reaction cross-section of the $N(^4S)+O_2(X^3\sum_{g}^{-})\;\rightarrow\;NO(X^2\Pi)+O(^3P)$ reaction by the quasiclassical trajectory method with the 6th-order explicit symplectic algorithm, based on a new ground potential energy surface. The advantage of the 6th-order explicit symplectic algorithm, conserving both the total energy and the total angular momentum of the reaction system during the numerical integration of canonical equations, has firstly analyzed in this work, which make the calculation of the reaction probability more reliable. The variation of the reaction probability with the impact parameter and the influence of the relative translational energy on the reaction cross-section of the reaction have been discussed in detail. And the fact is found by the comparison that the reaction probability and the reaction cross-section of the reaction estimated in this work are more reasonable than the theoretical ones determined by Gilibert et al.

The Effect of Cross Education using Serial Reaction Time (연속반응시간과제를 이용한 교차훈련의 효과)

  • Choi, Jin-Ho;Park, So-Hyun
    • The Journal of Korean Physical Therapy
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    • v.20 no.4
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    • pp.15-20
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    • 2008
  • Purpose: We investigated the effects of physical practice, mental practice, and cross education using serial reaction time (SRT). We recruited 21 right-handed healthy males and females who gave consent and had no clinical history for their upper limbs. Methods: The subjects were divided into three groups; actual practice (n=7), mental practice (n=7), and controls (n=7), who performed actual training, mental training, or no intervention respectively for three weeks. Super lab 4.0 displayed four symbols on the monitor and subjects pushed on the matching button, with reaction time assessed pre- and post-intervention. Results: Reaction time was significantly lower after actual or mental practice (p<0.05). Actual practice also decreased left hand reaction time. Conclusion: Actual practice and mental practice can improve motor learning, but mental practice is not sufficient for cross education.

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Formation of Cross-Linked Products of The Reaction Center D1 Protein in Photosystem II under Light Stress

  • Uchida, Suguru;Kato, Yoji;Yamamoto, Yasusi
    • Journal of Photoscience
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    • v.9 no.2
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    • pp.382-384
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    • 2002
  • When illuminated with strong visible light, the reaction center Dl protein of photo system II is photodamage and degraded. Reactive oxygen species and endogenous cationic radicals generated by photochemical reactions are the cause of the damage to the Dl protein. Recently we found that the photodamaged Dl protein cross-links with the surrounding polypeptides such as D2 and CP43 in photosystem II. As the cross-linking reaction is dependent on the presence of oxygen, reactive oxygen species are suggested to be involved. Among the reactive oxygen species examined, ? OH was most effective in the formation of the cross-linked products. These results indicate that the cross-linking is mostly due to ? OH generated at photosystem II. The cross-linking site of the Dl protein is not known. As several tyrosine residues exist at the D­E loop of the Dl protein, there is a possibility that di-Tyr is formed between the D­E loop of the Dl protein and surrounding polypeptides during the strong illumination. Therefore, we examined the formation of di-Tyr using the monoclonal antibody against di-Tyr under excess illumination of the photosystem II membranes. The results obtained here suggest that no di-Tyr is formed during the excess illumination of photosystem II.

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Etiology of Delayed Inflammatory Reaction Induced by Hyaluronic Acid Filler

  • Won Lee;Sabrina Shah-Desai;Nark-Kyoung Rho;Jeongmok Cho
    • Archives of Plastic Surgery
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    • v.51 no.1
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    • pp.20-26
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    • 2024
  • The etiology and pathophysiology of delayed inflammatory reactions caused by hyaluronic acid fillers have not yet been elucidated. Previous studies have suggested that the etiology can be attributed to the hyaluronic acid filler itself, patient's immunological status, infection, and injection technique. Hyaluronic acid fillers are composed of high-molecular weight hyaluronic acids that are chemically cross-linked using substances such as 1,4-butanediol diglycidyl ether (BDDE). The mechanism by which BDDE cross-links the two hyaluronic acid disaccharides is still unclear and it may exist as a fully reacted cross-linker, pendant cross-linker, deactivated cross-linker, and residual cross-linker. The hyaluronic acid filler also contains impurities such as silicone oil and aluminum during the manufacturing process. Impurities can induce a foreign body reaction when the hyaluronic acid filler is injected into the body. Aseptic hyaluronic acid filler injections should be performed while considering the possibility of biofilm formation or delayed inflammatory reaction. Delayed inflammatory reactions tend to occur when patients experience flu-like illnesses; thus, the patient's immunological status plays an important role in delayed inflammatory reactions. Large-bolus hyaluronic acid filler injections can induce foreign body reactions and carry a relatively high risk of granuloma formation.

Synthesis of Neopentyl Biphenylsulfonates Using the Suzuki-Miyaura Reaction

  • Cho, Chul-Hee;Kim, Chul-Bae;Sun, Myung-Chul;Park, Kwang-Yong
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1632-1636
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    • 2003
  • Palladium-catalyzed cross-coupling reactions of neopentyloxysulfonylphenyl bromides with arylboronic acids provided a variety of neopentyl biphenylsulfonates in good yields. 2-Bromo- and 4-bromobenzenesulfonates underwent the coupling reaction more rapidly than 3-bromobenzenesulfonate, while chlorobenzenesulfonate did not produce the coupling product under the standard reaction conditions.

The Effect of Cross-Education in Nondominant Arm with Normal Adult (정상인의 비우성 상지를 이용한 교차훈련의 효과)

  • Choi, Jin-Ho;Lee, Mi-Young
    • The Journal of Korean Physical Therapy
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    • v.23 no.2
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    • pp.31-36
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    • 2011
  • Purpose: We investigated the effects of physical practice, mental practice, and cross education using serial reaction time (SRT) in the non-dominant left arm of right-handed individuals. Methods: Subjects were divided into three groups; physical practice (n=8), mental practice (n=8) and controls (n=8). They did, respectively, physical training or mental training, or had no intervention for three weeks. Super lab 4.0 displayed four symbols on the monitor and subjects were asked to push the matching button. Reaction time was assessed pre- and post-intervention. Results: Reaction time was significantly lower after physical practice (p<0.05), but mental practice did not significantly lower reaction time? in the left hand. Also, reaction time was not significantly lower after physical practice or mental practice in the right hand. Conclusion: Physical practice can improve motor learning, but mental practice is not sufficient. Also, neither physical practice nor mental practice is sufficient for cross education from the nondominant to the dominant arm.

Characterization of Edible Film Fabricated with Channel Catfish Ictalurus punctatus Gelatin by Cross-Linking with Transglutaminase

  • Oh, Jun-Hyun
    • Fisheries and Aquatic Sciences
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    • v.15 no.1
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    • pp.9-14
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    • 2012
  • The objectives of this research were to improve the film-forming properties of Channel Catfish Ictalurus punctatus skin gelatin (CSG) by cross-linking with transglutaminase (TG), determine and optimize the TG reaction time, and characterize the mechanical and barrier properties of CSG edible film. Cross-linking of CSG was performed by TG for 0, 10, 20, 30, and 40 min at $50^{\circ}C$, and the reaction was confirmed by sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). The color and mechanical and barrier properties of edible films fabricated with CSG cross-linked with TG were characterized. Gelatin yields from the extraction ranged from 18.2% to 23.3%. SDS-PAGE exhibited dark bands at 120 and 250 kDa, indicating successful TG-mediated cross-linking. The color of CSG film was not affected by TG cross-linking. The tensile strength of CSG films cross-linked with TG decreased from 42.59 to 21.73 MPa and the percent elongation increased from 42.92% to 76.96% as reaction times increased from 0 to 40 min. There was no significant difference in water vapor permeability of CSG films.

A study on (n, α) reaction cross sections using a new empirical systematic

  • Sema Kucuksucu;Mustafa Yigit
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4026-4031
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    • 2023
  • In this article, we report a new empirical formula for quick calculation of cross sections of (n, α) reactions with 14-15 MeV neutrons. Cross sections are analysed in terms of the compound nucleus model. A systematic trend for 14-15 MeV neutrons is found in the variation of (n, α) reaction cross sections with the parameters (N - Z + 1), (En + Q)0.5 and N/Z. The empirical relation between the cross sections and these parameters has been obtained, which give fairly good fits with the experimental data. We have also investigated the odd-even effects on (n, α) cross sections considering binding energy systematic of the shell model. The present formula is very useful in predicting of the (n, α) cross sections, where the measurements are not available as well as in testing new experimental data.

Preparation of Blood Glue from Porcine Plasma Protein and Cross-linking Reaction of Plasma Protein with Formaldehyde

  • Cho, Yongsik;Lee, Hwahyoung;Song, Kyung Bin
    • Journal of Applied Biological Chemistry
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    • v.42 no.2
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    • pp.81-84
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    • 1999
  • Blood glue was prepared to reutilize porcine blood. Plasma proteins after lyophilization were treated by addition of wood flour, sodium hydroxide, sodium silicate, and hydrated lime to make blood glue with a suitable adhesivity. Characteristics of the prepared blood glue was monitored by measuring the viscosity with time, and the relationship between degree of hydrolysis of plasma proteins by addition of various amounts of sodium hydroxide and adhesivity was studied. To prevent the emission of formaldehyde during manufacturing of plywood by blood glue, the cross-linking reaction of plasma protein with formaldehyde was also examined. Fourier transform infrared, circular dichroism, and fluorescence spectroscopy study showed that blood plasma proteins react with formaldehyde, resulting in removal of formaldehyde by cross-linking reaction.

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Neutron yield and energy spectrum of 13C(alpha,n)16O reaction in liquid scintillator of KamLAND: A Nedis-2m simulation

  • Vlaskin, Gennady N.;Bedenko, Sergey V.;Ghal-Eh, Nima;Vega-Carrillo, Hector R.
    • Nuclear Engineering and Technology
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    • v.53 no.12
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    • pp.4067-4071
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    • 2021
  • The 13C (α,n)16O reaction cross-section is important data for nuclear physics, astrophysical, and neutrino physics experiments, however, they exhibit uncertainties due to the discrepancies in the experimental data. In this study, using the Nedis-2m program code, the energy spectrum of α-induced neutrons in a thin carbon target was calculated and the corresponding reaction cross-section was refined in the alpha particle energy range of 5-8 MeV. The results were used to calculate the intensity and energy spectrum of background neutrons produced in the liquid scintillator of KamLAND. The results will be useful in a variety of astrophysical and neutrino experiments especially those based on LS or Gd-LS detectors.