• Journal of the Korean Chemical Society
• /
• v.42 no.2
• /
• pp.156-160
• /
• 1998

Probe diffusion with latex particles in two different types of chemically cross linked gel has been studied. The diffusion of particles in silica gel is decreased by decreasing the gel correlation length but the particles' diffusion in the acrylamide gel still shows the heterogeneity of the gel. By increasing the contents of the gel network the silica gel makes a more homogeneous and compact structure than that of acrylamide gel which has partial heterodyning. Dynamic light scattering study with the probe particles in two different gels reveals the heterogeneity of the gel network. The latex particles trapping in the gel has been investigated by using non-ergodic concepts.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2005.07b
• /
• pp.1291-1293
• /
• 2005

Hybrid insulator pentacene thin film transistors (TFTs) were fabricated with thermally grown oxide and cross-linked polyvinylalcohol (PVA) including surface treatment by dilute ploymethylmethacrylate (PMMA) layers on $n^+$ doped silicon wafer. Through the optimization of $SiO_2$ layer thickness in hybrid insulator structure, carrier mobility was increased to above 35 times than that of the TFT only with the gate insulator of $SiO_2$ at the same transverse electric field. The carrier mobility of 1.80 $cm^2$/V-s, subthreshold swing of 1.81 V/decade, and $I_{on}$/ $I_{off}$ current ratio > 1.10 × $10^5$ were obtained at low bias (less than -30 V) condition. The result is one of the best reported performances of pentacne TFTs with hybrid insulator including cross-linked PVA material at low voltage operation.

• Journal of the Semiconductor & Display Technology
• /
• v.9 no.4
• /
• pp.1-5
• /
• 2010

The PVA (poly-vinyl alcohol) insulators were spun coated onto ITO coated glass substrates with the capacitors of Glass/ITO/PVA/Al structure. The effects of PVA concentrations (3.0, 4.0 and 5.0 wt%) on the morphology and electrical properties of the films were investigated. As the concentration of PVA increased from 3.0 to 5.0 wt%, the leakage current of device decreased from 17.1 to 0.23 pA. From the AFM measurement, the RMS value decreased with increasing PVA concentration, showing the improvement of insulator film roughness. The capacitances of the films with PVA concentrations of 4.0 and 5.0 wt% were about 28.1 and 24.2 nF, respectively. The lowest leakage current of 1.77 PA was obtained at the film thickness of 117.5 nm for the device with fixed PVA concentration of 5.0 wt%.

• Journal of Microbiology and Biotechnology
• /
• v.21 no.11
• /
• pp.1159-1165
• /
• 2011

Biodiesel is methyl and ethyl esters of long-chain fatty acids produced from vegetable oils or animal fats. Lipase enzymes have occasionally been used for the production of this biofuel. Recently, biodiesel production using immobilized lipase has received increased attention. Through enhanced stability and reusability, immobilized lipase can contribute to the reduction of the costs inherent to biodiesel production. In this study, methanol-tolerant lipase M37 from Photobacterium lipolyticum was immobilized using the cross-linked enzyme aggregate (CLEA) method. Lipase M37 has a high lysine content (9.7%) in its protein sequence. Most lysine residues are located evenly over the surface of the protein, except for the lid structure region, which makes the CLEA preparation yield quite high (~93%). CLEA M37 evidences an optimal temperature of $30^{\circ}C$, and an optimal pH of 9-10. It was stable up to $50^{\circ}C$ and in a pH range of 4.0-11.0. Both soluble M37 and CLEA M37 were stable in the presence of high concentrations of methanol, ethanol, 1-propanol, and n-butanol. That is, their activities were maintained at solvent concentrations above 10% (v/v). CLEA M37 could produce biodiesel from olive oil and alcohols such as methanol and ethanol. Additionally, CLEA M37 generated biodiesel via both 2-step methanol feeding procedures. Considering its physical stability and reusability, CLEA M37 may potentially be used as a catalyst in organic synthesis, including the biodiesel production reaction.

• Textile Coloration and Finishing
• /
• v.35 no.4
• /
• pp.231-238
• /
• 2023

Microporous gel films of 29 m were prepared by the gel drawing of UHMWPE/soybean oil blend (4:6, w/w) up to 800%. The stretched films containing the optimal photoinitiator concentration, depending on the film thickness, was cross-linked under 365 nm LED-UV irradiation and the oil was extracted with n-hexane, resulting in a gel fraction of 95 % or more. With the formation of the cross-linked structure, the melt-down temperature and melt-down elongation increased by 16 ℃ and by 63% respectively. Also the thermal stability of the crosslinked UHMWPE was proved by the area shrinkage under the heat treatment decreased to 3.8 % compared to 17.4 % for the pristine film, and by the reductions in the combustion heat. The enhanced thermal stability of the crosslinked UHMWPE microporous membranes can be used for various industrial applications such as filters, electric vehicles and energy storage systems.

• 한국정보디스플레이학회:학술대회논문집
• /
• 2006.08a
• /
• pp.1178-1181
• /
• 2006

We fabricated a flexible OTFT(organic thin film transistor) backplane for the electrophoretic display. The backplane was composed of $128{\times}96pixels$ on the Polyethylene Naphthalate substrate in which each pixel had one OTFT. The OTFTs employed bottom contact structure and used the cross-linked polyvinylphenol for gate insulator and pentacene for active layer

• 한국정보디스플레이학회:학술대회논문집
• /
• 2007.08a
• /
• pp.159-161
• /
• 2007

We fabricated flexible OTFT-backplanes for the electrophoretic display(EPD). The OTFTs employed bottom contact structure on PEN substrate and used the cross-linked polyvinylphenol for gate insulator, pentacene for active layer. Especially, we used PVA/Acryl double layers for passivation of backplane as well as for pixel dielectric layer between backplane and EPD panel. The OTFT-EPD panel worked successfully anddemonstrated to display some patterns.

• Journal of the Korean Society for Aviation and Aeronautics
• /
• v.19 no.4
• /
• pp.74-82
• /
• 2011

In order to enhance the aviation industry in Korea, many strategies have been published by some researchers as well as the government. However, considering the constrained conditions in real, since the ranking of their importance has not determined yet, they are difficult to be implemented by decision makers. Therefore, in terms of their demand for deciding the significance of strategies, the evaluation model of this paper was developed. In this study, the Cross-impact Hierarchy Process(CHP), an linked model of both the Analytic Hierarchy Process(AHP) and Cross Impact Analysis(CIA), was selected as the best model. That is because the strategies are not independent from each other, and one strategy can affect the others depending on its realization, which can be considered in CHP. To achieve our objective, at first, the strategies were categorized and arranged according to the evaluation structure. Secondly, the parameters such as conditional probability and weights were estimated from the survey conducted by 16 experts in the aviation field. Lastly, the result of the assessment were discussed, and further studies were suggested.

• The Korean Journal of Vision Science
• /
• v.20 no.4
• /
• pp.513-521
• /
• 2018

Purpose : : In this study, we made dopamine-functionalized hydrogels containing a cross-linked hyaluronic acid (HA) network and investigated their antioxidant activities. Methods : In the first step, we made poly hydroxyethyl methacrylate(p(HEMA))-based hydrogels post-modified with an interpenetrating polymer network(IPN) structure composed of HA polymers and a p(HEMA) network. The subsequent functionalization with dopamine via an amide coupling reaction resulted in the antioxidant hydrogels. Their antioxidant activities were evaluated using 2,2'-azino-bis-(3-ethylbenzothiazoline-6-sulfonic acid) and 2,2-diphenyl-1-picrylhydrazyl radical scavenging assays. Results : The dopamine-modified hydrogels exhibited significant antioxidant activities, when compared to unmodified control. The presence of the HA-IPN structure improved the surface wettability of the hydrogel while dopamine-conjugated IPN hydrogel did not demonstrate the significant difference compared to hydrogel control. Dopamine-modified hydrogels exhibited high transmittance (>88%). Conclusion : The results demonstrate that the development of antioxidant hydrogels based on dopamine-conjugated HA-IPN structures may help develop ophthalmic and biomedical materials.

• Proceedings of the Korean Society For Composite Materials Conference
• /
• 2003.10a
• /
• pp.111-114
• /
• 2003

Thermosets are highly cross-linked polymers with a three-dimensional molecular structure. The network structure gives rise to mechanical properties, however, one major drawback of thermosets, which also results from their network structure, is their poor resistance to impact and to crack initiation. In this study, to solve this problem, the reactive thermoplastics such as amine terminated polyetherimide (ATPEI), ATPEI-CTBN-ATPEI(ABA) triblock copolymer, CTBN-ATPEI(AB) diblock copolymer, and carboxyl group modified ATPEI was synthesized, after that blended with epoxy resin, and the carbon fiber reinforced composites were fabricated. The impact load, energy, and delamination were investigated by using drop weight impact test and C-scan test. As a results, the ABA/epoxy blend system showed good impact properties.