• 제목/요약/키워드: Cross-linked density

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Ethylene Polymerization Using (n-BuCp)$_{2}ZrCl_{2}$ Catalyst Activated with a Cross-linked MAO-Supported Cocatalyst

  • Yoon, Keun-Byoung
    • Macromolecular Research
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    • 제12권4호
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    • pp.336-341
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    • 2004
  • A new type of cross-linked methylaluminoxane (MAO)-supported cocatalyst has been prepared by the reaction of a soluble MAO and a cross-liking agent such as an aromatic diamine compound. The cross-linked MAO-supported cocatalyst was used for the polymerization of ethylene in the presence of bis(n-butylcyclopentadienyl) zirconium dichloride, (n-BuCp)$_2$ZrCl$_2$. The catalyst activity of (n-BuCp)$_2$ZrCl$_2$ cocatalyzed with the new supported cocatalyst was higher than that of the commercial silica-supported MAO (SMAO) cocatalyst. The molecular weight and the bulk density of the polyethylene produced by using the new supported cocatalyst were slightly higher than those of polyethylene synthesized using commercial SMAO. The resulting polyethylene particles possess spherical morphologies with very few fine particles.

와이블 분포식을 이용한 에폭시 복합체의 절연 신뢰도 분석 (Analysis of Insulating Reliability in Epoxy Composites using Weibull Distribution Equation)

  • Park, No-Bong;Lim, Jung-Kwan;Park, Yong-Pil
    • 한국정보통신학회:학술대회논문집
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    • 한국해양정보통신학회 2003년도 춘계종합학술대회
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    • pp.813-816
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    • 2003
  • The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, according to Weibull distribution analysis, reducing breakdown probability of equipment insulation lower than 0.1 % level requires the allowable field intensity values to be kept under 21.5 MV/cm.

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DC 절연파괴 특성을 이용한 Epoxy 복합체의 절연 신뢰도 평가 (Evaluation of Insulating Reliability in Epoxy Composites by DC Dielectric Breakdown Properties)

  • 임중관;박용필;김정호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2001년도 하계학술대회 논문집
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    • pp.92-95
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    • 2001
  • The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5 [Mv/cm].

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절연파괴 특성을 이용한 Epoxy 복합체의 전기적 열화 분석 (Analysis of Electrical Degradation in Epoxy Composites by Dielectric Breakdown Properties)

  • 최철호;박용필;임중관
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 하계학술대회 논문집
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    • pp.414-419
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    • 2002
  • The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of (idled specimens with treating silane, the breakdown strength become much higher Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5 MV/cm.

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Evaluation of Insulating Reliability in Epoxy Composites

  • Park, No-Bong;Yang, Dong-Bok;Lim, Jung-Kwan;Park, Yong-Pil;Lee, Hee-Kab;Kim, Gui-Yeul
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 하계학술대회 논문집 Vol.4 No.2
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    • pp.1200-1203
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    • 2003
  • The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, according to Weibull distribution analysis, reducing breakdown probability of equipment insulation lower than 0.1% level requires the allowable field allowable field intensity values to be kept under 21.5 MV/cm.

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Effects of a Compatibilizer on the Tensile Properties of Low-Density Polyethylene/Modified Starch Blends

  • Park, Jin-Woo;Kim, Gue-Hyun;Moon, Jin-Bok
    • 한국환경과학회지
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    • 제22권10호
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    • pp.1287-1294
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    • 2013
  • In this study, thermoplastic starch (TPS), cross-linked starch (CS), and cross-linked starch modified with glycerol (CTPS) were prepared, and the mechanical properties of the compatibilized low-density polyethylene (LDPE) blends (LDPE/TPS, LDPE/CS, and LDPE/CTPS) were investigated and compared with those of uncompatibilized LDPE/TPS, LDPE/CS, and LDPE/CTPS blends. Maleic-anhydride-grafted polyethylene was used as the compatibilizer. The enhanced tensile strength and elongation at break for the compatibilized LDPE/modified starch blends are a result of the improved compatibility between LDPE and the modified starch, which was confirmed by torque measurements and scanning electron microscopy.

절연파괴 특성을 이용한 Epoxy 복합체의 전기적 열화 평가 (Evaluation of Electrical Degradation in Epoxy Composites by Dielectric Breakdown Properties)

  • 임중관;박용필
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2002년도 춘계학술대회 논문집 유기절연재료 전자세라믹 방전플라즈마 일렉트렛트 및 응용기술
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    • pp.212-217
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    • 2002
  • The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric field is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5 MV/cm.

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와이블 분포식을 이용한 Epoxy 복합체의 절연 신뢰도 해석 (Analysis of Insulating Reliability in Epoxy Composites Using Weibull Distribution Equation)

  • 임중관;박용필;이준웅
    • 한국전기전자재료학회논문지
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    • 제14권8호
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    • pp.647-651
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    • 2001
  • The dielectric breakdown of epoxy composites used for transformers was experimented and then its data were applied to Weibull distribution probability. First of all, speaking of dielectric breakdown properties, the more hardener increased, the stronger breakdown strength became at low temperature because of cross-linked density by the virtue of ester radical. The breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised and the electric filed is concentrated. In the case of filled specimens with treating silane, the breakdown strength become much higher. Finally, from the analysis of weibull distribution, it was confirmed that to low allowed breakdown probability under 0,.1%, the applied field value needed to be under 21.5MV/cm.

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인쇄 회로 기판용 에폭시 복합체의 첨가제에 따른 절연 신뢰도 (Insulating Reliability according to additives in Epoxy Composites for PCB Material)

  • 양정윤;박영철;박건호
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 춘계학술대회 논문집 기술교육전문연구회
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    • pp.159-163
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    • 2003
  • In this study, the DC dielectric breakdown of epoxy composites used for PCB material was experimented and then its data were simulated by Weibull distribution equation. The more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical, and the breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised, the electric field is concentrated, and the acceleration of electron and the growth of electron avalanche are early accomplished. From the analysis of Weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1[%], the applied field value needed to be under 21.5[kV/mm].

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Oligomeric Characterization of GroESLx Chaperonin from Symbiotic X-Bacteric in Amoeba proteus

  • Jung, Gwang-Hyun;Ahn, Tae-In
    • Animal cells and systems
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    • 제6권3호
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    • pp.227-232
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    • 2002
  • GroESLx proteins of symbiotic X-bacteria were overproduced in Escherichia coli and their structural characteristics were assayed after simple purification. The GroESx and GroELx were heat-stable at 8$0^{\circ}C$ and 5$0^{\circ}C$, respectively. After heat-treatment, GroESx was purified by DEAE Sephadex A-50 chromatography and GroELx was purified by step- and linear sucrose density gradient ultracentrifugation. Molecular masses of GroESx and GroELx were 50-80 kDa and 800 kDa, respectively, as estimated by sucrose density gradient ultracentrifugation. In chemical cross-linking analysis, subunits of GroESx were mostly cross-linked by incubation for 3 h in 0.4% glutaralde-hyde and GroESx was found to be composed of homo-heptamer subunits. Those of GroELx were cross-linked within 10 min in 0.3% glutaraldehyde and GroELx was in two stacks of homo-heptamer subunits. On the other hand, GroESx and GroELx proteins in a solution could not be cross-linked even after incubation for 3 h in 0.5% glutaraldehyde. GroELx was stable at 4-37$^{\circ}C$. In the presence of both GroESx and ATP, GroELx$_{14}$ was stable at 37$^{\circ}C$ but not at 4$^{\circ}C$ or 24$^{\circ}C$. Thus, we confirmed the oligomeric properties of GroESx$_{7}$ and GroELx$_{14}$ and their stability to heat and in the interaction with GroESx.x.