• Title/Summary/Keyword: Cross-Coupling Effect

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Effect of Phenolic Mediators and Humic Acid on the Removal of 1-Indanone Using Manganese Oxide (망간산화물(Birnessite)을 이용한 1- Indanone 제거 시 페놀계 반응매개체와 휴믹산(HA) 영향 평가)

  • Choi, Chan-Kyu;Eom, Won-Suk;Shin, Hyun-Sang
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.7
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    • pp.445-453
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    • 2012
  • An investigation for removal of 1-indanone (1-ID), which were commonly produced from the biological and/or chemical treatment and natural weathering of the PAHs-contaminated soils, via oxidative transformation mediated by birnessite in the presence of various phenolic mediators is described. This study also examines the potential effect of the natural occurring substance humic acid (HA) on the oxidative transformation. The experiment was carried out in aqueous phase as a batch test (10 mg/L 1-ID, 0.3 mM phenolic mediators, $1.0g/L\;{\delta}-MnO_2$, at pH 5). All of the 11 tested phenoilic mediators belong to the group of natural occurring phenols and are widely used as model constituents of humic substances. From the results of HPLC analysis, it is demonstrated that 1-ID was not reactive to birnessite itself, but it can be effectively removed in birnessite-mediated cross coupling reactions in the presence of the phenolic mediators. The percent removals of 1-ID after 2 day incubation were ranged from 9.2 to 71.2% depending on the phenolic mediators applied. The initial rate constant ($K_{int}$, $hr^{-1}$) values for the 1-ID removals obtained from the pseudo-first-order kinetic plots also widely ranged from 0.18 to 15.0. Results of the correlative analysis between the removal efficiencies and structural characteristics of phenolic mediators indicate that the transformation of the 1-ID was considerably enhanced by the addition of electron-donating substituents (e.g., -OH, $-OCH_3$) at the benzne ring, and much less enhanced by the addition of electron-withdrawing substituents (e.g., -COOH, -CHO). The presence of HA showed that removal efficiencies of 1-ID in the birnessite-phenolic mediator systems decreased with increasing HA concentrations. However at low concentration of HA (< 2 mg/L), it caused some enhancement in the removals of 1-ID as compared to the control.

Study on Mixing Condition of the Rubber Composite Containing Functionalized S-SBR, Silica and Silane : II. Effect of Mixing Temperature and Time (변성 S-SBR Silica-Silane 고무복합체의 배합조건에 대한 연구 : II. 배합온도와 시간의 영향)

  • Jang, Suk-Hee;Kim, Wook-Soo;Kang, Yong-Gu;Han, Min-Hyun;Chang, Sang-Mok
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.103-113
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    • 2013
  • The properties of the rubber composites containing a silane and silica were evaluated by changing the mixing time and temperature, in order to find the optimum mixing conditions. Characteristics of the compounds were evaluated after mixing at $120^{\circ}C$, $140^{\circ}C$, and $160^{\circ}C$ with various mixing time. With increasing of mixing time, mooney viscosity decreased while the bound rubber contents of the compounds increased. Viscosity rise by increased mixing time was bigger at low temperature and the higher the mixing temperature the faster in the formation of bound rubber. With lower mixing temperature of $120^{\circ}C$, cross-linking rate was almost constant. Dynamic viscoelastic properties and dispersity of the compound showed that dispersion of ingredients and reaction was not sufficient with the mixing time of less than 10min. On the contrary, with high temperature, it was obvious that good dynamic and physical properties could be obtained due to sufficient coupling reaction, however it was thought this high temperature is not optimum because of sensitive cross-linking rate and physical properties and excessive formation of bound rubber. Consequently, it was confirmed that the mixing condition of 10min at $140^{\circ}C$ was optimum for the silane coupling reaction and dispersion of functionalized S-SBR containing silica and silane.

Experimental investigation of SRHSC columns under biaxial loading

  • Wang, Peng;Shi, Qing X.;Wang, Feng;Wang, Qiu W.
    • Earthquakes and Structures
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    • v.13 no.5
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    • pp.485-496
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    • 2017
  • The behavior of 8 steel reinforced high-strength concrete (SRHSC) columns, which comprised of four identical columns with cross-shaped steel and other four identical columns with square steel tube, was investigated experimentally under cyclic uniaxial and biaxial loading independently. The influence of steel configuration and loading path on the global behavior of SRHSC columns in terms of failure process, hysteretic characteristics, stiffness degradation and ductility were investigated and discussed, as well as stress level of the longitudinal and transverse reinforcing bars and steel. The research results indicate that with a same steel ratio deformation capacity of steel reinforced concrete columns with a square steel tube is better than the one with a cross-shaped steel. Loading path affects hysteretic characteristics of the specimens significantly. Under asymmetrical loading path, hysteretic characteristics of the specimens are also asymmetry. Compared with specimens under unidirectional loading, specimens subjected to bidirectional loading have poor carrying capacity, fast stiffness degradation, small yielding displacement, poor ductility and small ultimate failure drift. It also demonstrates that loading paths affect the deformation capacity or deformation performance significantly. Longitudinal reinforcement yielding occurs before the peak load is attained, while steel yielding occurs at the peak load. During later displacement loading, strain of longitudinal and transverse reinforcing bars and steel of specimens under biaxial loading increased faster than those of specimens subjected to unidirectional loading. Therefore, the bidirectional loading path has great influence on the seismic performance such as carrying capacity and deformation performance, which should be paid more attentions in structure design.

Fabrication of High Speed Optical Matrix Wwitch by Ti:Ti:LiNbO3 (Ti:Ti:LiNbO3를 이용한 초고속 광 매트릭스 스위치 제조)

  • Yang, U-Seok;Kwak, Yong-Seok;Kim, Je-Min;Yoon, Hyeong-Do;Lee, Han-Yeong;Yoon, Dae-Ho
    • Korean Journal of Materials Research
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    • v.12 no.4
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    • pp.254-258
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    • 2002
  • To realize channel cross-connecting in optical communications systems, a high speed optical matrix switch was fabricated using z-cut $LiNbO_3$. For switch fabrication was design bending structure and coupling length and four $2{\times}2$ directional couplers were integrated on one substrate far construction of a $4{\times}4$ switch. Single-mode optical waveguides were formed by Ti-diffusion at a wet $O_2$ atmosphere. Ti-diffusion profile, refractive index variation and waveguide morphology were analyzed by Prism coupler and optical microscopy, respectively.

Decoupling Vector Control for a High-Speed Synchronous Reluctance Motor (고속 동기 릴럭턴스 전동기의 비간섭 벡터제어)

  • 백동기;성세진
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.12 no.4
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    • pp.128-135
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    • 1998
  • In the high speed range for salient type synchronous reluctance motor, the effect of iron loss can not be negligible. In this paper, under he assumption that stator iron loss is generated from the equivalent eddy current in the stator, we derive the voltage equations including iron loss from the model that is added the equivalent iron loss in the equivalent inductance in series. The variation of iron loss is dependent on the increase of the operating frequency change for he worse a performance of the vector control system. As there is cross coupling between the d and q axes, it is hard to apply the vector control to the proposed model. Hence, we propose a decoupling current controller for including the effects of iron loss, And we show that the proposed vector control scheme achieves the desired performances through simulation results.

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On the free vibration response of laminated composite plates via FEM

  • Sehoul, Mohammed;Benguediab, Soumia;Benguediab, Mohamed;Selim, Mahmoud M.;Bourada, Fouad;Tounsi, Abdelouahed;Hussain, Muzamal
    • Steel and Composite Structures
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    • v.39 no.2
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    • pp.149-158
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    • 2021
  • In this research paper, the free vibrational response of laminated composite plates is investigated using a non-polynomial refined shear deformation theory (NP-RSDT). The most interesting feature of this theory is the parabolic distribution of transverse shear deformations while ensuring the conditions of nullity of shear stresses at the free surfaces of the plate without requiring the Shear correction factor "Ks". A fourth-nodded isoparametric element with four degrees of freedom per node is employed for laminated composite plates. The numerical analysis of simply supported square anti-symmetric cross-ply and angle-ply laminated plate is carried out using a special discretization based on four-node finite element method which four degrees of freedom per node. Several numerical results are presented to show the effect of the coupling parameters of the plate such as the modulus ratios, the thickness ratio and the plate layers number on adimensional eigen frequencies. All numerical results presented using the current finite element method (FEM) is presented in 3D curve form.

Study on Property Modification with Polymer Compositions in the Manufacture of Compounds for Cable Sheath

  • Li, Xiang Xu;Lee, Sang Bong;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.220-224
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    • 2019
  • Herein, three polymer compounds were manufactured using three polymer combination methods, ethylene-vinyl acetate/ethylene-propylene-diene-copolymer (EPDM), ethylene-vinyl acetate (EVA)/polyethylene-A (PE-A; density: 0.870), and ethylene-vinyl acetate (EVA)/polyethylene-B (PE-B; density: 0.885), for making cable sheath for use in the shipping industry. In this study, EVA, EPDM, PE-A, and PE-B were used as matrix polymers, and EVA-grafted maleic anhydride was used as a coupling agent for compounding with various compounds such as a fire retardant, cross-linking agent, filler, and other additives, besides the plasticizer. ${\Delta}T$, Mooney viscosity, and tensile strength increased in order of EPDM < PE-A < PE-B, the probable reason is due to the different crosslinking effect. The three compounds showed similar results for fire resistance and aging resistance after compounding process, but they showed excellent cold resistance owing to the non-polarity of the polymers and sufficient plasticizer content.

Investigating the effect of edge crack on the modal properties of composite wing using dynamic stiffness matrix

  • Torabi, Ali Reza;Shams, Shahrokh;Fatehi-Narab, Mahdi
    • Steel and Composite Structures
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    • v.39 no.5
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    • pp.543-564
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    • 2021
  • In this study free vibration analysis of a cracked Goland composite wing is investigated. The wing is modelled as a cantilevered beam based on Euler- Bernoulli equations. Also, composite material is modelled based on lamina fiber-reinforced. Edge crack is modelled by additional boundary conditions and local flexibility matrix in crack location, Castigliano's theorem and energy release rate formulation. Governing differential equations are extracted by Hamilton's principle. Using the separation of variables method, general solution in the normalized form for bending and torsion deflection is achieved then expressions for the cross-sectional rotation, the bending moment, the shear force and the torsional moment for the cantilevered beam are obtained. The cracked beam is modelled by separation of beam into two interconnected intact beams. Free vibration analysis of the beam is performed by applying boundary conditions at the fixed end, the free end, continuity conditions in the crack location of the beam and dynamic stiffness matrix determinant. Also, the effects of various parameters such as length and location of crack and fiber angle on natural frequencies and mode shapes are studied. Modal analysis results illustrate that natural frequencies and mode shapes are affected by depth and location of edge crack and coupling parameter.

Vortex-induced vibration characteristics of multi-mode and spanwise waveform about flexible pipe subject to shear flow

  • Bao, Jian;Chen, Zheng-Shou
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.13 no.1
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    • pp.163-177
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    • 2021
  • Numerical simulations of the Vortex-Induced Vibration (VIV) about a large-scale flexible pipe subject to shear flow were carried out in this paper. Efficiency verification was performed firstly, validating that the proposed fluid-structure interaction solution strategy is competent in predicting the VIV response. Then, the VIV characteristics related to multi-mode and spanwise hybrid waveform about the flexible pipe attributed to shear flow were investigated. When inflow velocity rises, higher vibration modes are apt to be excited, and the spanwise waveform easily convertes from a standing-wave-dominated status to a hybrid standing-traveling wave status. The multi-mode or even multiple-dominant-mode is prone to occur, that is, the dominant mode is often followed by several apparent subordinate modes with considerable vibration energy. Hence, the shedding frequencies no longer obey Strouhal law, and vibration trajectories become intricate. According to the motion analysis concerning the coupled cross-flow and in-line vibrations, as well as the corresponding wake patterns, a tight coupling interaction exists between the structural deformation and the wake flow behind the flexible pipe. In addition, the evolution of the vortex tube along the pipe span and a strong 3D effect are observed due to the slenderness of the flexible pipe and the variability of the vortex shedding attributed to the shear flow.

Nonlinear Finite Element Analysis of Reinforced Concrete Column using Timoshenko Beam Theory and Fiber Section Model (Timoshenko보 이론 및 층상화 단면모델을 이용한 RC 기둥의 비선형 유한요소해석)

  • Park, Soon Eung;Park, Moon Ho;Kwon, Min Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.4A
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    • pp.577-585
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    • 2006
  • In this research, nonlinear Timoshenko beam element that is able to capture nonlinear shear deformation is developed. The proposed model shows more reasonable prediction than Bernoulli beam theory in short columns or strong shear column due to the consideration of shear deformation. The cross-section is modeled as fiber approach. Since the model is based on the fiber approach for section discretization, the plastic progress of the section can be traced and the coupling effect of the axial and flexural response. The developed element is implemented into the finite element program to analysis general reinforced concrete structures. As parametric study, reinforced concrete columns are analyzed and compared with experimental results, analyzed the property of behavior for reinforced concrete columns.