• Applied Microscopy
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• 제46권2호
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• pp.105-109
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• 2016

Palladium has been used as a catalyst not only in Suzuki and Heck cross coupling reaction in organic chemistry, but also in automobile industry for the reduction of vehicle exhausts. The catalytic activity of Pd nanoparticles depends strongly on their size and exposed crystalline facets. In this study, the single crystalline palladium nanocubes/nanorods were prepared in the presence of polyvinyl pyrrolidone (PVP) and potassium bromide (KBr) using the polyol method. Selected area diffraction pattern and high-resolution transmission electron microscopy (TEM) were performed by TEM. The result shows that the ratio of KBr/PVP is the key factor to determine whether the product is cubes or rods. The as-prepared Pd nanocubes were highly uniform in both size and shape. The ordered packing structures including monolayer and multilayer can be fabricated via the rate-controlled evaporation of solution solvent. The catalytic activity of these Pd nanocubes towards heck reaction of iodobenzene with acrylate or acrylic acid was found to be higher than that of Pd nanorods. We suspect it is caused by the difference of energy state while Pd nanocubes is {100} plane and nanorods is {111} plane.

• Nuclear Engineering and Technology
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• 제46권2호
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• pp.263-272
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• 2014

Scattering source calculations using conventional spherical harmonic expansion may require lots of computation time to treat full-coupled three-dimensional photon-electron transport in a highly anisotropic scattering medium where their scattering cross sections should be expanded with very high order (e.g., $P_7$ or higher) Legendre expansions. In this paper, we introduce a modified scattering kernel approach to avoid the unnecessarily repeated calculations involved with the scattering source calculation, and used it with parallel computing to effectively reduce the computation time. Its computational efficiency was tested for three-dimensional full-coupled photon-electron transport problems using our computer program which solves the multi-group discrete ordinates transport equation by using the discontinuous finite element method with unstructured tetrahedral meshes for complicated geometrical problems. The numerical tests show that we can improve speed up to 17~42 times for the elapsed time per iteration using the modified scattering kernel, not only in the single CPU calculation but also in the parallel computing with several CPUs.

• Bulletin of the Korean Chemical Society
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• 제34권4호
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• pp.1127-1130
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• 2013

Formation of the monodisperse submicrospheres consisting of ionic palladium(II) complexes, $[(Me_4en)Pd(L)]_2(X)_4$($Me_4en$ = N,N,N',N'-tetramethylethylenediamine; L = bis(4-(4-pyridylcarboxyl)phenyl)methane; $X^-=BF_4{^-}$ and $ClO_4{^-}$), has been carried out without any templates or additives. The submicrospheres were coated with silicates, and then calcined in air at $550^{\circ}C$ for 1 h, to efficiently form hollow-spherical $SiO_2$ submicro-reactors dotted with palladium(0) nanoparticles (PdNPs). That is, the submicrospheres act as both a template and a source of the palladium metal nanoparticles. The submicro-reactors containing nano-catalysts have been characterized by means of SEM, TEM, and XPS. Notably, the reactors were proved to be very effective for Suzuki-Miyaura cross-coupling and hydrogenation reactions.

• 대한기계학회논문집
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• 제16권12호
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• pp.2306-2314
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• 1992

본 연구에서는 Lagrangian 방정식을 이용해 알루미늄, CFRP, GFRP, BFRP 등으 로 혼합적층된 cross-ply 사각판에 대해 굽힘-신장연성을 고려하여 Runge-Kutta Gill 법을 적용하여 수치적으로 비선형진동해석을 수행하였다.그리고 여러가지 적층방법 에 따라 비선형 진동에 어떠한 영향이 미치는가를 검토하였으며, 형상비(a/b), 모우드 의 변화 그리고 탄성계수비에 따른 비선형진동 거동을 규명하였다. 한편, 기본진동 수에 대해서는 상용 유한요소프로그램인 ABAQUS의 결과와 비교하였으며, 단일 적층된 판의 비선형진동거동에 대해서는 Singh의 결과와 비교 검토하였다.

• Journal of electromagnetic engineering and science
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• 제10권4호
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• pp.276-281
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• 2010

In this paper, an electromagnetic induction on a telecommunication line by the distribution line of a power provision system or a feeder line of an electrified railway system has been verified through experiments. The basic cause of induction occurrence by these practical power provision systems is the returning current through the earth. This principle has been confirmed by the experiments documented in this paper which implemented these mechanisms to incur an induction. Experimental methods were used to produce the returning current through the earth. The experiment to find a relationship between inducing strength and the distance between the two phase lines in a power provision line has also been included to confirm that, when the distance is enlarged, the induction effect increases as the cross-nullification effect of magnetic fluxes decreases. An experiment for the existence of a shielding effect by another conduction length material has been addedas a protection measure against the induction.

• Journal of Power Electronics
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• 제16권3호
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• pp.1176-1189
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• 2016

In this paper, a novel quasi-direct power control (Q-DPC) scheme based on a resonant frequency adaptive proportional-resonant (PR) current controller with a variable frequency resonant phase locked loop (RPLL) is proposed, which can achieve a fast power response with a unity power factor. It can also adapt to variations of the generator frequency in T-type Three-level shaft synchronous generator (SSG) converters. The PR controller under the static α-β frame is designed to track ac signals and to avert the strong cross coupling under the rotating d-q frame. The fundamental frequency can be precisely acquired by a RPLL from the generator terminal voltage which is distorted by harmonics. Thus, the resonant frequency of the PR controller can be confirmed exactly with optimized performance. Based on an instantaneous power balance, the load power feed-forward is added to the power command to improve the anti-disturbance performance of the dc-link. Simulations based on MATLAB/Simulink and experimental results obtained from a 75kW prototype validate the correctness and effectiveness of the proposed control scheme.

• Structural Engineering and Mechanics
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• 제62권4호
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• pp.465-475
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• 2017

Photovoltaic (PV) panels are used in high-rise buildings to convert solar energy to electricity. Due to the considerable energy consumption of high-rise buildings, applying PV technology is of great significance to energy saving. In the application of PV panels, one of the most important construction issues is the connection of the PV panel with the main structures. One major difficulty of the connection design is that the PV panel connection consists of two separate components with coupling and indeterminate dimension. In this paper, the gap element is employed in these two separated but coupled components, i.e., hook and catch. Topology optimization is applied to optimize and design the cross-section of the PV panel connection. Pareto optimization is conducted to operate the optimization subject to multiple load scenarios. The initial design for the topology optimization is determined by the common design specified by the Technical Code for Glass Curtain Wall Engineering (JGJ 102-2003). Gravity and wind load scenarios are considered for the optimization and numerical analysis. Post analysis is conducted for the optimal design obtained by the topology optimization due to the manufactory requirements. Generally, compared with the conventional design, the optimized connector reduces material use with improved structural characteristics.

• 지구물리와물리탐사
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• 제13권4호
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• pp.330-335
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• 2010

시추공 주시 토모그래피에 의하여 도출된 속도 영상의 신뢰도 평가를 위하여 파선-속도격자의 결합도와 시스템 행렬의 역산 특성 분석에 대한 연구를 실시하였다. 분석 대상은 SIRT법에 의하여 도출된 속도 모델과 이를 도출한 초동 주시와 파선 정보이다. 파선-속도격자 결합도는 파선 밀도 즉 격자 당 투사 파선 수와 파선 선분들의 합으로 산출하였고, 도출된 속도모델의 분해능 및 불확실성에 대한 정보는 데이터 공간(초동주시)과 모델 공간(속도모델)을 관련짓는 시스템 행렬의 특이 값 분해로부터 도출하였다.

• Smart Structures and Systems
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• 제17권1호
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• pp.31-43
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• 2016

Applications of ultrasonic tomography to concrete structures have been reported for many years. However, practical and effective application of this tool for nondestructive assessment of internal concrete condition is hampered by time consuming transducer coupling that limits the amount of ultrasonic data that can be collected. This research aims to deploy recent developments in air-coupled ultrasonic measurements of solids, described in Part 1 of this paper set, to concrete in order to image internal inclusions. Ultrasonic signals are collected from concrete samples using a fully air-coupled (contactless) test configuration. These air coupled data are compared to those collected using partial semi-contact and full-contact test configurations. Two samples are considered: a 150 mm diameter cylinder with an internal circular void and a prism with $300mm{\times}300mm$ square cross-section that contains internal damaged regions and embedded reinforcement. The heterogeneous nature of concrete material structure complicates the application and interpretation of ultrasonic measurements and imaging. Volumetric inclusions within the concrete specimens are identified in the constructed velocity tomograms, but wave scattering at internal interfaces of the concrete disrupts the images. This disruption reduces defect detection accuracy as compared with tomograms built up of data collected from homogeneous solid samples (PVC) that are described in Part 1 of this paper set. Semi-contact measurements provide some improvement in accuracy through higher signal-to-noise ratio while still allowing for reasonably rapid data collection.

• Nuclear Engineering and Technology
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• 제49권1호
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• pp.82-91
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• 2017

Liquid alloy systems have a high degree of thermal conductivity, far superior to ordinary nonmetallic liquids and inherent high densities and electrical conductivities. This results in the use of these materials for specific heat conducting and dissipation applications for the nuclear and space sectors. Uniquely, they can be used to conduct heat and electricity between nonmetallic and metallic surfaces. The motion of liquid metals in strong magnetic fields generally induces electric currents, which, while interacting with the magnetic field, produce electromagnetic forces. Electromagnetic pumps exploit the fact that liquid metals are conducting fluids capable of carrying currents, which is a source of electromagnetic fields useful for pumping and diagnostics. The coupling between the electromagnetics and thermo-fluid mechanical phenomena and the determination of its geometry and electrical configuration, gives rise to complex engineering magnetohydrodynamics problems. The development of tools to model, characterize, design, and build liquid metal thermomagnetic systems for space, nuclear, and industrial applications are of primordial importance and represent a cross-cutting technology that can provide unique design and development capabilities as well as a better understanding of the physics behind the magneto-hydrodynamics of liquid metals. First studies for the development of computational tools for the design of liquid metal electromagnetic pumps are discussed.