• Journal of Korea Technical Association of The Pulp and Paper Industry
• /
• v.34 no.5
• /
• pp.1-17
• /
• 2002

The immobilization and consolidation of the model coatings based on the plastic pigment and latex binder of known particle sizes were theoretically Studied in terms of the dense random packing of binary spheres and varying extent of latex film shrinkage. The porosity of the model coatings was calculated based on three proposed latex shrinkage models: Maximum, Minimum, and Linearly Decreasing Latex Shrinkage. The increasing extent of latex shrinkage was calculated up to the critical pigment volume concentration(CPVC) as a function of plastic pigment volume fractions, and the maximum latex shrinkage was estimated from the CPVC. Also, the number of pores and the average equivalent spherical pore diameters were calculated based on those proposed models. The opacity and gloss of the model coatings on polyester films were measured and their porosity was also determined by a simple coat weight-thickness method. As expected, various coating structure-property-composition relationships, such as opacity, gloss, porosity, etc., were shown to exhibit sharp transitions near the CPVC. The CPVC values determined by the opacity, gloss, and porosity vs. PVC relationships, respectively, agreed very well with each other. Especially, the CPVC's determined by the opacity and porosity vs. PVC curves were identical. The comparison between the theoretically calculated and experimental porosity values showed that the intermediate value between the maximum and minimum latex shrinkage would best fit the experimental porosity data. The effect of plastic pigment particle size on the optical properties and porosity of model coatings was also studied and it was observed that the coating opacity and porosity increased with increasing plastic pigment particle size, but the gloss decreased. The ink gloss of the uncalendered model coatings applied onto commercial sheet offset coated papers was shown to be affected by both the coating gloss and porosity: the higher the coating gloss, the higher the ink gloss, but the higher the coating porosity, the lower the ink gloss. Their printability was also studied in terms of the number of passes-to-fail and the rate of ink setting as a function of both plastic pigment volume fractions and plastic pigment particle sizes. A minimum crack-free temperature(MCR) of latex-bound coatings was proposed to better predict the behaviors of latexes as coating binders. The wet state of model coating dispersions, the surfaces of consolidated model coatings, and their internal structure were examined by both electron and atomic force microscopy, and their micrographs were found to be consistent with our immobilization and consolidation models.

• Applied Chemistry for Engineering
• /
• v.18 no.3
• /
• pp.267-272
• /
• 2007

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the trimethyltetradecylammonium bromide (TTAB) with the polyoxyethylene (23) lauryl ether (Brij 35) at $25^{\circ}C$ in water and in aqueous solutions of n-butanol (0.1 M, 0.2 M, and 0.3 M) were determined as a function of ${\alpha}_1$ (the overall mole fraction of TTAB) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters ($X_i$, ${\gamma}_i$, $C_i$, ${a_i}^M$, ${\beta}$, and ${\Delta}H_{mix}$) were calculated by means of the equations derived from the nonideal mixed micellar model. The effects of n-butanol on the micellization of TTAB/Brij 35 mixtures have been also studied by analyzing the measured and calculated thermodynamic parameters.

• Journal of the Korean Chemical Society
• /
• v.50 no.5
• /
• pp.355-361
• /
• 2006

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the sodium dodecylbenzenesulfonate (DBS) with the polyoxyethylene(23) lauryl ether (Brij 35) at 25oC in water and aqueous solutions of n-butanol (0.1M, 0.2M, and 0.3M) were determined as a function of a1 (the overall mole fraction of DBS) by the use of electric conductivity method and surface tensiometer method. Various thermodynamic parameters (Xi, i, Ci, aiM, , and Hmix) were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the micellization of the DBS/Brij 35 mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters.

• Wind and Structures
• /
• v.10 no.1
• /
• pp.1-22
• /
• 2007

The suppression of aerodynamic response of long-span suspension bridges during erection and after completion by using single TMD and multi TMD is presented in this paper. An advanced finite-element-based aerodynamic model that can be used to analyze both flutter instability and buffeting response in the time domain is also proposed. The frequency-dependent flutter derivatives are transferred into a time-dependent rational function, through which the coupling effects of three-dimensional aerodynamic motions under gusty winds can be accurately considered. The modal damping of a structure-TMD system is analyzed by the state-space approach. The numerical examples are performed on the Akashi Kaikyo Bridge with a main span of 1990 m. The bridge is idealized by a three-dimensional finite-element model consisting of 681 nodes. The results show that when the wind velocity is low, about 20 m/s, the multi TMD type 1 (the vertical and horizontal TMD with 1% mass ratio in each direction together with the torsional TMD with ratio of 1% mass moment of inertia) can significantly reduce the buffeting response in vertical, horizontal and torsional directions by 8.6-13%. When the wind velocity increases to 40 m/s, the control efficiency of a multi TMD in reducing the torsional buffeting response increases greatly to 28%. However, its control efficiency in the vertical and horizontal directions reduces. The results also indicate that the critical wind velocity for flutter instability during erection is significantly lower than that of the completed bridge. By pylon-to-midspan configuration, the minimum critical wind velocity of 57.70 m/s occurs at stage of 85% deck completion.

• Journal of the Korean Chemical Society
• /
• v.48 no.3
• /
• pp.236-242
• /
• 2004

The critical micelle concentration (CMC) and the counterion binding constant (B) in a mixed micellar state of the Dodecylpyridinium chloride (DPC) with the Cetyldimethylethylammonium bromide (CDEAB) at 25$^{\circ}C$ in aqueous solutions of n-butanol were determined as a function of ${\alpha}_1$ (the overall mole fraction of DPC) by the use of electric conductivity method. Various thermodynamic parameters (($X_i,\;{\gamma}_i,\;C_i,\;a^M_i,\;{\beta},\;and {\Delta}H_{mix})$were calculated by means of the equations derived from the nonideal mixed micellar model. The effect of n-butanol on the mixed micellization of the DPC/CDEAB mixtures has been also studied by analyzing the measured and calculated thermodynamic parameters (CMC, B 및 $;{\Delta}G_o\;^m$).

• Journal of the Korean Geotechnical Society
• /
• v.25 no.9
• /
• pp.77-92
• /
• 2009

In the present paper, a numerical study was carried out for a reasonable and realistic evaluation of tension loads in piles during deep excavation in Singapore soft soil applying pile-plugged jet grouted slab. Based on 2-dimensional finite element analyses using linear elastic-perfectly plastic soil model obeying Mohr-Coulomb failure criterion, effects of pile-plugged jet grouted slab on the stability during excavation were examined, and a parametric study was also conducted to investigate critical influencing parameters in the estimation of reliable pile tension loads. Finally, based on the Modified Cam-Clay model, pile tension loads were estimated by considering on-going consolidation state of the Singapore clay deposit and the range of critical parameters observed during laboratory tests.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2022.05a
• /
• pp.516-516
• /
• 2022

Agricultural reservoirs are critical water resources structures to ensure continuous water supplies for rice cultivation in Korea. Climate change has increased the risk of reservoir failure by exacerbating discrepancies in upstream runoff generation, downstream irrigation water demands, and evaporation losses. In this study, the variations in water balance components of 400 major reservoirs during 1973-2017 were examined to identify the reservoirs with reliable storage capacities and resilience. A conceptual lumped hydrological model was used to transform the incident rainfall into the inflows entering the reservoirs and the paddy water balance model was used to estimate the irrigation water demand. Historical climate data analysis showed a sharp warming gradient during the last 45 years that was particularly evident in the central and southern regions of the country, which were also the main agricultural areas with high reservoir density. We noted a country-wide progressive increase in average annual cumulative rainfall, but the forcing mechanism of the rainfall increment and its spatial-temporal trends were not fully understood. Climate warming resulted in a significant increase in irrigation water demand, while heavy rains increased runoff generation in the reservoir watersheds. Most reservoirs had reliable storage capacities to meet the demands of a 10-year return frequency drought but the resilience of reservoirs gradually declined over time. This suggests that the recovery time of reservoirs from the failure state had increased which also signifies that the duration of the dry season has been prolonged while the wet season has become shorter and/or more intense. The watershed-irrigated area ratio (W-I_ratio) was critical and the results showed that a slight disruption in reservoir water balance under the influence of future climate change would seriously compromise the performance of reservoirs with W-I_ratio< 5.

• Proceedings of the Korean Institute Of Construction Engineering and Management
• /
• 2004.11a
• /
• pp.526-530
• /
• 2004

The portion of plant industry has increased within construction market. In spite of plant industry is dynamic field which leads state-of-the-art and creates a value, phased information management and knowledge intensive business accomplishment are insufficient. Henceforth plant is expected to demand increment of industrial project from hereafter international plant industry market. The continuous plan technique and know-how accumulation are urgent from domestic. 1'his research analyzes the areas in which domestic plant industry is insufficient and then elicits project management key success factors from current operation process. In addition, this research compares domestic plant level with overseas plant level. This study establishes work models for critical work phases based on the analysis of domestic plant technical level.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.23 no.7
• /
• pp.911-917
• /
• 1999

The sonic nozzle is widely used as reference device for calibrating flowmeters In gas flow measurement and its use requires the Critical Flow Factor(CFF) based on the thermodynamic properties of the gas at the nozzle throat. ISO-9300 provides the calculating method of the factor. But since the CFF from this method show an error over ${\pm}0.5%$ In specific conditions and of ${\pm}0.1{\sim}{\pm}0.2%$ in common Natural Gas(NG) custody transfer condition. this method cannot be applied for gas flow measurement with sonic nozzle. Each research bodies or organizations of the world have joined in order to calculate the CFF more accurately. They have performed these works using their own method and compared the results with each other under the management of ISO. KOGAS have joined those works, because the high-pressure natural gas flow calibration facility of KOGAS will be constructed in late 1999, and then had necessities to calculate a CFF accurately. The calculation method of KOGAS was using the equation of state from AGA-8('94), high accuracy model of ideal gas properties and the solutions of thermodynamic equations. The evaluation results have had a very good consistency within ${\pm}0.05%$ in most NO custody transfer conditions compared to the speed of sound for methane and also shown that the CFF was within ${\pm}0.1%$ compared to the results of other works of the world.

• Research in Mathematical Education
• /
• v.23 no.3
• /
• pp.149-164
• /
• 2020

This study aimed to establish an observation protocol for mathematical modeling as an alternative way to examine instructional alignment to the Common Core State Standards for Mathematics. The instructional alignment observation protocol (IAOP) for mathematical modeling was established through careful reviews on the fidelity of implementation (FOI) framework and prior studies on mathematical modeling. I shared the initial version of the IAOP including 15 items across the structural and instructional critical components as the FOI framework suggested. Thus, the IAOP covers what teachers should do and know for practices of mathematical modeling in classrooms and what teachers and students are expected to do. Based on the findings in this study, validity and reliability of the IAOP should be evaluated in follow-up studies.