• Title/Summary/Keyword: Critical potential

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On the Size of Quantum Dots with Bound Hydrogenic Impurity States

  • Sun, Ho-Sung
    • Bulletin of the Korean Chemical Society
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    • v.30 no.2
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    • pp.315-318
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    • 2009
  • Some particular bound state energies of an electron, under Coulomb potential field, confined in a two-dimensional circle and a three-dimensional sphere are analytically derived. The derivation shows that the electron cannot be bound in a negative energy state when the circle (or sphere) is smaller than a certain critical size. The critical size dependency on the strength of Coulomb potential and the angular momentum of the electron is also analytically derived. This system mimics quantum dots. Therefore the derivation provides new information on a minimum critical size of quantum dots with hydrogenic impurity.

Redox Reaction on Polarization Curve Variations of Polymer with Enzymes

  • Park, Chil-Nam
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.3
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    • pp.165-171
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    • 2000
  • Experiments were carried out to measure variations in the oxidation potential and current density using the polarization curves of polycarbonate. The results were then examined to identify the influences affecting the oxidation potential related to various conditions, such as temperature, pH, and oxydase(citrate and lipase). The lines representing the active anodic and cathodic dissolution shifted only slightly in the potential direction relative to temperature, pH, and the effect of the enzyme. The Tafel slope for the anodic and cathodic dissolution was determined such that the reversibility polarization was indicated as being effected by various conditions. The slope of the polarization curves describing the active-to-passive transition region shifted noticeably in their direction. Also, by varying the conditions, the optimum conditions for the most ready transform were identified, including temperature, pH, oxidation rate, and resistance of oxidation potential. The critical oxidation sensitivity(I(sub)r/I(sub)f) of the anodic current density peak and maximum passive current density was also determined, which is used in measuring the critical corrosion sensitivity of a polycarbonate.

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Influence of Redox Potential Current Density on Polarization Curves with Polypropylene Polymer

  • Park, Chil-Nam;Kim, Myung-Sun
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.4
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    • pp.255-261
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    • 2000
  • Experiments were carried out to measure the corrosion potential and current density variations in the polarization curves of polypropylene. In particular, the results were examined to identify those influences affecting the corrosion potential, such as temperature, pH, salt, and oxygen. The Tafel slope for the anodic dissolution was determined based on the polarization effect under various conditions. Furthermore, the optimum conditions for the most rapid transformation were establish based on a variety of conditions, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(I(sub)r/I(sub)f). This I(sub)r/I(sub)f value was then used to measure the critical corrosion sensitivity of polypropylene. The potentiodynamic parameters of corrosion were obtained using a Tafel plot.

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EXISTENCE OF THE SOLUTIONS FOR THE SINGULAR POTENTIAL ELLIPTIC SYSTEM

  • Jung, Tacksun;Choi, Q-Heung
    • Korean Journal of Mathematics
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    • v.20 no.1
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    • pp.107-116
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    • 2012
  • We investigate the multiple solutions for a class of the elliptic system with the singular potential nonlinearity. We obtain a theorem which shows the existence of the solution for a class of the elliptic system with singular potential nonlinearity and Dirichlet boundary condition. We obtain this result by using variational method and critical point theory.

Influence of Corrosion Potential and Current Density on Polarization Curve Variations using Polycarbonate[III]

  • Park, Chil-Nam;Yang, Hyo-Kyung;Kim, Sun-Kyu;Kim, Myung-Sun;Cheong, Kyung-Hoon
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.4 no.1
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    • pp.43-50
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    • 2000
  • In this study, experiments were carried out to measure the variations in the corrosion potential and current density of polarization curves using polycarbonate. The results were particularly examined to identify the influences affecting the corrosion potential including various conditions such as temperature, pH, catalytic enzyme, and salt. The lines representing the active anodic dissolution were only slightly shifted in the potential direction by temperature, pH, enzyme, and salt. The tafel slope for the anodic dissolution was determined based on the polarization effect with various conditions. The slope of the polarization curves describing the active-to-passive transition region were noticeably shifted in direction. Also, from the variation in the conditions, the optimum conditions were established for the most rapid transformation, including temperature, pH, corrosion rate, and resistance of corrosion potential. The second anodic current density peak and maximum passive current density were designated as the critical corrosion sensitivity(Ir/If). The value of Ir/If was then used in measuring the extent of the critical corrosion sensitivity of the polycarbonate. The potentiodynamic parameters of the corrosion were obtained using a Tafel plot.

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Determination of Critical Chloride Content of Ordinary Portland Cement Concrete by Linear Polarization Technique (선형분극법을 이용한 보통프틀랜드시멘트 콘크리트의 임계염화물량)

  • Kim, Hong-Sam;Cheong, Hai-Moon;Ahn, Tae-Song
    • Journal of the Korean Ceramic Society
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    • v.44 no.9
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    • pp.524-528
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    • 2007
  • The results of evaluating steel corrosion in concrete containing chloride content of various levels indicated that the more chloride content in concrete leads to the lower potential and higher corrosion current density. However, the open circuit potential of steel varied with time and exposure condition, and the corelation between the open circuit potential and corrosion current density was not obvious. In order to determine the critical threshold content of chloride of steel corrosion in concrete, the concept of average corrosion current density was employed. The range of critical chloride content in portland cement concretes was about $1.56{\sim}1.77%$($Cl^-$, %, wt of cement content) along with water-cement ratio, and higher water-cement ratio resulted in reduction in critical threshold chloride content.

Stability analysis of gas-liquid interface using viscous potential flow (점성포텐셜유동을 이용한 이상유동장의 표면안정성 해석)

  • Kim, Hyung-Jun;Kwon, Se-Jin
    • Proceedings of the KSME Conference
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    • 2007.05b
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    • pp.3033-3038
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    • 2007
  • In this research, Rayleigh instability of gas-liquid flow in annular pipe is studied in film boiling using viscous potential flow. Viscous potential flow is a kind of approximation of gas-liquid interface considering velocity field as potential including viscosity. A dispersion relation is obtained including the effect of heat and mass transfer and viscosity. New expression for dispersion relation in film boiling and critical wave number is obtained. Viscosity and heat and mass transfer have a stabilizing effect on instability and its effect appears in maximum growth rate and critical wave number. And the existence of marginal stability region is shown.

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Measurement of Localized Corrosion Resistance in Additively Manufactured Ti-6Al-4V Alloys Using Electrochemical Critical Localized Corrosion Temperature (E-CLCT) versus Electrochemical Critical Localized Corrosion Potential (E-CLCP) (적층가공 (3D 프린팅) Ti-6Al-4V합금의 국부부식 저항성 평가를 위한 임계국부부식온도와 임계국부부식전위 측정방법의 비교)

  • Seo, Dong-Il;Lee, Jae-Bong
    • Corrosion Science and Technology
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    • v.20 no.1
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    • pp.37-43
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    • 2021
  • Additively manufactured (AM) Ti-6Al-4V alloys exhibit a dominant acicular martensite phase (α'), which is characterized by an unstable energy state and highly localized corrosion susceptibility. Electrochemical critical localized corrosion temperature (E-CLCT, ISO 22910: 2020) and electrochemical critical localized corrosion potential (E-CLCP, ISO AWI 4631: 2021) were measured to analyze the localized corrosion resistance of the AM Ti-6Al-4V alloy. Although E-CLCP was measured under mild corrosive conditions such as human body, the validity of evaluating localized corrosion resistance of AM titanium alloys was demonstrated by comparison with E-CLCT. However, the mechanisms of resistance to localized corrosion on the as-received and heat-treated AM Ti-6Al-4V alloys under E-CLCT and E-CLCP differ at various temperatures because of differences in properties under localized corrosion and repassivation. The E-CLCT is mainly measured for initiation of localized corrosion on the AM titanium alloys based on temperature, whereas the E-CLCP yields repassivation potential of re-generated passive films of AM titanium alloys after breaking down.

Critical Free Surface Flows in a Sloshing Tank

  • Scolan, Y.M
    • Journal of Advanced Research in Ocean Engineering
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    • v.4 no.4
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    • pp.163-173
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    • 2018
  • There are many issues in fluid structure interactions when dealing with the free surface flows in a sloshing tank. For example the problem of how yielding a highly nonlinear wave with a simple forced motion over a short duration is of concern here. Nonlinear waves are generated in a rectangular tank which is forced horizontally; its motion consists of a single cycle of oscillation. One of the objectives is to end up with a shape of the free surface yielding a wide range of critical flows by tuning few parameters. The configuration that is studied here concerns a plunging breaker accompanied with a critical jet where great kinematics are simulated. The numerical simulations are performed with a twodimensional code which solves the fully nonlinear free surface boundary conditions in Potential Theory.