• Journal of the Korean Society of Safety
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• v.7 no.4
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• pp.45-53
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• 1992

Sponataneous ignition characteristics for granulated activated carbon were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 5$^{\circ}C$, 1$0^{\circ}C$ and 15$^{\circ}C$ respectively, and the period in each amplitude was varied at an interval of 30minutes from zero to 3hours. As the results of experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample decreased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank-Kamenetskii's thermal Ignition theory was 38.82［kca1/mo1］ In case of varying the ambient temperature sinusoidally, the critical spontaneous ignition tempera-ture was lower than that at the constant ambient temperature, and the minimum critical spontaneous ignition temperature decreased with the amplitude of heating sinusoidal curve. At the same amplitude, the critical spontaneous ignition temperature decreased until it reached the minimum point and then in-creased as the period increased.

• Journal of the Korean Society of Safety
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• v.7 no.1
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• pp.47-56
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• 1992

Spontaneous ignition charactenstics for fish meal were observed by performing experiments at constant ambient temperature and varying the ambient temperature sinusoidally. As the results of the experiments at a constant ambient temperature, the critical spontaneous ignition temperature of the sample for large, intermediate and small vessels was 170.5$^{\circ}C$, 177.5$^{\circ}C$ and 188.5$^{\circ}C$, respectively. The critical spontaneous ignition temperature decreased as the sample vessel size increased. Apparent activation energy of used fish meal calculated from the Frank-Kamenetskii's thermal ignition theory was 37.60Kcal/mol. In case of varying the ambient temperature sinusoidally, the amplitudes of temperature were 1$0^{\circ}C$, 2$0^{\circ}C$ and 3$0^{\circ}C$ respectively with the period in each amplitude 1hr, 2hrs and 3hrs. The results showed that the critical spontaneous ignition temperatures at the varied amplitudes of temperature were lower than that at the constant anbient temperature and increased as the amplitude increased. At the same amplitude, the critical spontaneous ignition temperature increased with the period.

• Journal of the Korean Society of Safety
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• v.10 no.2
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• pp.84-91
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• 1995

The characteristics of critical spontaneous ignition of granulated activated carbon were investigated In atmospheres of differing oxygen concentration. At the same concentration the larger vessels yielded the lower critical spontaneous ignition temperature. At the same vessel, as the concentration of oxygen was reduced, Ignition occurred later and at higher ambient temperature, and critical spontaneous ignition temperature increased. The apparent activation energy calculated from the Frank-Kamenetskii's ignition theory appeared to be the slight different value respectively and the mean apparent activation energy was 19850㎈/㏖.

• Journal of the Korean Society of Safety
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• v.8 no.3
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• pp.44-49
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• 1993

The spontaneous ignition induction time and temperature distribution were observed by performing experiments for granulated activated carbon. As the results of the experiments at the same amplitude, the critical spontaneous ignition temperature was decreased with increase of the time period, while, the ignition induction time was increased with the increase of the time period. The critical spontaneous ignition temperature was decreased with the increase of the amplitude for the shorter period. The temperature distribution of the sample showed the highest around ignition-point at center of the vessel and after ignition the highest temperature was moved toward surface of the vessel.

• Journal of the Korean Society of Safety
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• v.9 no.3
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• pp.74-81
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• 1994

The critical spontaneous ignition temperature for activated carbon were observed by performing experiments for granulated activated carbon with varying the period. As the results of the experiments, the critical spontaneous ignition temperature according to period of 0.5hr, 1.5hr and 2.5hr was 177.5$^{\circ}C$, 176.5$^{\circ}C$ and 172.5$^{\circ}C$ respectively, and the approximate expression of the critical spontaneous ignition temperature obtained for ambient temperature amplitudes was as follow ; $\delta$$_{c}$ (X, $\omega$)=$\delta$$_{c}${1-0.381 exp(-0.930.$\omega$$^{0.811}$)}.

• Journal of the Korean Society of Safety
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• v.10 no.4
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• pp.75-80
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• 1995

Spontaneous ignition characteristics of rice cracker were observed by preforming experiments at constant ambient temperature. As the results of the experiments, the critical spontaneous ignition temperature were exponentially decreased with the increase of ambient temperature. Type of combustion of rice cracker are smouldering combustion at low ignition temperature and flame combustion at high temperature. The rice cracker containing pam oil showed lower spontaneous ignition temperature than pure rice cracker because of oxidation heat of pam oil.

• Journal of the Korean Society of Safety
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• v.6 no.4
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• pp.66-72
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• 1991

Spontaneous ignition characteristics were observed by performing experiments for granulated activated carbon at constant ambient temperature in an oven. As the results of the experiments, the critical spontaneous ignition temperature of sample for large, intermediate and small vessels was 158.5$^{\circ}C$ , 165.5$^{\circ}C$ and 174.5$^{\circ}C$, respectively. It was found that the critical spontaneous ignition temperature decreased and the ignition induction time increased as the sample vessel size increased. Apparent activation energy of the sample calculated from the Frank= kamenetskii's thermal ignition theory was 17.81＊10$^3$J/mol.

• Fire Science and Engineering
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• v.22 no.1
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• pp.99-104
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• 2008

It is important to understand thermal characteristic as a method to estimate the new materials, because spontaneous ignition characterized by causing combustion in the low temperature without ignition source. If can not find out the thermal characteristics of materials, it is frequent that causes of fires could not be found. The danger level of spontaneous ignition material should be estimated and by closely studying its thermal characteristic. However, RPF(Refuse Paper & Plastic Fuel) is a solid matter and getting increasesa year by year because it is an economy profit as alternative energy for limited fossil fuels. Some time RPF occur a fire in the cases of its production process and conservation. Therefore study for thermal stability and critical ignition temperature of RPF was so imperative that the experiment by means of Bombe Calorimeter, TG-DTA, MS80, SIT-II, and Wire Basket Test was implemented. As a result, RPF had a caloric value 26.4-28.3 MJ/kg, and its initial pyrolysis temperature was $192^{\circ}C$ at heating rate 2 K/min. With the result of analysis by MS 80 which is an instrument measuring microscopic calory, pure RPF not containing water has higher caloric value than RPF containing 20% water. Also, SIT-II which is an instrument of insulated auto-ignition was ignited by $118.5^{\circ}C$. This temperature is lower than that of Wire Basket Test. The critical ignition temperature was calculated by Frank-Kamenetskii equation can cause ignition at $80^{\circ}C$ when conserved in the height of 10 m by the standard of infinity slab.

• Journal of the Korean Society of Safety
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• v.20 no.3 s.71
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• pp.98-104
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• 2005

This study experimentally and theoretically examines the fire characteristics of 100- by 100- by 50-mm samples of flame retardant treated Douglas fir. Samples were exposed to a range of incident heat fluxes 10 to $50kW/m^2$. The time to ignition measurements obtained from the cone heater were used to derive characteristic properties of the materials. A one-dimensional integral model has been used to predict the, time to ignition, critical heat flux and ignition temperature of samples. Ignition data and best-fit curves confirm ${{\dot{q}}_i}^{'}{\rightarrow}{{\dot{q}}_{cr}^{'}\;then\;t_{ig}{\rightarrow}{\infty}$ and when ${{\dot{q}}_i}^'{\gg}{{\dot{q}}_{cr}^'\;then\;t_{ig}{\rightarrow}0$. And Ignition of flame retardant treated samples occurred not at incident heat flux of bellow $10kW/m^2.$. By a one-dimensional integral model, the critical heat flux of each samples was predicted $10.21kW/m^2,\;11.82kW/m^2,\;and\;14.16kW/m^2$ for the D-N, D-F2, and D-F4, respectively. In ignition temperature of each samples, flame retardant treated samples were measured high about $50^{\circ}C$ than non-treated samples. Water-soluble flame retardant used in this study finds out more effect in delay of time to ignition when incident heat flux is low than high.

• Journal of the Korean Society of Safety
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• v.22 no.5
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• pp.77-83
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• 2007

This study is conducted on spontaneous ignition temperature and activation energy of Hydroxypropyl Methyl Cellulose(HMC) powder. HMC is a kind of cellulose derivative and used as additives for building material, surface coating, printing ink, adhesives, cosmetics and medical supplies. So this material has been widely used as important additive in the chemical industry fields and a mount of production has increased year by year. Therefore, it is very important to find out the thermal ignition characteristics of its danger and the critical ignition temperature. This study was performed by the Spontaneous Ignition Tester(SIT) and so on. Based on the data of the SIT-II, the critical ignition point of HMC is about $186^{\circ}C$ which is slightly lower than normal cellulose.