• 제목/요약/키워드: Critical behavior

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Thermal Behavior of Critical Micelle Concentration from the Standpoint of Flory-Huggins Model

  • Lim, Kyung-Hee
    • Bulletin of the Korean Chemical Society
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    • 제30권9호
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    • pp.2001-2006
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    • 2009
  • Temperature dependence of the critical micelle concentration (CMC), $x_{CMC}$, in micellization can be described by ln $x_{CMC}$ = A + BT + C lnT + D/T, which has been derived statistical-mechanically. Here A, B, C, and D are fitting parameters. The equation fits the CMC data better than conventionally used polynomial equations of temperature. Moreover, it yields the unique(exponent) value of 2 when the CMC is expressed in a power-law form. This finding is quite significant, because it may point to the universality of the thermal behavior of CMC. Hence, in this article, the nature of the equation ln $x_{CMC}$ = A + BT + C lnT + D/T is examined from a lattice-theory point of view through the Flory-Huggins model. It is found that a linear behavior of heat capacity change of micellization is responsible for the CMC equation of temperature.

사각 관 구조물의 충격에 의한 좌굴특성 (Buckling Behavior of a Square Tube Structure by Lateral Impact Load)

  • 윤경호;송기남;강흥석
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.812-818
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    • 2001
  • The drop type impact test and finite element analysis are established for examining the buckling behavior of a square tube under the lateral impact load. Based on these results, the effects by the boundary conditions for supporting the structure are reviewed, which are as follows. One is pinned condition by screw; the other is fixed by welding. The critical impact force and acceleration by test are nearly same between two cases. However, the critical impact velocity of the pinned condition is higher than that of the fixed case. Therefore, the dynamic buckling behavior of a pinned structure is better than the fixed condition in view of critical impact velocity. These test and analysis results will be adaptable for predicting the dynamic structural integrity of a tube structure not only the axial impact event but the lateral impact event.

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온도, 변형 및 응력 계측을 통한 초기재령 콘크리트의 임계수화도 및 열팽창계수 추정 (Estimation of Critical Degree of Hydration and Thermal Expansion Coefficient of Early-Age Concrete from Measured Temperature, Strain and Stress)

  • 오병환;최성철;신준호
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2002년도 가을 학술발표회 논문집
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    • pp.809-814
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    • 2002
  • Recently, the properties of early-age concrete are increasingly important because these properties directly influence the behavior of early-age concrete structures including stress and cracking behavior. Nevertheless, the studies on early-age concrete are limited to strength and temperature development. The purpose of present study is to propose a simple and rational method which can predict the stress and strain behavior of young age concrete. A series of test have been done to measure the temperature development, strains and stresses in concrete members. The concept of equivalent age was used to define the degree of hydration and this degree of hydration was used to calculate the strength and elastic modulus. The critical degree of hydration and thermal expansion coefficient were calculated using experimental data. It is seen that the critical degree of hydration range from 0.05 to 0.11 based on the measuring method. The thermal expansion coefficient was calculated based on the measured non-mechanical strain and it is found that the coefficient decreases slightly with the increase of age. The consideration of critical degree of hydration in calculating stresses gives more accurate results. The present study provides useful method and data in evaluating early-age behavior of concrete structure.

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평행 와이어와 충돌하는 액적 거동에 관한 연구 (A Study on the Behavior of Droplets Colliding with Parallel Wires)

  • 나종경;노동환;정용준;강보선
    • 한국분무공학회지
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    • 제26권3호
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    • pp.149-156
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    • 2021
  • In this study, the behavior of the droplet colliding with parallel wires was analyzed by time-delay photography. The impact behavior modes and the critical capture speed were analyzed by changing fluids, the droplet velocity, the wire diameter and the distance between wires. Seven typical modes of impacting droplet on parallel wires were observed. The tendency of mode change was generally similar when the wire diameter was changed, but the increase of the wire diameter caused the increase of the droplet velocity at which the mode changed. The modes at the highest droplet velocity were the splitting mode when the wires were closest, the passing and splitting mode in the middle, and the passing mode when the wires were farthest apart. The critical capture speed increased as the wire diameter increased and the distance between wires decreased. The ethanol droplet showed the lowest critical capture speed.

강자성 Co0.5Fe0.5 합금 박막에서의 자화역전현상 연구 (Study on Magnetization Reversal Behavior in Ferromagnetic Co0.5Fe0.5 Alloy Films)

  • 류광수
    • 한국자기학회지
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    • 제25권6호
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    • pp.180-184
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    • 2015
  • 실시간 자구 관찰이 가능한 광자기 현미경을 이용하여 강자성 나노자성체 CoFe 박막에서의 자화역전현상을 연구하였다. 흥미롭게도, 박막의 두께가 증가함에 따라 자구벽의 운동이 단일 자구벽의 운동 성향에서 무작위적인 자구들의 역전 성향으로 변함을 알 수 있었다. 또한, 자구벽 운동에서의 자구들의 점프사이즈들의 통계적인 해석 결과, CoFe박막에서의 자구역전현상이 임계지수 ${\tau}{\sim}1.33$를 가지는 임계축척현상을 보임을 알 수 있었다.

알루미나 세라믹스의 열피로 거동 (Themal Fatigue Behavior of Alumina Ceramics)

  • 정우찬;한봉석;이홍림;이형직
    • 한국세라믹학회지
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    • 제35권10호
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    • pp.1094-1100
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    • 1998
  • The thermal fatigue behavior of alumina ceramics was investigated by water quenching method. Single-quench thermal shock tests were performed to decide the critical thermal shock temperature difference ($\Delta$Tc) which was found to be 225$^{\circ}C$ Cyclic thermal shock fatigue tests were performed at temperature diff-erences of 175$^{\circ}C$, 187$^{\circ}C$ and 200$^{\circ}C$ respectively. After cyclic thermal shock fatigue test the distributions of retained strength and crack were observed. Retained strength was measured by four point bending method and crack observation method bydye penetration. In terms of the retained strength distribution the critical number of thermal shock cycles(Nc) were 7 for $\Delta$T=200$^{\circ}C$, 35 for $\Delta$T=187$^{\circ}C$ and 180for $\Delta$T=175$^{\circ}C$ respec-tively. In terms of the crack observation the critical number of thermal shock cycles were 5 for $\Delta$T==200$^{\circ}C$ 20 for $\Delta$T==187$^{\circ}C$ and 150 for $\Delta$T=175$^{\circ}C$ respectively. The difference of Nc investigated by two different methods is due to the formation of the longitudinal cracks which had no effect on the four point bending strength. Therefore the thermal fatigue behavior of alumina ceramics could be more accurately described by the crack observation method than the retained strength measurement method.

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Monte Carlo Investigation of Spatially Adaptable Magnetic Behavior in Stretchable Uniaxial Ferromagnetic Monolayer Film

  • Laosiritaworn, Yongyut;Laosiritaworn, Wimalin
    • Journal of Magnetics
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    • 제20권1호
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    • pp.11-20
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    • 2015
  • In this work, Monte Carlo simulation was employed to model the stretchable Ising monolayer film to investigate the effect of the spatial distance variation among magnetic atoms on magnetic behavior of the film. The exchange interaction was considered as functions of initial interatomic distance and the stretched distance (or the strain). Following Bethe-Slater picture, the magnetic exchange interaction took the Lennard-Jones potential-like function. Monte Carlo simulations via the Wolff and Metropolis algorithms were used to update the spin systems, where equilibrium and dynamic magnetic profiles were collected. From the results, the strain was found to have strong influences on magnetic behavior, especially the critical behavior. Specifically, the phase transition point was found to either increase or decrease depending on how the exchange interaction shifts (i.e. towards or away from the maximum value). In addition, empirical functions which predict how the critical temperatures scale with initial interatomic distance and the strain were proposed, which provides qualitatively view how to fine tune the magnetic critical point in monolayer film using the substrate modification induced strain.

셀프리더십, 진로결정 자기효능감, 비판적 사고성향이 진로준비행동에 미치는 영향: 간호대학생 중심으로 (Influences of Self-leardership, Career Decision-Making Self-Efficacy, and Critical Thinking Disposition on Career Preparation Behavior: Focused on Nursing Students)

  • 김경하
    • 한국융합학회논문지
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    • 제12권9호
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    • pp.307-314
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    • 2021
  • 본 연구는 셀프리더십, 진로결정 자기효능감, 비판적 사고성향이 간호대학생의 진로준비행동에 미치는 영향을 파악하기 위해 시행된 서술적 조사연구이다. G시와 M시의 간호학과에 재학중인 간호대학생을 대상으로 2019년 4월부터 6월까지 자료를 수집하였고 208명의 자료를 분석하였다. 자료는 기술적 통계, 독립표본 평균 검정, 일원 배치 분산분석, 피어슨 상관계수, 다중회귀분석을 실시하였다. 분석 결과, 셀프리더십(β=.331, p<.001)과 진로결정 자기효능감(β=.302, p<.001)은 진로준비행동에 정적으로 영향을 나타냈으며, 연구모형은 진로준비행동을 38.7% 설명하였다. 이러한 연구 결과를 통해 간호대학생의 진로준비행동을 촉진하기 위해 셀프리더십과 진로결정 자기효능감을 향상키기기 위한 방안들이 간호교육 현장에서 개발 및 운영되어야 함을 알 수 있다.

컴퓨터 시뮬레이션에 의한 트랙터와 트레일러의 선회운동 (Turning Behavior of Tractor-Trailer System by Computer Simulation)

  • 김종훈;최창현
    • Journal of Biosystems Engineering
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    • 제16권4호
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    • pp.346-354
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    • 1991
  • Turning behavior of tractor-trailer system was studied to guide the tractor and trailer. Based upon kinematic relationship between the tractor and the trailer, a mathematical model was developed and analyzed by computer simulation. A field test was carried out to verify the mathematical model. Following conclusions were drawn from this study. 1. A mathematical model and a simulation program for turning behavior of tractor-trailer system were developed. 2. The results of the field tests showed that the RMS errors were less than 0.33m and the mathematical model based upon kinematic relationship can be used for mapping guidance system for tractor and trailer. 3. As the steering angle was increased, the turning radius was decreased. When the tractor travelled at the low speed, the travel speed of the tractor did not affect turning radius but did affect running time and stability for steering. 4. When the tractor travelled under the critical velocity, the towed trailer followed smoothly. When the the tractor travelled faster than the critical velocity, the towed trailer oscillated. The critical velocity was determined from the specification of the tractor and the trailer.

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Parametric study using finite element simulation for low cycle fatigue behavior of end plate moment connection

  • Lim, Chemin;Choi, Wonchang;Sumner, Emmett A.
    • Steel and Composite Structures
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    • 제14권1호
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    • pp.57-71
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    • 2013
  • The prediction of the low cycle fatigue (LCF) life of beam-column connections requires an LCF model that is developed using specific geometric information. The beam-column connection has several geometric variables, and changes in these variables must be taken into account to ensure sufficient robustness of the design. Previous research has verified that the finite element model (FEM) can be used to simulate LCF behavior at the end plate moment connection (EPMC). Three critical parameters, i.e., end plate thickness, beam flange thickness, and bolt distance, have been selected for this study to determine the geometric effects on LCF behavior. Seven FEMs for different geometries have been developed using these three critical parameters. The finite element analysis results have led to the development of a modified LCF model for the critical parameter groups.