• Korean Journal of Environmental Agriculture
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• v.22 no.3
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• pp.233-235
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• 2003

Heavy metal contents in commercial horticultural growing media were investigated Fifty-three samples were collected nationwide during 2000 to 2001 and heavy metals in the samples were analyzed by ICP-OES after acid digestion and 0.1N HCl extraction. Average contents of total Cd, Cr, Co, Ni, Pb, and Zn by acid digestion in the growing media were 0.69, 35.7, 14.9, 15.5, 12.7, and 54.8 mg/kg DW, respectively. The ranges of heavy metal in the growing media were $0{\sim}1.82$, $0{\sim}259.8$, $1.6{\sim}69.5$, $0{\sim}60.7$, $0{\sim}36.5$, $12.9{\sim}124.0\;mg/kg$ DW for Cd, Cr, Co, Ni, Pb, and Zn, respectively. Heavy metal contents in the commercial horticultural growing media were showed lower levels than the permitted levels for quality control described by Korean Standard Analytical Method for Growing Media. Average contents and ranges of 0.1 N HCl extractable heavy metals were 0.08 and $0{\sim}0.20$ for Cd, 0.38 and $0{\sim}2.10$ for Cr, 1.45 and $0{\sim}4.03$ for Cu, 0.85 and $0{\sim}3.31$ for Ni, 0.84 and $0{\sim}2.21$ for Pb, and 30.68 and $0.18{\sim}88.45\;mg/kg$ DW for Zn, respectively. These concentrations by 0.1 N HCl extraction showed much less levels than those of total heavy metals by acid digestion.

• Economic and Environmental Geology
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• v.30 no.6
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• pp.567-586
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• 1997

Concentrations of several heavy metals in soils derived from black shale and slate have been reported to be higher than the average concentrations in non-polluted soils. This study describes and characterizes soil minerals, and investigates the distribution of heavy metals in soils, and then examines their relationship. Soils in the study area are mainly consist of guartz and feldspars with minor amount of kaolin, illite, vermiculite, chlorite and illite-vermiculite interstratified minerals. Mineral compositions are similar in mountain-, farmland-, and paddy-soils. The residual soils derived from sandy phyllites contain less illites than those from black shale and black slate. Heavy metals appear to be more concentrated in soils than in rocks. The concentrate ratios in soils to rocks ranges 1.1 times for Cr, 2 for Cu, 1.4 for Ni. The contour maps of Cd, Zn, Pb, Cu contents using 0.43N $HNO_3$-extraction imply that these elements are highly concentrated in the soils near the past uranium exploration region, coal seams, black slate beds and tailings than other parts of the study area. The proportions of the day in most soils are less than 10%. In spite of small proportions of the clay, the concentrations of heavy metals from clay fractions to the total concentrations are high: 1~2.4 times for Co, 1.4~2.5 for Cu, 1.2~2.6 for Ni, 1~5 for Pb, 1~2.7 for Zn and 1.6~1.8 for Cr and V. The contents of organic carbons in clay fractions are also 1.5~3.9 times higher than in silt and sand fractions. Cu, Pb and organic carbons show positive relationship in all size fractions. In the size-fractionated soil profile samples, the contents of heavy metals and organic carbons show analogous trends with depth. For the clay fractions of soil profile samples, the contents of heavy metals with depth have analogous trends to abundances of vermiculites, which have the high CEC in main clay minerals.

• The Korean Journal of Malacology
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• v.28 no.3
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• pp.233-244
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• 2012

Goseong bay, located in southeast sea of Korea with an area of 2,100 ha, is a semi-enclosed bay well-known for oyster farming cultured in an extended range of 148 ha. The objective of this study is to provide the fundamental data in order to manage the effective sea area. A total 26 of surface sediment were collected from Goseong bay to evaluate their sedimentary environment and heavy metals. The loss on Ignition (LOI), C/N ratio, acid volatile sulfide (AVS) and heavy metals were analyzed. loss on ignition (LOI) of surface sediment range from 1.00% to 3.03% (average 2.00%). The carbonate content ranges from 0.52% to 4.29% (average 2.37%). C/N ratio of organic matter showed that most part of organic matter comes from neighboring continent. Acid volatile sulfide (AVS) value of surface sediment from 0.02 mg/g to 1.43 mg/g (average 0.24 mg/g). A ten element of surface sediments (Al, As, Cd, Cr, Cu, Hg, Ni, Pb, V, Zn) were calculated by enrichment factor (Ef) and the results show that some areas are highly polluted with respect Cu and Hg. The correlation matrix displays the existence of remarkable levels of correlation with both positive and negative values among different variable pairs. LOI and AVS showed both positive values. LOI and AVS values falls under 2% and 1%. Therefore, Goseong bay showed good in quality of sediment.

• Journal of Korean Society on Water Environment
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• v.22 no.4
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• pp.666-671
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• 2006

Effects of a rainfall event (July 28, 2005) on the hydrochemical characteristics of the Jungrang river, the biggest tributary of the Han river, was investigated. Significant spatial variations in the hydrochemical characteristics were observed. At JR2 location, concentrations of T-N and T-P were relatively low indicating occurrence of active oxidation in the stepped drop structure. At JR3 location, concentrations of Na, K, Cl, $NH_4-N$ and EC were elevated suggesting increased discharge from the nearby waste-water treatment plant and tributaries. The rain event diluted major dissolved ion concentrations in the river by 12~52%. The $NO_3-N$ levels were preserved during the rain then increased about twofold after rainfall, suggesting increased discharge of nitrate-contaminated groundwater. Heavy metals including Cd, Co, Cr, Cu and Pb were not detected in all water samples and the leachates from surface sediment samples. Concentrations of Fe, Mn, Al and Zn were below the Korean Drinking Water Guideline. Results of this study suggested that establishment of water-quality monitoring protocols describing temporal and spatial variations in parameters sensitive to rainfall events, relatively steady factors, and contaminant sources is required.

• Journal of Korean Society on Water Environment
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• v.27 no.3
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• pp.300-305
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• 2011

This study aimed at analyzing the runoff quality by the layer thickness and material of soil roof to make best use of the rainwater falling on it in terms of safety and efficiency and resulted in the following assessments. It turned out that the concentrations decreased more in T-N, $NO_3$-N, $NH_4$-N, T-P and $PO_4$-P in roof rainwater except 30 cm for the RW1 soil roof after passing through it than those of first rainwater. On the other hand, the concentrations in rainwater passing through gravel roof turned out to be equal or same to those of the first rainwater. As a result of analysis of metallic stuff in runoff, there was no indication of Cd, Cr, Mn and Pb as well. The concentration of Cu, Fe and Zn in rainwater through soil roof became less than that of the first rainwater. In this research, the soil roof showed the good efficiency in lowering the concentration of such components as nitrogen, phosphorus and metals. Based on the results from this work, more practical study would be required further in the future in relation to soil roof when installing the rainwater-utilizing facilities.

• Journal of Wetlands Research
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• v.8 no.4
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• pp.49-58
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• 2006

The extent and degree of contaminated sediments on lake Paldang were analyzed at 40 sites for organic matters, nutrients and heavy metals. COD, T-N and T-P were fairly correlated with the grain size of sediments, and the sites which were most distributed with sand were less contaminated with the sites covered with silt and clay. Phosphorus species were in the range of 7-58 for adsorbed-P, $13{\sim}411{\mu}g/g$ for NAI-P, $52{\sim}482{\mu}g/g$ for Apatite-P and $75{\sim}894{\mu}g/g$ for residual-P, respectively. Although heavy metals of sediments were detected at the range of $0.2-4.2{\mu}g/g$(Cr), $1.6{\sim}20.7{\mu}g/g$(Cu), 1.4~78.0ng/g(Hg), $2.1{\sim}18.9{\mu}g/g$(Pb), $1.8{\sim}99.5{\mu}g/g$(Zn), further survey over the long period were required for more monitoring data. The release rate of nutrients were found no relationship in this study.

• Korean Journal of Environmental Agriculture
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• v.23 no.1
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• pp.15-21
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• 2004

Objectives of this study were to monitor the distribution of heavy metals, to compare extractable heavy metal with total content and to investigate the relationships between soil physico-chemical properties and heavy metals in orchard soil. Sampling sites were 48 in Gyeonggi, 36 in Gangwon, 36 in Chungbuk, and 44 in Chungnam, Soils were collected farm form two depths, 0 to 20 and 20 to 40 cm (here after referred to as upper and lower layers) from March to May in 1998. Total contents of heavy metal in soils were analyzed by ICP-OES after acid digestion ($HNO_3$:HCl:$H_2O_2$) whereas extractable contents were measured after successive extraction of 0.1N-HCl, 0.05 M-EDTA, and 0.005 M-DTPA. Mercury was analysed by mercury atomizer. The average contents of Cd Cu, and Pb in the extractant with 0.1N-HCl at upper layer were 0.080, 4.23, and 3.42 mg/kg, respectively. As content in the extractant with 1N-HCl was 0.44 mg/kg, and total contents of Zn, Ni and Hg were 78.9, 16.1, and 0.052 mg/kg, respectively. The ratios of concentrations of heavy metals to threshold values (Cd 1.5, Cu 50, Pb 100, Zn 300, Ni 40, Hg 4 mg/ke in Soil Environmental Conservation Act in Korea (2001) were low in the range of $1/2.5{\sim}1/76.9$ in orchard soils. The ratios of extractable heavy metal to total content ranged $5.4{\sim}9.21%$ for Cd, $27.9{\sim}47.8%$ for Cu, $12.6{\sim}21.8$% for Pb, $15.8{\sim}20.3%$ for Zn, $5.3{\sim}6.3%$ for Ni, and $0.7{\sim}3.6%$ for Zn, respectively. Cu and Pb contents in 0.05 M-EDTA extractable solution were higher than those in the other extractable solution. Total contents of Cd, Ni and Ni in soils were negatively correlated with sand content but positively correlated with silt and clay contents. Ratios of extractable heavy metal to total content were negatively correlated with clay content but ai and Ni contents were positively correlated with soil pH, organic matter, and available phosphorous. Therefore, the orchard soil was safe because the heavy metal contents of orchard soil were very low as compared to its threshold value in the Soil Environmental Conservation Act. However, it need to consider the input of agricultural materials to the agricultural land for farming practices for assessment of heavy metals.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.12
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• pp.1360-1365
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• 2007

The purpose of this study is to present the basic data for nonpoint pollutant loads from bridge road drainage sediments using the results to analyze organic matter and heavy metals from the four bridge drainage sampling sites with sediments of different particle size ranges. The sediment sample was collected from the bridge road drainage and the masses of nine sediments fractions were obtained after drying the separated sediment in an over at $85^{\circ}C:>2,000{\mu}m$, $1,000\sim2,000{\mu}m$, $850\sim1,000{\mu}m$, $425\sim850{\mu}m$, $212\sim425{\mu}m$, $125\sim212{\mu}m$, $90\sim125{\mu}m$, $75\sim90{\mu}m$, $<75{\mu}m$. The sediment extract was analyzed water quality constituents, including chemical oxygen demand(COD), total nitrogen(T-N), total phosphorus(T-P), heavy metals and particle size distribution. The results indicate that most of particle size ranges of the bridge road sediments was $125\sim425{\mu}m$, and portion of $<75{\mu}m$ was low. But most of the pollutants are associated with the finer fractions of the load sediments. As the results of analysis, the range and average values of COD, T-N, T-P, Fe, Cu, Cr, and Pb were $177\sim198.8$ mg/kg(77.6 mg/kg), $23\sim200$ mg/kg(83 mg/kg), T-P $18\sim215$ mg/kg(129 mg/kg), and $1,508\sim5,612$ mg/kg(3,835 mg/kg), $9.2\sim69.3$ mg/kg(49 mg/kg), $19.1\sim662.2$ mg/kg(214 mg/kg), and $28.4\sim251.4$ mg/kg(114 mg/kg), respectively. The relationship between sediment size and pollutants concentration have an inverse proportion. The removal of road sediments with frequently could be reduced the significant nonpoint pollutant load, because of the bridge road sediment contains considerable micro-particles and heavy metals.

• Journal of Environmental Health Sciences
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• v.24 no.3
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• pp.124-130
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• 1998

This study was to examine the utilization of waste egg snells for removal of heavy metals in laboratory wastewater. It was estimated that pH increasing formed heavy metals into a hydroxide and then settled to remove them. Removal rate of heavy metals were increased as increased dosage, low adsorbate concentration and passed reaction time. Average adsorption volumes of Cr, Cu, Mn and Pb per g were about 1.21 mg, 1.1 mg, 0.96 mg and 1.04 mg, respectively. If we reflected the adsorption capacity(k) and adsorption intensity(1/n) of Freundlich isotherm, we couldn't consider waste egg shells as a good adsorbent. It seemed that heavy metals contained in complex wastewater was removed to be influenced by inital pH, solubilities with passed reaction rime and competitive reaction.

• Proceedings of the KWS Conference
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• 2006.10a
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• pp.196-198
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• 2006

이 연구는 CBN을 건전한 브레이징을 하기 위해서, CBN과 금속필러메탈 접합계면에서의 금속성분과 산화물, 탄화물의 거동을 분석하는데 있다. 진공 인덕션 브레이징으로 온도는 $950{\sim}1100^{\circ}C$에서 브레이징 유지시간은 $5{\sim}30$분로 실시하였다. 금속필러로는 Ni-7Cr-3Fe-3B-4Si(wt.%)와 Ag-25Cu-5Ti(wt.%)을 사용하여 브레이징된 CBN은 $950{\sim}1000$도, 유지시간 10분 사이에서 각각 건전한 계면과 표면을 얻을 수 있었으며, 계면에서 Ti-rich상과 화합물이 확인되었다. 이상의 결과로 부터 화합물의 생성과 건전한 접합공정은 브레이징 온도와 시간이 좌우하며, N과 B, Ti의 함유량이 CBN의 브레이징 접합 특성의 중요변수로 생각되어진다. CBN과 Ni계/Ag계 브레이징 필러의 계면에서의 미세조직 및 화학반응의 메커니즘은 SEM, EPMA, XRD를 이용하여 분석하였다.