• Title/Summary/Keyword: Cr-Ni 강

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Reheat Cracking Susceptibility of CrMoV Steel (CrMoV강의 재열균열 민감도에 관한 연구)

  • 김광수
    • Proceedings of the KWS Conference
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    • 2004.05a
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    • pp.168-170
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    • 2004
  • 터빈로터는 발전설비 중에서 가장 핵심 부분이며 동시에 심한 고온 응력을 받는 부분이다. 터빈로터 재료로는 Ni-Cr-Mo-V강과 CrMoV 강등이 사용된다. CrMoV 강은 발전 설비로 장시간 사용 중 열적피로나 크립손상, 고온 부식 등의 문제가 단독 혹은 복합적으로 발생하여 재료에 손상을 입히게 되고 결국에는 설비의 수명을 단축 시키곤 한다. (중략)

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Effect of Sealing Materials and Parameters on the Corrosion Resistance of HVOF-Sprayed CrC-NiCr Coatings (실링재 및 실링방법이 HVOF 용사된 CrC-NiCr 코팅의 내식성에 미치는 영향)

  • Jeong, Younghun;Nam, Uk-Hee;Byon, Eungsun;Kang, Tae-Il;Kang, Chung-Yun
    • Journal of the Korean institute of surface engineering
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    • v.47 no.6
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    • pp.323-329
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    • 2014
  • Effects of sealant and sealing procedure on corrosion resistance of high velocity oxy-fuel (HVOF) sprayed coatings were studied. HVOF-sprayed CrC-20NiCr coatings were sealed using three commercial sealants based on phenolics and epoxy. Penetration depth of sealants, measured by fluorescent microscope technique, was between $19{\mu}m$ and $340{\mu}m$ depending on sealant, sealing condition or sealing procedure. It was found that sealing on rotation status was more effective than that on stationary specimen due to the Coriolis effect of fluid in pores of the coating. From the CASS results, corrosion resistance of properly sealed CrC-20NiCr coatings was equal to that of hexa-valent chromium plating.

Matrix Effects on X-Ray Fluorescence Intensities in Fe-Ni-Cr System (철-니켈-크롬 三成分系에서 X-線 螢光의 매트릭스 效果에 관한 硏究)

  • Yang Che-Hyon;Yeh Jin-Hae
    • Journal of the Korean Chemical Society
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    • v.37 no.10
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    • pp.861-866
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    • 1993
  • In general, the concentration of constituents can be more accurately measured in x-ray fluorescence analysis of Fe-Ni-Cr alloy by reducing and correcting the matrix effect with standard ingot samples. Because of the difficult the treatment at a high temperature in preparing the ingot samples of various concentrations, several standard specimens were prepared by mixing the powders of the metallic oxides in certain proportions and pressing them with a costant pressure. With the metallic oxide specimens thus obtained, different matrix coefficients were calculate from the intensities of the strength of the x-ray fluorescence and the concentration of the substances. It is found that effects of Fe and Cr on Ni are absorption rich and effects of Fe and Ni on Cr are enhancement rich, whereas Ni enhances Fe Fluorescence but Cr absorves Fe K${\alpha}$ line. And the x-ray fluorescence intensities were compared and analyzed between the metallic oxides and the ingot samples.

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기계재료로 쓰이는 내열강재의 현황

  • 신민교
    • Journal of the KSME
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    • v.26 no.4
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    • pp.284-289
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    • 1986
  • 이들 기기, 장치는 대부분 철강재가 그 근간을 이루고 있지만, 특히 고온부를 형성하는 부재는 내열용 철강과 합금이다. 강을 모재로 하고 고온에서의 강도유지를 위하여 유용한 소랴의 Cr, Mo 등을 합금시킨 저합금내열강이 1차적으로 사용되어 왔으나 사용조건이 고도화 되면서 이들 합금성분 량이 늘어나 주로 Cr 성분을 증가시킨 고 Cr 페라이트계, 그리고 Ni 성분을 다량으로 첨가한 오스테나이트계 내열강이 제 2차, 제 3차대상이 되어 연구 발전되어 왔다. 그 사용한계는 사용 가스등 환경의 영향과 고온의 크리이프나 피로, 파괴에 대한 저항성등에 크게 좌우되지만, 대개 2.25Cr-1Mo 강의 저합금강에서 $550^{\circ}C$, 9~12% Cr인 페라이트계 내열강에서 $^650{\circ}C$ 까지가 한도이며 그 이상온도에서는 오스테나이트계 내열강이 고려의 대상이 되고 있는 것 같다. 이들 고온부에 사용되는 철강 재료를 중심으로 최근의 동향을 주로 금속학적 입장에서 살펴보기로 한다.

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Correlation of Heavy Metal Concentrations between Total Digestion and Aqua Regia Digestion for Sediments from Yeongsan and Seomjin Watersheds (완전분해와 전분해 방법에 의한 영산강.섬진강수계 퇴적물의 중금속농도 상관관계)

  • Oh, Da-Yeon;Choi, Kyoung-Kyoon;Huh, In-Ae;Hwang, In-Seong;Kim, Young-Hoon;Hur, Jin;Shin, Hyun-Sang;Oh, Jeong-Eun;Shin, Won-Sik;Park, Jeong-Hun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.1
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    • pp.32-38
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    • 2011
  • In this study, the correlations of concentrations in sediment heavy metals between two pretreatment methods, total digestion and aqua regia digestion, have been investigated. Total 43 samples had been collected from streams and lakes in Yeongsan and Seomjin watersheds. They were decomposed in two pretreatment methods and five metal components (Cd, Cr, Ni, Pb, Zn) were analyzed. Overall average concentrations of heavy metals were Zn>Cr>Pb>Ni>Cd in the order. The concentrations of aqua regia digestion were 35.0% (Cd), 53.8% (Cr), 66.2% (Ni), 64.4% (Pb) and 76.4% (Zn) of the concentrations of total digestion and heavy metal concentrations of total digestion were higher. Heavy metal concentrations in sediments from lakes were higher than those from streams. The correlation equations between the concentrations of total digestion and aqua regia digestion were obtained. The concentrations of Zn and Ni, which showed strong linear correlations, increased in aqua regia digestion as the concentration in total digestion increased. The linear correlation coefficients between two digestion methods for most analyzed metals were above the average correlation. However, these results can be applied with limitations due to heterogeneity of sediments.

Effect of Ni on the High Strength Characteristic of 9Cr Ferritic Heat Resistant Steel Applied to the Power Plants (발전플렌트용 9Cr 페라이트 내열강의 고온강도 특성에 미치는 Ni의 영향)

  • Kang, C.Y.;Miyahara, K.
    • Journal of Power System Engineering
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    • v.4 no.1
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    • pp.74-80
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    • 2000
  • This present study was investigated effect of Ni contents on the high temperature strength characteristic in 9Cr ferritic heat-resistant steel added 1.7%W in place of Mo in order to restraint laves phase formation. Precipitation amount of carbide, number of particle per unit area and particle size of carbide were decreased with increase of Ni content. In the steels, carbides of $M_{23}C_6$ type was mainly precipitated, but laves phases could not precipitated. Tensile and yield strength, creep strength and creep rupture time was decreased, but elongation were increased due to decreasing of particle number per unite area and carbide amount precipitated with increase of Ni content.

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Effect of Alloying Elements of Mn and Ni on the Pitting Corrosion Resistance of 22Cr Lean Duplex Stainless Steel (22Cr 린 듀플렉스 스테인리스강의 공식저항성에 미치는 Mn과 Ni 첨가의 영향)

  • Ahn, Y.S.;Bae, K.K.
    • Journal of Power System Engineering
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    • v.16 no.5
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    • pp.76-82
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    • 2012
  • Duplex stainless steels have the dual microstructure of austenite and ferrite phases. This steel exhibits generally a high corrosion resistance and higher mechanical strength compared with austenitic stainless steels. The steels used in the investigation have the chemical composition of Fe-22Cr-xNi-yMn-0.2N in which the contents of Ni and Mn were varied with maintaining the equal [Ni/Cr] equivalent. The fraction of ferrite phase was increased with the increase of annealing temperature. The impact factor of Mn element on the [Ni] equivalent was amended on the basis of the results of the investigation. 4Mn-2Ni alloy showed the highest pitting corrosion resistance. The fraction ratio, grain size and misorientation angle between grains were measured, and the correlation with pitting potential was investigated.

MISFET type H2 sensor using pd-black catalytic metal gate for high performance (Pd-black 촉매금속 이용한 고성능 MISFET 형 수소센서)

  • Kang, Ki-Ho;Cho, Yong-Soo;Han, Sang-Do;Choi, Sie-Young
    • Journal of Sensor Science and Technology
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    • v.15 no.2
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    • pp.90-96
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    • 2006
  • We have fabricated the Pd-blck/NiCr gate MISFET-type $H_2$ sensor to detect the hydrogen in atmosphere. A differential pair-type structure was used to minimize the intrinsic voltage drift of the MISFET. The Pd-black film was deposited in the argon environment by thermal evaporation. In order to eliminate the blister formation in the surface of the hydrogen sensing gate metal, Pd-black/NiCr double metal layer was deposited on the gate insulator. The scanning electron microscopy and the auger electron spectroscopy was used to analyze their surface morphology and basic structure. The Pd-black/NiCr gate MISFET has been shown high sensitivity and stability more than Pd-planar/NiCr gate MISFET.

Effect of Alloying Elements of Si, Mn, Ni, and Cr on Oxidation of Steels between 1050℃ and 1200℃ in Air (강의 대기 중 1050~1200℃의 산화에 미치는 합금원소 Si, Mn, Ni, Cr의 영향)

  • Lee, Dong Bok
    • Korean Journal of Metals and Materials
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    • v.50 no.4
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    • pp.300-309
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    • 2012
  • Low-carbon steels and a stainless steel were oxidized isothermally and cyclically between $1050^{\circ}C$ and $1200^{\circ}C$ for up to 100 min in air to find the effect of alloying elements of Si, Mn, Ni, and Cr on their oxidation. The most active alloying element of Si was scattered inside the oxide scale, at the scale-alloy interface and as internal oxide precipitates beneath the oxide scale. Manganese, which could not effectively improve the oxidation resistance, was rather uniformly distributed in the oxide scale. Nickel and chromium tended to present at the lower part of the oxide scale. Excessively thick porous scales formed on the low-carbon steels, whereas thin but non-adherent scales containing $Cr_2O_3$ formed on the stainless steel.

Hardening Characteristics of Aluminum Alloy Surface by PTA Overlaying with Metal Powders (II) -Hardening charactersteristics and wear resistance of thicker surface alloyed layer- (플라즈마분체 오버레이법에 의한 알루미늄합금 표면의 경화특성에 관한 연구( II ) -후막 표면 합금화층의 경화특성과 내마모성-)

  • ;中田一博;;;松田福久
    • Journal of Welding and Joining
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    • v.12 no.4
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    • pp.102-109
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    • 1994
  • The thick and hard alloyed layer was formed on the surface of Aluminum Cast Alloy(AC2B) by PTA overlaying process with Cr, Cu and Ni metal powders under the condition of overlaying current 150A, overlaying speed 150mm/min and different powder feeding rate 5-20g/min. The characteristics of hardening and were resistance of alloyed layer have been investigated in relation to microstructure of alloyed layer. As a result, it was made clear that Cu powder was the most superier one in three metal powders used due to an uniform hardness distribution of Hv 250-350, good wear resistance and freedom from cracking in alloyed layer of which microstructure consisted of hypereutectic. On the contrary, irregular hardness distribution was usually obtained in Cr or Ni alloyed layers of which hardness was increased as Cr or Ni contents and reached to maximum hardness of about Hv 400-850 at about 60wt% Cr or 40wt% Ni in alloyed layer. However the cracking occurred in these alloyed layers with higher hardness than Hv 250-300 at more than 20-25wt% of Cr or Ni contents in alloyed layer. Wear rate of alloyed layer was decreased to 1/10 in Cu alloyed layer and 1/5 or 1/3 in Cr or Ni alloyed layer with same hardness of about Hv 300 in comparison with that of base metal at higher sliding speed.

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