• Journal of Welding and Joining
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• 제15권1호
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• pp.101-108
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• 1997

손상된 터어빈 로터강의 보수 용접에 있어서 용접부의 크립 파단 수명과 탄화물간의 관계가 연구되었다. 탄화물은 탄화물 추출 복제법을 이용하여 확인되었으며 로터강에는 Molybdenum 주성분의$M_2C$, Vanadium 주성분의 $M_4C_3$, 및 Chromium 주성분의 $M_{23}C_6$와 $M_7C_3$ 탄화물이 존재하였다. 한편 ICHAZ에서 파단된 시험편의 파단면에서는 구상의 조대한 Molybdenum 주성분의 $M_6C$ 탄화물이 발견되었다. 조대한 Molybdenum 주성분의 $M_6C$ 탄화물의 석출은 탄화물 주위에 고용경화 원소인 Molybdenum 농도를 떨어뜨려 기공 발생 원인을 제공하였다. CGHAZ에서 파단된 용접부의 파단면에서는 조대한 $M_6C$ 와 $M_{23}C_6$가 발견되었다.

• 한국표면공학회:학술대회논문집
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• 한국표면공학회 2018년도 춘계학술대회 논문집
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• pp.111-111
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• 2018

ASTM A387-Gr.91 강은 우수한 고온 강도, 크리이프 저항성 그리고 내산화성 등으로 인해 화력 및 바이오매스 발전 시설과 같은 고온 설비의 구조재료로 널리 사용되고 있다. 고온 환경에서 높은 강도는 탄화물과 탄질화물에 의한 석출강화가 주 요인으로 작용한다. 열처리 과정에서 Mo, Cr, Mn, 그리고 Fe는 구-오스테나이트 및 마르텐사이트 라스 입계에 $M_{23}C_6$ 탄화물로 석출되며, V, Nb, 및 N은 조직 내부에 미세한 MX 탄질화물로 석출된다. 따라서 합금의 고온 강도는 조직 내 석출물의 개수밀도와 크기에 크게 의존한다. 그러나 적용 환경의 특성 상 고온 노출에 따른 2차상 석출 및 조대화의 조직열화 현상이 발생하며, 이는 재료의 강도를 저하시킨다. 본 연구에서는 ASTM A387-Gr.91 강의 미세조직 열화에 따른 강도저하 및 파괴 양상을 고찰하는데 그 목적을 두었다. 본 연구에서 사용된 ASTM A387-Gr.91 강의 화학성분(wt, %)은 0.1 C, 0.38 Si, 0.46 Mn, 0.25 Ni, 8.38 Cr, 0.93 Mo, 0.18 V, 0.09 Nb, 그리고 나머지는 Fe 이다. 조직열화 및 기계적 강도저하 특성을 평가하기 위한 등온열화는 $650^{\circ}C$의 대기 환경에서 최대 1000시간동안 실시하였다. 열화된 시험편의 미세조직 및 탄화물에 대한 분석은 SEM과 EDS를 이용하여 실시하였다. 그리고 기계적 강도 평가는 인장실험과 비커스 경도시험을 통해 실시하였다. 또한 열화 시간에 따른 파단양상의 변화를 관찰하기 위해 인장시험편의 파단면을 SEM과 EDS를 이용하여 분석하였다. 그 결과, 열화에 따른 마르텐사이트 라스의 소실, 탄화물의 조대화, 그리고 2차상 석출의 조직 열화현상이 나타났다. 또한 기계적 강도는 조직 열화에 따라 저하되는 경향을 나타냈다.

• Nuclear Engineering and Technology
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• 제50권1호
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• pp.116-125
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• 2018

Modified 9Cr-1Mo ferritic steel is a preferred material for steam generators in nuclear power plants for their creep strength and good corrosion resistance. Austenitic stainless steels, such as type 316LN, are used in the high temperature segments such as reactor pressure vessels and primary piping systems. So, the dissimilar joints between these materials are inevitable. In this investigation, dissimilar joints were fabricated by the Shielded Metal Arc Welding (SMAW) process with Inconel 82/182 filler metals. The notch tensile properties and Charpy V-notch impact toughness properties of various regions of dissimilar metal weld joints (DMWJs) were evaluated as per the standards. The microhardness distribution across the DMWJs was recorded. Microstructural features of different regions were characterized by optical and scanning electron microscopy. Inhomogeneous notch tensile properties were observed across the DMWJs. Impact toughness values of various regions of the DMWJs were slightly higher than the prescribed value. Formation of a carbon-enriched hard zone at the interface between the ferritic steel and the buttering material enhanced the notch tensile properties of the heat-affected-zone (HAZ) of P91. The complex microstructure developed at the interfaces of the DMWJs was the reason for inhomogeneous mechanical properties.

• Corrosion Science and Technology
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• 제20권6호
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• pp.451-465
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• 2021

In this investigation, electrochemical characteristics and damage behavior of 316L stainless steel polymer electrolyte membrane fuel cell(PEMFC) were analyzed by potentiodynamic and potentiostatic tests in cathode operating condition of PEMFC. As the result of potentiodynamic polarization test, range of passive region was larger than range of active region. In the result of potentiostatic test, damage depth and width, pit volume, and surface roughness were increased 1.57, 1.27, 2.48, and 1.34 times, respectively, at 1.2 V compared to 0.6 V at 24 hours. Also, as a result of linear regression analysis of damage depth and width graph, trend lines of damage depth and width according to applied potentials were 16.6 and 14.3 times larger, respectively. This demonstrated that applied potential had a greater effect on pitting damage depth of 316L stainless steel. The damage tendency values were 0.329 at 6 hours and 0.633 at 24 hours with applied potentials, representing rapid growth in depth direction according to the test times and applied potentials. Scanning electron microscopy images revealed that surface of specimen exhibited clear pitting damage with test times and applied potentials, which was thought to be because a stable oxide film was formed by Cr and Mo.

• 한국해양공학회지
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• 제6권1호
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• pp.78-86
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• 1992

The creep behaviors of 1%Cr-Mo-V and 12%Cr steam turbine rotor steels under static or cyclic load were examined at 600 and $700^{\circ}C$. The relationship between these two kinds of phenomena was studied and the experimental results were summarized as follows: 1) It is confirmed that the cyclic creep strain dependent on time is more available for creep, behavior analysis according to frequency change than that dependent on number of cycles, and the static creep, the special case of cyclic creep with stress ratio of 1 can be also more effectively analyzed by time-dependence. 2) The steady cyclic creep rate vs. the steady static creep rate, increases according to the increase of stress ratio, and this phenomena may occur on occasion of the decrease of the internal stress. 3) The initial strain affects on all the creep properties of the transient region, the steady state region and the rupture time in cyclic creep as well as static creep, and the quantitative relationships among them exist.

• 대한기계학회논문집A
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• 제22권1호
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• pp.44-51
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• 1998

In order to develop the evaluation methods of degradation for the Ni-Cr-Mo-V steel, which is in use for turbine rotor in nuclear power plant, the degraded materials were prepared by simulated degradation methods. The result of impact test and fatigue crack growth test shows that the FATT(Fracture Appearance Transition Temperature) and fatigue crack growth rate increased with the increase of degradation. And the result of new electrochemical polarization test method was suggested for the evaluating FATT, fatigue crack growth exponent and coefficient C values based on the results of relationship between corrosion current density(Icorr) & FATT, and the m & C and Icorr.

• 한국해양공학회지
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• 제6권1호
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• pp.105-112
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• 1992

The main purpose of this study is to derive a law of fatigue crack growth rate in the region of elastic or elasto-plastic fracture mechanics at elevated temperatures through the application of dimensional analysis. An equation of elasto-plastic fatigue crack growth rate at elevated temperatures appeared a new Arrhenius type equation containing J-integral range and absolute temperature. The elastic or elasto-plastic crack growth rate equation shows a fairly good agreement with the experimental results for Cr-Mo-V rotor steel and Hastelloy-X alloy in the comparatively wide temperature ranges.

• Journal of Welding and Joining
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• 제21권1호
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• pp.99-106
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• 2003

This research was aimed to evaluate the material degradation with various microstructures of X20CrMoV121 steel weldment by Advanced Small Punch(ASP) test. Due to the regional limitation on constitutive structures, the minimized loading ball(${\varphi}1.5mm$) and bore diameter of lower die(${\varphi}3mm$) were designed for the ASP test. The micro-hardness test was also performed to assess the mechanical properties with artificial aging heat treatment. Material degradation was estimated by ductile-brittle transition temperature(DBTT). The results obtained from the ASP test were compared with those from conventional small punch(CSP) test and CVN impact test for several weldment microstructures. It was found that the ASP test clearly showed the microstructural dependance on the material degradation in the weldment.

• 동력기계공학회지
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• 제15권3호
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• pp.52-57
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• 2011

440A martensitic stainless steels which were modified with reduced carbon content(~0.5wt.%) and addition of small amount of vanadium, tungsten and molybdenum 0.4wt.%, 0.4wt.% and 0.68wt.% respectively were manufactured. Effects of alloying elements and tempering temperatures on the intergranular corrosion were investigated through the method of DL-EPR(Double-electrochemical potentiodynamic reactivation). It was thought that the highest DOS(Degree of sensitization) of specimens was obtained at the tempering temperature of $450^{\circ}C$ regardless of types of alloy because of the precipitation of Cr7C3. Addition of vanadium lowered DOS a little above the tempering temperature of $550^{\circ}C$. It was considered to be effected by precipitation of VC carbides. Intergranular corrosion was influenced more by tempering temperature than by alloying elements of V, W and Mo.

• 열처리공학회지
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• 제9권4호
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• pp.229-233
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• 1996

This work has been carried out to reduce the softening of heat affected zone on laser surface alloying. Iron based rapid solidification material with $Cr_{5-10}$, $V_{1-3}$, $Mo_{3-7}$, $W_{2-5}$, $B_{7-8}$, $C_{2-3}$, $Si_{0.5-1}at%$ was alloyed on the surface of SM45C steel. The excellent softening resistance in alloyed and heat affected zone showed, which could be attributed to the formation of stable high temperature precipitates.