• 한국기계기술학회지
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• 제13권2호
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• pp.115-121
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• 2011

The size of hydrogen molecule is not so small as to invade into the lattice of material, and therefore, hydrogen invades into the material as atom. Hydrogen movement is done by diffusion or dislocation movement in the near crack tip or plastic deformation. Hydrogen appeared to have many effects on the mechanical properties of the Cr-Mo steel alloys. The materials for this study are 1.25Cr-0.5Mo and 2.25Cr-1Mo steels used at high temperature and pressure. The hydrogen amount obtained by theoretical calculation was almost same with the result solved by finite element analysis. The distribution of hydrogen concentration and average concentration was calculated for a flat specimen. Also, finite element analysis was employed to simulate the redistribution of hydrogen due to stress gradient. The calculation of hydrogen concentration diffused into the material by finite element method will provide the basis for the prediction of delayed fracture of notched specimen. The distribution of hydrogen concentration invaded into the smooth and notched specimen was obtained by finite element analysis. The hydrogen amount is much in smooth specimen and tends to concentrate in the vicinity of surface. Hydrogen embrittlement susceptibility of notched specimen after hydrogen charging is more remarkable than that of smooth specimen.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2005년도 추계학술발표대회 개요집
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• pp.29-31
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• 2005

The purpose of this study is to establish the predictive equation of the distortion at the ES and SA weldment of Cr-Mo low alloy steel. In order to do it, the effect of heat input, plate thickness and strip wire width for ESW on the distortion at the ES and SA weldment was evaluated using FEA. Based on the results, the principal factors controlling the distortion of the ES and SA weldment were identified and the predictive equation was established.

• Corrosion Science and Technology
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• 제9권4호
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• pp.164-170
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• 2010

Thermodynamic consideration was performed for Alloy 617 exposed to an impure helium ($H_2$ 20pa, $H_2O$ 0.5pa, $CH_4$ 2pa and CO 5pa) at $950^{\circ}C$. Oxidation power was decreased in the order Al > Ti > Si > Cr > Mn. Decarburization and carburization reactions were available leading to carbon activity decrease and increase, respectively, depending on carbon and Cr activities. The thermodynamic prediction was compared with the experimental results obtained in similar conditions (($H_2$ 20pa, $H_2O$ 0.05pa, $CH_4$ 5pa and CO 2pa) and $950^{\circ}C$) by others for Alloy 617. The driving force for oxidation of Al, Ti and Si is very large to be oxidized at a given impure helium and the environment is actually carburizing towards the structural alloy, which is consistent with this work.

• 한국재료학회지
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• 제23권9호
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• pp.483-488
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• 2013

Over the past few decades, high-nitrogen austenitic steels have steadily received greater attention since they provide a unique combination of high strength and ductility, good corrosion resistance, and non-magnetic properties. Recently, highnitrogen 18Mn-18Cr austenitic steels with enhanced strength have been developed and widely used for generator retaining rings in order to prevent the copper wiring from being displaced by the centrifugal forces occurring during high-speed rotation. The high-nitrogen austenitic steels for generator retaining ring should be expanded at room temperature and then stress relief annealed at around $400^{\circ}C$ to achieve the required mechanical properties. In this study, four kinds of high-nitrogen 18Mn-18Cr austenitic steels with different nitrogen content were fabricated by using a pressurized vacuum induction melting furnace, and then the effects of nitrogen content, cold working, and stress relieving on tensile properties were investigated. The yield and tensile strengths increased proportionally with increasing nitrogen content and cold working, and they further increased after stress relieving treatment. Based on these results, a semi-empirical equation was proposed to predict the tensile strength of highnitrogen 18Mn-18Cr austenitic steels for generator retaining rings. It will be a useful for the effective fabrication of high-nitrogen 18Mn-18Cr austenitic steels for generator retaining rings with the required tensile properties.

• 대한화학회지
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• 제30권2호
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• pp.181-187
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• 1986

$trans-Cr^{Ⅲ}N_4XY$착물의 광화학적 치환반응에 있어서 한개의 리간드가 떨어져서 생기는 가상적 1차중간체의 총안정화에너지를 고려함으로서 치환되는 리간드를 예측할 수 있다. 총안정화 에너지와 d-궤도함수의 1전자에너지준위는 각종첩모형체계내에서 계산하였는데, 계산결과에 의하면 총안정화에너지 값이 큰 중간체일수록 보다 쉽게 생성된다고 할 수 있다. 결과적으로 총안정화에너지의 상대적인 값은 가장 낮은 에너지의 d-d전이에 해당하는 파장의 빛을 쪼여줄 때 $trans-Cr^{Ⅲ}N_4XY$착물에서 어느 리간드가 우선적으로 불안정하게 되는가를 결정하는데 이용될 수 있으며, $trans-Cr^{Ⅲ}N_4XY$착물의 광수화반응에 있어서 떨어지는 리간드에 대한 이러한 예측은 실험상의 결과와 일치하고 있다.

• 전기학회논문지
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• 제58권12호
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• pp.2538-2541
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• 2009

H.264/AVC High 4:4:4 Intra/Predictive profiles supports RGB 4:4:4 sequences for high fidelity video. RGB color planes rather than YCbCr color planes are preferred by high-fidelity video applications such as digital cinema, medical imaging, and UHDTV. Several RGB coding tools have therefore been developed to improve the coding efficiency of RGB video. In this paper, we propose a new method to extract more accurate correlation parameters for inter-plane prediction. We use a searching method to determine the matched macroblock (MB) that has a similar inter-color relation to the current MB. Using this block, we can infer more accurate correlation parameters to predict chroma MB from luma MB. Our proposed inter-plane prediction mode shows an average bits saving of 15.6% and a PSNR increase of 0.99 dB compared with H.264 high4:4:4 intra-profile RGB coding. Furthermore, extensive performance evaluation revealed that our proposed algorithm has better coding efficiency than existing algorithms..

• 대한기계학회논문집A
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• 제26권6호
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• pp.1069-1076
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• 2002

The high temperature creep behavior of heat machine systems such as aircraft engines, boilers and turbines in power plants and nuclear reactor components have been considered as an important and needful fact. There are considerable research results available for the design of high temperature tube materials in power plants. However, few studies on the Initial Strain Method (ISM) capable of securing repair, maintenance, cost loss and life loss have been made. In this method, 3 long time prediction Of high temperature creep characteristics can be dramatically induced through a short time experiment. The purpose of present study is to investigate the high temperature creep lift of Udimet 720, SCM 440-STD61 and 1Cr-0.5Mo steel using the ISM. The creep test was performed at 40$0^{\circ}C$ to $700^{\circ}C$ under a pure loading. In the prediction of creep life for each materials, the equation of ISM was superior of Larson-Miller Parameter(LMP). Especially, the long time prediction of creep life was identified to improve the reliability.

• 동력기계공학회지
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• 제6권2호
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• pp.40-47
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• 2002

In this paper, friction welding optimization for 1Cr0.5Mo-STS304 (${\phi}14\;mm$), AE applications for the weld quality evaluation and the applications of various life prediction methods such as LMP (Larson-Miller Parameter) and ISM (initial strain method) were investigated : The creep behaviors of those steels and the friction welded joints under static load were examined by ISM combined with LMP at 400, 500, 550 and $600^{\circ}C$, and the relationship between these two kinds of phenomena was studied. The real-time predicting equations of elevated-temperature creep life (rupture time) under any creep stress at any elevated-temperature could be developed by LMP and LMP-ISM. It was confirmed that the life prediction equations by LMP and LMP-ISM are effective only up to 102 h and can not be used for long times of 103-106 h, but by ISM it can be used for long times creep prediction of more than 104 h with most reliability.

• 한국해양공학회:학술대회논문집
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• 한국해양공학회 2001년도 춘계학술대회 논문집
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• pp.307-313
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• 2001

In this Paper, friction welding optimization for 1Cr0.5Mo-STS304($\Phi$14mm), AE applications for the weld quality evaluation and the applications of various life prediction methods such as LMP(Larson-Miller Parameter) and ISM(initial strain method) were investigated : the creep behaviors of those steels and the friction welded joints under static load were examined by ISM combined with LMP at 400, 500, 550 and $600^{\circ}C$, and the relationship between these two kinds of phenomena was studied. The real-time predicting equations of elevated-temperature creep life(fracture time) under any creep stress at any elevated- temperature could be developed by LMP and LMP-ISM, It was confirmed that the life prediction equations by LMP and LMP-ISM are effective only up to 10$^2$hrs and can not be used for long times of 10$^3$-10$^{6}$ hrs, but by ISM it can be used for long times creep prediction of more than 10$^4$hrs with most reliability.

• Elastomers and Composites
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• 제47권1호
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• pp.9-17
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• 2012

본 연구에서는 클로로프렌 고무의 열 및 해수에 의한 노화 현상에 따른 물성 변화 및 사용 수명을 예측하였다. 가속 스트레스 수준은 열노화 $80^{\circ}C$, $100^{\circ}C$, $120^{\circ}C$, 해수침지노화 $40^{\circ}C$, $60^{\circ}C$, $80^{\circ}C$에서 2년 3개월(20,000Hr)동안 가속노화를 통해 인장시험을 수행하여 신장률, 인장강도, 경도를 통한 물성변화 측정을 하였다. 분석 결과신장율 저하가 가장 주된 고장지배모드임을 알 수 있었다. 아레누이스 식을 이용한 노화수명 예측 결과 열노화된 CR의 예측 수명은 $23^{\circ}C$에서 125년이며, 해수침지노화된 CR의 예측수명은 $23^{\circ}C$에서 9년이었다. SEM과 SEMEDS 분석 결과, 해수노화시편이 균열과 SEM-EDS에서는 산소의 농도가 증가하였으며, 이를 바탕으로 FT-IR에서는 해수와의 반응에 의하여 C-O와 C=O 결합이 생성되었음을 관찰하였다. 또한 DSC와 TGA 분석에서는 해수침지노화에 의하여 유리전이온도가 상승하며 분해온도가 낮아짐을 관찰하였다.